← Back to Patent Explorer
US4307159A Expired / Lapsed US ⏱️ 0.0 years remaining

Zinc halogen battery electrolyte compositions with bismuth additive

Assignee: Energy Development Associates Inc
•
Filing: 1980-03-28
•
Granted: 1981-12-22
•
Expires: 2000-03-28
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract This disclosure relates to a zinc halogen battery electrolyte composition containing an additive providing increased battery capacity. The improved electrolyte composition involves the use of a bismuth additive to inhibit undesirable irregular plating and reduce nodular or dendritic growth on the zinc electrode.

Inventors

  • 👤 Michael J. Hammond
  • 👤 Patricia H. Schultz
  • 👤 Vladimir Feiman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 04:38
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/36; H01M10/365; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 52 words
An electrolyte composition for use in a metal halogen battery construction having at least one positive electrode and at least one negative electrode, said electrolyte composition comprising an aqueous metal halide solution and bismuth as an additive to said electrolyte in a quantity effective in reducing dendrite formation on said negative electrode.
Claim 2
Dependent Claim 52 words
An electrolyte composition for use in a metal halogen battery construction having at least one positive electrode and at least one negative electrode, said electrolyte composition comprising an aqueous metal halide solution and bismuth as an additive to said electrolyte in a quantity effective in reducing dendrite formation on said negative electrode.
Claim 3
Dependent Claim 52 words
An electrolyte composition for use in a zinc halogen battery construction having at least one positive electrode and at least one negative electrode, said electrolyte composition comprising an aqueous zinc halide solution and bismuth as an additive to said electrolyte in a quantity effective in reducing dendrite formation on said negative electrode.
Claim 4
Dependent Claim 52 words
An electrolyte composition for use in a zinc halogen battery construction having at least one positive electrode and at least one negative electrode, said electrolyte composition comprising an aqueous zinc halide solution and bismuth as an additive to said electrolyte in a quantity effective in reducing dendrite formation on said negative electrode.
Claim 5
Dependent Claim 25 words
An improved zinc halogen battery construction comprising at least one positive electrode and at least one negative electrode and the electrolyte composition of claim 2.
Claim 6
Dependent Claim 54 words
An electrolyte composition for use in a zinc chlorine battery construction having at least one positive electrode and at least one negative electrode, said electrolyte composition comprising an aqueous zinc chloride solution and bismuth as an additive to said electrolyte in an amount from about 50 to about 150 milligrams per liter of electrolyte.
Claim 7
Dependent Claim 54 words
An electrolyte composition for use in a zinc chlorine battery construction having at least one positive electrode and at least one negative electrode, said electrolyte composition comprising an aqueous zinc chloride solution and bismuth as an additive to said electrolyte in an amount from about 50 to about 150 milligrams per liter of electrolyte.
Claim 8
Dependent Claim 27 words
The invention of claim 4 wherein said bismuth is present in said electrolyte in an amount from about 70 to about 80 milligrams per liter of electrolyte.
Claim 9
Dependent Claim 24 words
The invention of claim 4 wherein said bismuth is present in said electrolyte in an amount of about 75 milligrams per liter of electrolyte.
Claim 10
Dependent Claim 25 words
An improved zinc chlorine battery construction comprising at least one positive electrode and at least one negative electrode and the electrolyte composition of claim 4.
Claim 11
Dependent Claim 53 words
An electrolyte composition for use in a zinc chlorine battery construction having at least one positive electrode and at lease one negative electrode, said electrolyte composition comprising an aqueous zinc chloride solution and bismuth as an additive to said eleectrolyte in a quantity effective to increase the charge capacity density of said battery.
Claim 12
Dependent Claim 53 words
An electrolyte composition for use in a zinc chlorine battery construction having at least one positive electrode and at lease one negative electrode, said electrolyte composition comprising an aqueous zinc chloride solution and bismuth as an additive to said eleectrolyte in a quantity effective to increase the charge capacity density of said battery.
Claim 13
Dependent Claim 27 words
The invention of claim 8 wherein said bismuth is present in said electrolyte in an amount from about 50 to about 150 milligrams per liter of electrolyte.

References Cited (Backward Citations)

US3713888A Cited
US3793079A Cited
US3811946A Cited
US3881958A Cited
US3953302A Cited
US3993502A Cited
US4001036A Cited
US4144381A Cited
US4181777A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-12-21 1985-06-22 1985-12-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-12-21 1989-06-22 1989-12-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-12-21 1993-06-22 1993-12-22 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag