US4309330A
Expired / Lapsed
US
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Copolymer emulsion
Assignee: Resonac Corp
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Filing: 1981-02-19
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Granted: 1982-01-05
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Expires: 2001-02-19
Abstract
Abstract A copolymer emulsion comprising (I) a copolymer obtained by copolymerizing (A) a dicyclopentadiene derivative, (B), an α,β-unsaturated monomer having one or more OH groups, (C) an α,β-unsaturated monomer copolymerizable with the components (A) and (B), followed by the reaction of the resulting copolymer with (D) a partial allyl ether of polyhydric alcohol having one or more terminal isocyanate groups, and (II) water can be cross-linked and cured at normal temperatures to give coating films particularly excellent in hardness, water resistance, corrosion resistance and solvent resistance.
Inventors
- 👤 Ryoji Ukita
- 👤 Takao Hirayama
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 02:00
CPC Classifications
D; D21; D21H; D21H19/00; D21H19/36; D21H19/44; D21H19/56; C; C08; C08F; C08F265/00; C08F265/04; C08F277/00; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/6705; C08G18/70; C08G18/81; C08G18/8141; C08G18/815
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
140 words
A copolymer emulsion comprising (I) a copolymer obtained by copolymerizing (A) a dicyclopentadiene derivative of the formula: ##STR6## wherein R is hydrogen, halogen or a lower alkyl group, in an amount of 2 to 30 parts by weight, (B) an α,β-unsaturated monomer having one or more hydroxyl groups in an amount of 3 to 20 parts by weight, and (C) an α,β-unsaturated monomer copolymerizable with the components (A) and (B) in an amount sufficient for making the total amount of the components (A), (B) and (C) 100 parts by weight, followed by the reaction of the resulting copolymer with (D) a partial allyl ether of polyhydric alcohol having one or more terminal isocyanate groups obtained by reacting a partial allyl ether of polyhydric alcohol with a diisocyanate in an amount of 2 to 20 parts by weight, and (II) water.
Claim 2
Dependent Claim
140 words
A copolymer emulsion comprising (I) a copolymer obtained by copolymerizing (A) a dicyclopentadiene derivative of the formula: ##STR6## wherein R is hydrogen, halogen or a lower alkyl group, in an amount of 2 to 30 parts by weight, (B) an α,β-unsaturated monomer having one or more hydroxyl groups in an amount of 3 to 20 parts by weight, and (C) an α,β-unsaturated monomer copolymerizable with the components (A) and (B) in an amount sufficient for making the total amount of the components (A), (B) and (C) 100 parts by weight, followed by the reaction of the resulting copolymer with (D) a partial allyl ether of polyhydric alcohol having one or more terminal isocyanate groups obtained by reacting a partial allyl ether of polyhydric alcohol with a diisocyanate in an amount of 2 to 20 parts by weight, and (II) water.
Claim 3
Dependent Claim
52 words
A copolymer emulsion according to claim 1, wherein the component (D) is a reaction product obtained by reacting a partial allyl ether of polyhydric alcohol with a diisocyanate in equivalent ratio of the OH group of the former to the NCO group of the latter in the range of 1/2 to 1/2.2.
Claim 4
Dependent Claim
24 words
A copolymer emulsion according to claim 1 or 2, wherein the partial allyl ether of polyhydric alcohol has one hydroxyl group in the molecule.
Claim 5
Dependent Claim
35 words
A copolymer emulsion according to claim 3, wherein the partial allyl ether of polyhydric alcohol is a monoallyl ether of dihydric alcohol, a diallyl ether of trihydric alcohol or a triallyl ether of tetrahydric alcohol.
Claim 6
Dependent Claim
22 words
A coploymer emulsion according to claim 1, wherein the component (A) is dicyclopentenyl methacrylate, dicyclopentyl acrylate, dicyclopentenyl α-chlorocylate, or a mixture thereof.
Claim 7
Dependent Claim
17 words
A copolymer emulsion according to claim 1, wherein the component (B) is β-hydroxyethyl acrylate or β-hydroxyethyl methacrylate.
Claim 8
Dependent Claim
26 words
A copolymer emulsion according to claim 1, wherein the component (D) is a reaction product of trimethylolpropane diallyl ether with tolylene diisocyanate in 1:1 eqivalent ratio.
Claim 9
Dependent Claim
132 words
A copolymer produced by copolymerizing (A) a dicyclopentadiene derivative of the formula: ##STR7## wherein R is hydrogen, halogen or a lower alkyl group, in an amount of 2 to 30 parts by weight, (B) an α,β-unsaturated monomer having one or more hydroxyl groups in an amount of 3 to 20 parts by weight, and (C) an α,β-unsaturated monomer copolymerizable with the components (A) and (B) in an amount sufficient for making the total amount of the components (A), (B) and (C) 100 parts by weight, followed by the reaction of the resulting copolymer with (D) a partial allyl ether of polyhydric alcohol having one or more terminal isocyanate groups obtained by reacting a partial allyl ether of polyhydric alcohol with a diisocyanate in an amount of 2 to 20 parts by weight.
Claim 10
Dependent Claim
132 words
A copolymer produced by copolymerizing (A) a dicyclopentadiene derivative of the formula: ##STR7## wherein R is hydrogen, halogen or a lower alkyl group, in an amount of 2 to 30 parts by weight, (B) an α,β-unsaturated monomer having one or more hydroxyl groups in an amount of 3 to 20 parts by weight, and (C) an α,β-unsaturated monomer copolymerizable with the components (A) and (B) in an amount sufficient for making the total amount of the components (A), (B) and (C) 100 parts by weight, followed by the reaction of the resulting copolymer with (D) a partial allyl ether of polyhydric alcohol having one or more terminal isocyanate groups obtained by reacting a partial allyl ether of polyhydric alcohol with a diisocyanate in an amount of 2 to 20 parts by weight.
Claim 11
Dependent Claim
52 words
A copolymer according to claim 8, wherein the component (A) is dicyclopentadiene methacrylate, the component (B) is β-hydroxyethyl methacrylate, the component (C) is methyl methacrylate, butyl acrylate, acrylic acid or a mixture thereof, and the component (D) is a reaction product of trimethylolpropane diallyl ether with tolylene diisocyanate in 1:1 equivalent ratio.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-01-04 | 1985-07-06 | 1986-01-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-01-04 | 1989-07-06 | 1990-01-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-01-04 | 1993-07-06 | 1994-01-05 | $7700.00 | Window Closed / Lapsed |