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US4306952A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrolytic process and apparatus

Assignee: Magneto Chemie NV
•
Filing: 1980-05-22
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Granted: 1981-12-22
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Expires: 2000-05-22
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Abstract

Abstract Method and apparatus for electrolyzing halogen salt solutions having a low halogen salt concentration with direct formation of halogen, using an electrolytic cell comprising at least one anode and at least two electrodes which can function as cathodes. The anode is permanently connected as an anode, a portion of the anodic current is passed through one electrode which can function as a cathode, and a cathodic current is passed through the other electrode which can function as a cathode. The polarity of the electrode functioning as a co-anode and of the electrode functioning as a cathode is periodically changed in cycles of 80-330 minutes.

Inventors

  • 👤 Hermanus J. Jansen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 08:34
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/46; C02F1/461; C02F1/46104; C02F1/46109; C02F1/467; C02F1/4672; C02F1/4674; C25; C25B; C25B15/00; C02F2001/46119; C02F2001/46133; C02F2001/46138; C02F2103/00; C02F2103/42; C02F2201/00; C02F2201/46; C02F2201/461; C02F2201/46105; C02F2201/4612; C02F2201/46125; C02F2201/4613; C02F2303/00; C02F2303/04

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 142 words
An electrolytic process in which depositions on the cathode are removed by periodically rendering the polarity of the cathode anodic, comprising (a) using at least one anode and at least two electrodes which can function as cathodes; (b) passing an anodic current through the anode so that the anode always remains the anode; (c) passing a portion of the anodic current through an electrode which can serve as a cathode to remove deposits formed thereon; (d) passing a cathodic current through the other electrode which can serve as a cathode; and (e) periodically changing the polarity of the electrode functioning as a co-anode and the electrode functioning as a cathode, characterized by the step of periodically reversing the polarity of the electrode functioning as a co-anode and the electrode functioning as a cathode in cycles having a period of between 80-330 minutes.
Claim 2
Dependent Claim 142 words
An electrolytic process in which depositions on the cathode are removed by periodically rendering the polarity of the cathode anodic, comprising (a) using at least one anode and at least two electrodes which can function as cathodes; (b) passing an anodic current through the anode so that the anode always remains the anode; (c) passing a portion of the anodic current through an electrode which can serve as a cathode to remove deposits formed thereon; (d) passing a cathodic current through the other electrode which can serve as a cathode; and (e) periodically changing the polarity of the electrode functioning as a co-anode and the electrode functioning as a cathode, characterized by the step of periodically reversing the polarity of the electrode functioning as a co-anode and the electrode functioning as a cathode in cycles having a period of between 80-330 minutes.
Claim 3
Dependent Claim 51 words
A method as claimed in claim 1, wherein the step of periodically reversing includes periods in which the period in the cycles in which the electrode which can serve as a cathode functions as a co-anode is equal, or substantially equal, to the period in which it functions as a cathode.
Claim 4
Dependent Claim 25 words
A method as claimed in claim 1, including the step of passing the electrolyte along the electrodes with a velocity of less than 25 cm/sec.
Claim 5
Dependent Claim 26 words
A method as claimed in claim 1 or 2 or 3, including the step of passing 85-97% of the total anodic current through the permanent anode.
Claim 6
Dependent Claim 27 words
A method as claimed in claim 1 or 2 or 3, including the step of using an anode of titanium expanded mesh having an activating coating thereon.
Claim 7
Dependent Claim 23 words
A method as claimed in claim 1 or 2 or 3, including the step of using graphite electrodes which can serve as cathode.
Claim 8
Dependent Claim 44 words
A method as claimed in claim 1 or 2 or 3, including the step of using, for the electrodes which can serve as cathodes, electrodes of titanium with an active coating of one or more noble metals, noble metal oxides and/or valve metal oxides.
Claim 9
Dependent Claim 21 words
A method as claimed in claim 7, including using as said active coating a mixture of rhutenium oxide and titanium oxide.

References Cited (Backward Citations)

US3600286A Cited
US3785954A Cited
US4085028A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-12-21 1985-06-22 1985-12-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-12-21 1989-06-22 1989-12-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-12-21 1993-06-22 1993-12-22 $7700.00 Window Closed / Lapsed

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