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US4308188A Expired / Lapsed US ⏱️ 0.0 years remaining

Zwitterion polymer for water borne coatings

Assignee: International Minerals and Chemical Corp
•
Filing: 1980-06-02
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Granted: 1981-12-29
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Expires: 2000-06-02
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Abstract

Abstract A water-dilutable polymer for use in water-borne coatings comprising the half ester zwitterion reaction product of a polymer containing cyclic acid anhydride groups with an alkanolamine of the formula ##STR1## where R is hydrogen or hydroxy, R 1 is hydrogen, hydroxy or methyl and can be the same or different, and R 2 is hydrogen or an aliphatic hydrocarbon group of from 1 to 3 carbon atoms.

Inventors

  • 👤 Zeno W. Wicks
  • 👤 Milton E. Woods
  • 👤 Chiew-Wah Koay

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 07:16
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/30; C08F8/32

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 53 words
A polymer useful in water-borne coatings comprising the half ester zwitterion reaction product of a polymer containing acid anhydride groups with an alkanolamine of the formula ##STR5## where R is hydrogen or hydroxy and R 1 is hydrogen, hydroxy or methyl and can be the same or different, and R 2 is hydrogen.
Claim 2
Dependent Claim 53 words
A polymer useful in water-borne coatings comprising the half ester zwitterion reaction product of a polymer containing acid anhydride groups with an alkanolamine of the formula ##STR5## where R is hydrogen or hydroxy and R 1 is hydrogen, hydroxy or methyl and can be the same or different, and R 2 is hydrogen.
Claim 3
Dependent Claim 13 words
The polymer of claim 1 wherein R and R 1 are each hydrogen.
Claim 4
Dependent Claim 13 words
The polymer of claim 1 wherein R and R 1 are each hydroxyl.
Claim 5
Dependent Claim 14 words
The polymer of claim 1 wherein R is hydroxyl and R 1 is hydrogen.
Claim 6
Dependent Claim 14 words
The polymer of claim 1 wherein R is hydroxyl and R 1 is methyl.
Claim 7
Dependent Claim 15 words
The water borne coating consisting essentially of the polymer of claim 1 dispersed in water.
Claim 8
Dependent Claim 74 words
A polymer obtained by reacting (a) a copolymer by reacting the vinyl ester of trimellitic anhydride with an alkyl acrylate or alkyl methacrylate, or mixture thereof, the alkyl group having from 1-4 carbon atoms, and (b) an alkanolamine of the formula ##STR6## where R is hydrogen or hydroxy and R 1 is hydrogen, hydroxy or methyl and can be the same or different, and R 2 is hydrogen, an aliphatic hydrocarbon group or aryl.
Claim 9
Dependent Claim 74 words
A polymer obtained by reacting (a) a copolymer by reacting the vinyl ester of trimellitic anhydride with an alkyl acrylate or alkyl methacrylate, or mixture thereof, the alkyl group having from 1-4 carbon atoms, and (b) an alkanolamine of the formula ##STR6## where R is hydrogen or hydroxy and R 1 is hydrogen, hydroxy or methyl and can be the same or different, and R 2 is hydrogen, an aliphatic hydrocarbon group or aryl.
Claim 10
Dependent Claim 10 words
A polymer of claim 7 wherein the alkanolamine is 2-amino-2-methyl-1-propanol.
Claim 11
Dependent Claim 75 words
A polymer useful in water-borne coatings comprising the half ester zwitterion reaction product of (a) a polymer prepared from a maleated epoxy ester, a maleated drying oil, styrenemaleic anhydride, maleinized rosin, 4-palmityl-1,2-butyric anhydride and 3-methoxy-1,2-butyric anhydride with (b) an alkanolamine of the formula ##STR7## where R is hydrogen or hydroxy, R 1 is hydrogen, hydroxy or methyl and can be the same or different, and R 2 is hydrogen, an aliphatic hydrocarbon group or aryl.
Claim 12
Dependent Claim 75 words
A polymer useful in water-borne coatings comprising the half ester zwitterion reaction product of (a) a polymer prepared from a maleated epoxy ester, a maleated drying oil, styrenemaleic anhydride, maleinized rosin, 4-palmityl-1,2-butyric anhydride and 3-methoxy-1,2-butyric anhydride with (b) an alkanolamine of the formula ##STR7## where R is hydrogen or hydroxy, R 1 is hydrogen, hydroxy or methyl and can be the same or different, and R 2 is hydrogen, an aliphatic hydrocarbon group or aryl.
Claim 13
Dependent Claim 10 words
A polymer of claim 9 prepared from maleated epoxy ester.
Claim 14
Dependent Claim 11 words
A polymer of claim 9 prepared from a maleated drying oil.
Claim 15
Dependent Claim 9 words
A polymer of claim 9 prepared from styrene-maleic anhydride.
Claim 16
Dependent Claim 9 words
A polymer of claim 9 prepared from maleinized rosin.
Claim 17
Dependent Claim 10 words
A polymer of claim 9 prepared from polymeric 4-palmityl-1,2-butyric anhydride.
Claim 18
Dependent Claim 10 words
A polymer of claim 9 prepared from polymeric 3-methoxy-1,2-butyric anhydride.

References Cited (Backward Citations)

US3203935A Cited
US3497550A Cited
US3585172A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-12-28 1985-06-29 1985-12-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-12-28 1989-06-29 1989-12-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-12-28 1993-06-29 1993-12-29 $7700.00 Window Closed / Lapsed

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