US4307172A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Imaging light-sensitive material with etchable opaque polyamide underlayer and light-sensitive resist overlayer
Assignee: Daicel Corp
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Filing: 1980-04-30
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Granted: 1981-12-22
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Expires: 2000-04-30
Abstract
Abstract Disclosed is an imaging light-sensitive material which comprises a transparent substrate, [I] a polyamide layer containing an alcohol-soluble polyamide as the major component and having a thickness of from 2 to 11 microns and [II] a light-sensitive layer having a thickness of from 0.5 to 5 microns.
Inventors
- 👤 Tetsuo Ishihara
- 👤 Keizi Kubo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 10:35
CPC Classifications
G; G03; G03F; G03F1/00; G03F1/54; G03F1/56; C; C08; C08L; C08L77/00; G03F7/00; G03F7/004; G03F7/09; G03F7/11
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
215 words
An imaging, light-sensitive material, comprising: a transparent substrate; an etchable, polyamide layer overlying said substrate, said polyamide layer having a thickness of from 2 to 11 microns and containing a dye or pigment so that said layer is opaque to actinic light, the film-forming component of said polyamide layer comprising alcohol-soluble polyamide as the major film-forming ingredient, said alcohol-soluble polyamide ingredient being one or a mixture of materials selected from the group consisting of nylon 6/66, nylon 6/66/610, nylon 6/66/610/612, nylon 6/66/12 and N-alkoxyalkyl polyamides wherein the alkoxy and alkyl groups each have from 1 to 8 carbon atoms and the degree of alkoxyalkylation is from 10 to 40%; a light-sensitive photoresist layer overlying said polyamide layer, said light-sensitive photoresist layer having a thickness of from 0.5 to 5 microns and containing a light-sensitive agent selected from the group consisting of azide compounds, o-quinone diazide compounds and organic solvent-soluble diazo compounds, said light-sensitive photoresist layer being capable of being transformed by imagewise exposure to actinic radiation into exposed and non-exposed areas which have different solubilities in an alkaline developer so that the areas which are more soluble in the alkaline developer can be removed to form a developed relief image whereupon the uncovered areas of said polyamide layer can be removed by an etching solution.
Claim 2
Dependent Claim
215 words
An imaging, light-sensitive material, comprising: a transparent substrate; an etchable, polyamide layer overlying said substrate, said polyamide layer having a thickness of from 2 to 11 microns and containing a dye or pigment so that said layer is opaque to actinic light, the film-forming component of said polyamide layer comprising alcohol-soluble polyamide as the major film-forming ingredient, said alcohol-soluble polyamide ingredient being one or a mixture of materials selected from the group consisting of nylon 6/66, nylon 6/66/610, nylon 6/66/610/612, nylon 6/66/12 and N-alkoxyalkyl polyamides wherein the alkoxy and alkyl groups each have from 1 to 8 carbon atoms and the degree of alkoxyalkylation is from 10 to 40%; a light-sensitive photoresist layer overlying said polyamide layer, said light-sensitive photoresist layer having a thickness of from 0.5 to 5 microns and containing a light-sensitive agent selected from the group consisting of azide compounds, o-quinone diazide compounds and organic solvent-soluble diazo compounds, said light-sensitive photoresist layer being capable of being transformed by imagewise exposure to actinic radiation into exposed and non-exposed areas which have different solubilities in an alkaline developer so that the areas which are more soluble in the alkaline developer can be removed to form a developed relief image whereupon the uncovered areas of said polyamide layer can be removed by an etching solution.
Claim 3
Dependent Claim
26 words
An imaging material as set forth in claim 1 wherein the thickness of said polyamide layer is in the range of from 4 to 10 microns.
Claim 4
Dependent Claim
18 words
An imaging material as set forth in claim 1 wherein said polyamide layer further comprises an oil-soluble dye.
Claim 5
Dependent Claim
35 words
An imaging material as set forth in claim 1 wherein said transparent substrate is a sheet or film of a polymer selected from the group consisting of polyethylene terephthalate, polypropylene, polystyrene, polycarbonate and cellulose acetate.
Claim 6
Dependent Claim
58 words
An imaging material as set forth in claim 1 or claim 2 in which the film-forming component of said polyamide layer consists essentially of a mixture of from 50 to 90% by weight of said N-alkoxyalkyl polyamide and the balance is nylon copolymer selected from the group consisting of nylon 6/66, nylon 6/66/610, nylon 6/66/610/612 and nylon 6/66/12.
Claim 7
Dependent Claim
58 words
An imaging material as set forth in claim 1 or claim 2 in which the film-forming component of said polyamide layer consists essentially of a mixture of from 80 to 99.9% by weight of said N-alkoxyalkyl polyamide and the balance is selected from the group consisting of cellulose nitrate, cellulose acetate propionate, cellulose acetate butyrate and cellulose propionate.
Claim 8
Dependent Claim
36 words
An imaging material as set forth in claim 1 or claim 2 in which said light-sensitive photoresist layer contains an alkali-soluble resin selected from the group consisting of alkali-soluble phenol-formaldehyde resins and alkali-soluble styrene-maleic anhydride resins.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-12-21 | 1985-06-22 | 1985-12-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-12-21 | 1989-06-22 | 1989-12-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-12-21 | 1993-06-22 | 1993-12-22 | $7700.00 | Window Closed / Lapsed |