US4307000A
Expired / Lapsed
US
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Aliphatic polyurethane coating composition
Assignee: EIDP Inc
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Filing: 1980-12-01
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Granted: 1981-12-22
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Expires: 2000-12-01
Abstract
Abstract A coating composition of an aliphatic polyurethane resin in an organic solvent; wherein the resin has terminal hydroxyl groups, a weight average molecular weight of about 3,000 to 30,000, and is the reaction product of a fatty acid ester of drying oil fatty acids, polyol, having at least three reactive hydroxyl groups, aromatic monobasic and an alkyl amino aromatic acid that provides ultraviolet light absorbing groups, and an aliphatic diisocyanate; the composition can contain conventional pigments, organo metallic driers, and light stabilizers and cures at ambient temperatures and is useful as primary finish for metals, plastics and reinforced plastics, and can be used as a refinish composition for automobiles and trucks.
Inventors
- 👤 Joseph A. Vasta
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 16:11
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/70; C08G18/72; C08G18/77; C08G18/28; C08G18/30; C08G18/36; C08G18/73; C08G18/74; C08G18/75; C09; C09D; C09D175/00; C09D175/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31573; Y10T428/31583; Y10T428/31587
Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
113 words
A coating composition comprising 30-90% by weight, based on the weight of the composition, of an organic solvent and 10-70% by weight, based on the weight of the composition, of a binder; wherein the binder comprises an aliphatic polyurethane resin having terminal hydroxyl groups and a weight average molecular weight of about 3,000 to 30,000 determined by gel permeation chromatography and consists of a condensation polymerization product of (1) a fatty acid ester consisting of the esterification product of drying oil fatty acids a polyol having at least three reactive hydroxyl groups an, aromatic monobasic acid, and an alkyl amino aromatic acid that provides ultraviolet light absorbing groups with (2) an aliphatic diisocyanate.
Claim 2
Dependent Claim
113 words
A coating composition comprising 30-90% by weight, based on the weight of the composition, of an organic solvent and 10-70% by weight, based on the weight of the composition, of a binder; wherein the binder comprises an aliphatic polyurethane resin having terminal hydroxyl groups and a weight average molecular weight of about 3,000 to 30,000 determined by gel permeation chromatography and consists of a condensation polymerization product of (1) a fatty acid ester consisting of the esterification product of drying oil fatty acids a polyol having at least three reactive hydroxyl groups an, aromatic monobasic acid, and an alkyl amino aromatic acid that provides ultraviolet light absorbing groups with (2) an aliphatic diisocyanate.
Claim 3
Dependent Claim
18 words
The coating composition of claim 1 containing pigment in a pigment to binder ratio of 0.5/100 to 300/100.
Claim 4
Dependent Claim
21 words
The coating composition of claim 1 containing 0.1-1% by weight, based on the weight of the binder, of organo metallic drier.
Claim 5
Dependent Claim
20 words
The coating composition of claim 1 containing 0.1-5% by weight, based on the weight of the binder, of light stabilizer.
Claim 6
Dependent Claim
16 words
The coating composition of claim 4 in which the light stabilizer is a substituted piperazine compound.
Claim 7
Dependent Claim
21 words
The coating composition of claim 1 containing 1-20% by weight, based on the weight of the binder, of a crosslinking agent.
Claim 8
Dependent Claim
17 words
The coating composition of claim 6 in which the crosslinking agent is an alkylated melamine formaldehyde resin.
Claim 9
Dependent Claim
43 words
The coating composition of claim 1 in which drying oil fatty acid is from the group of dehydrated castor oil fatty acids, soya oil fatty acids, tung oil fatty acids, linseed oil fatty acids, oiticica oil fatty acids and safflower oil fatty acids.
Claim 10
Dependent Claim
22 words
The coating composition of claim 1 in which the polyol is from the group of glycerol, trimethylol alkane, pentaerythritol dipentaerythritol and sorbitol.
Claim 11
Dependent Claim
25 words
The coating composition of claim 1 in which the aromatic monobasic acid is from the group of benzoic acid, butyl benzoic acid, and abietic acid.
Claim 12
Dependent Claim
23 words
The coating composition of claim 1 in which the alkyl amino aromatic acids is dimethyl amino benzoic acid or para amino benzoic acid.
Claim 13
Dependent Claim
31 words
The coating composition of claim 1 in which the aliphatic diisocyanate is selected from the group of alkylene diisocyanates having 2-12 carbon atoms in the alkylene group and alkylene bis(cyclohexyl isocyanates).
Claim 14
Dependent Claim
49 words
The coating composition of claim 1 in which the polyruethane resin consists of the condensation polymerization product of (1) a fatty acid ester consisting of the esterification product of trimethylol propane, dehydrated castor oil fatty acids, benzoic acid, and para dimethyl amino benzoic acid with (2) methylene bis(cyclohexyl isocyanate).
Claim 15
Dependent Claim
29 words
The coating composition of claim 12 containing about 0.1-5% by weight based on the weight of the binder, of an ultraviolet light stabilizer consisting of a substituted piperazine compound;
Claim 16
Dependent Claim
36 words
1-1% by weight, based on the weight of the binder of a blend of an organic cobalt drier and an organic calcium drier and pigment in a pigment to binder ratio of about 0.05/100 to 75/100.
Claim 17
Dependent Claim
36 words
1-1% by weight, based on the weight of the binder of a blend of an organic cobalt drier and an organic calcium drier and pigment in a pigment to binder ratio of about 0.05/100 to 75/100.
Claim 18
Dependent Claim
14 words
A substrate coated with a layer of the dried coalesced composition of claim 1.
Claim 19
Dependent Claim
23 words
A metal substrate coated with a primer layer of pigmented alkyd resin and a layer of the dried coalesced composition of claim 14.
Claim 20
Dependent Claim
20 words
A reinforced plastic substrate coated with a primer layer and a layer of the dried coalesced composition of claim 2.
Claim 21
Dependent Claim
106 words
A process for making an aliphatic polyurethane which comprises the following steps: (1) contacting drying oil fatty acids, polyol having at least three reactive hydroxyl groups, aromatic monobasic acid and an alkyl amino aromatic acid at a temperature of 160°-250° C. for about 2-8 hours to form a fatty acid ester and (2) contacting said fatty acid ester with aliphatic diisocyanate in the presence of a metallic organo catalyst for about 0.5 to 3 hours at a temperature of about 30°-100° C. to form said resin having terminal hydroxyl groups and a weight average molecular weight of about 3,000 to 30,000 determined by gel permeation chromatography.
Claim 22
Dependent Claim
106 words
A process for making an aliphatic polyurethane which comprises the following steps: (1) contacting drying oil fatty acids, polyol having at least three reactive hydroxyl groups, aromatic monobasic acid and an alkyl amino aromatic acid at a temperature of 160°-250° C. for about 2-8 hours to form a fatty acid ester and (2) contacting said fatty acid ester with aliphatic diisocyanate in the presence of a metallic organo catalyst for about 0.5 to 3 hours at a temperature of about 30°-100° C. to form said resin having terminal hydroxyl groups and a weight average molecular weight of about 3,000 to 30,000 determined by gel permeation chromatography.
Claim 23
Dependent Claim
27 words
The process of claim 18 which comprises the use in Step (1) of trimethylol propane, dehydrated castor oil fatty acids, benzoic acid and dimethyl amino benzoic acid.
Claim 24
Dependent Claim
14 words
The process of claim 19 in which the aliphatic diisocyanate is methylene bis(cyclohexyl isocyanate).
Claim 25
Dependent Claim
15 words
The process of claim 20 in which the metallic organo catalyst is ferric acetyl acetonate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-12-21 | 1985-06-22 | 1985-12-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-12-21 | 1989-06-22 | 1989-12-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-12-21 | 1993-06-22 | 1993-12-22 | $7700.00 | Window Closed / Lapsed |