US4306054A
Expired / Lapsed
US
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Process for the production of epoxide resins
Assignee: Leuna Werke Walter Ulbright Germany VEB
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Filing: 1979-11-05
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Granted: 1981-12-15
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Expires: 1999-11-05
Abstract
Abstract The invention relates to the continuous production of epoxide resins of low, medium and high molecular weight, and also to their purification and to that of the waste water. No raw materials are required in addition to epichlorohydrin, 2,2-bis-(4-hydroxyphenyl)-propane, alkali hydroxide and water. The raw materials are fed at a shear rate of 7.5-50×10 4 sec -1 (at a peripheral speed of the rotor of 15 to 50 m/sec and a distance of the rotor elements from the stator elements of 0.01 to 0.02 cm) continuously into a reactor and mixed in such a way that by the concentration of high kinetic energy in a very limited space the interfaces of the phases of the heterogeneous reaction mixture are increased to an extreme extent and the reagents are caused to react with one another within 5 sec. at the latest. The reaction proceeds very evenly in the reactor. By conversion of the kinetic energy and reaction heat of the chemical reaction the necessary reaction temperature is maintained for the reaction system within the reactor. The resins obtained and also their waste water are extracted in a pulsation unit in a counterflow, by means of water or organic solvents. This process enables epoxide resins of superior quality to be economically produced. The contamination of the waste water can be thus reduced to a minimum.
Inventors
- 👤 Ferdinand Alber
- 👤 Wolfgang Bohm
- 👤 Manfred Gaikowski
- 👤 Christian Gunther
- 👤 Herbert Hecker
- 👤 Walter Horingklee
- 👤 Lothar Kaiser
- 👤 Helmut Kopp
- 👤 Erna Lange
- 👤 Gotthold May
- 👤 Martin Muller
- 👤 Wieland Schafer
- 👤 Jurgen Schillgalies
- 👤 Manfred Scholz
- 👤 Gunter Seidel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 13:46
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/02; C08G59/04; C08G59/06; C08G59/063; C08G59/18; C08G59/20; C08G59/22; C08G59/24; C08G59/245
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
162 words
A continuous process for preparing epoxide resins in the presence of water and purifying both the waste water and the epoxide resins, which comprises reacting 2,2-bis-(4-hydroxyphenyl)-propane, epichlorohydrin and alkali metal hydroxide in the presence of water by means of continuously mixing said reactants in the presence of water at a shearing rate of 7.5-50×10 4 sec -1 and per cm and at a temperature of 60°-180° C. in a reaction zone, continuously withdrawing the reaction product, purifying said resin reaction product by dissolving said reaction product in an organic solvent and continuously extracting the inorganic salts formed during the reaction by means of aqueous counterflow to the organic solvent flow in a continuous pulsation amplitude of up to 250 mm, and a pulsation frequency of up to 25 Hz and at atmospheric pressure and at a temperature of 10° to 85° C., and continuously recovering pure neutral epoxide resin solution; and purifying said waste water by counterflow extraction with an organic solvent.
Claim 2
Dependent Claim
162 words
A continuous process for preparing epoxide resins in the presence of water and purifying both the waste water and the epoxide resins, which comprises reacting 2,2-bis-(4-hydroxyphenyl)-propane, epichlorohydrin and alkali metal hydroxide in the presence of water by means of continuously mixing said reactants in the presence of water at a shearing rate of 7.5-50×10 4 sec -1 and per cm and at a temperature of 60°-180° C. in a reaction zone, continuously withdrawing the reaction product, purifying said resin reaction product by dissolving said reaction product in an organic solvent and continuously extracting the inorganic salts formed during the reaction by means of aqueous counterflow to the organic solvent flow in a continuous pulsation amplitude of up to 250 mm, and a pulsation frequency of up to 25 Hz and at atmospheric pressure and at a temperature of 10° to 85° C., and continuously recovering pure neutral epoxide resin solution; and purifying said waste water by counterflow extraction with an organic solvent.
Claim 3
Dependent Claim
25 words
A process in accordance with claim 1, wherein a solution of 2,2-bis-(4-hydroxyphenyl)-propane in an aqueous alkali metal hydroxide solution is mixed with epichlorohydrin and reacted.
Claim 4
Dependent Claim
24 words
A process in accordance with claim 1, wherein a solution of 2,2-bis-(4-hydroxyphenyl)-propane in epichlorohydrin is mixed with aqueous alkali metal hydroxide solution and reacted.
Claim 5
Dependent Claim
18 words
A process in accordance with claim 1, wherein the pulsation unit consists of one to eight pulsation columns.
Claim 6
Dependent Claim
16 words
A process in accordance with claim 4, where the pulsation is effected by an inert gas.
Claim 7
Dependent Claim
13 words
A process in accordance with claim 5, wherein the inert gas is nitrogen.
Claim 8
Dependent Claim
25 words
A process in accordance with claim 4, wherein the pulsation amplitude is 6 to 25 mm and the pulsation frequency is 2 to 8 Hz.
Claim 9
Dependent Claim
16 words
A process in accordance with claim 4, wherein the pulsation unit consists of four pulsation columns.
Claim 10
Dependent Claim
21 words
A process in accordance with claim 1, wherein the resin solution contains between 10 and 60% by weight of epoxide resin.
Claim 11
Dependent Claim
15 words
A process in accordance with claim 9, wherein the percentage is between 25 and 45.
Claim 12
Dependent Claim
15 words
A process in accordance with claim 1, wherein the resin is in solution with toluene.
Claim 13
Dependent Claim
24 words
A process in accordance with claim 1, wherein the waste water of the epoxide resin contains less than 10% by weight of epoxide resin.
Claim 14
Dependent Claim
22 words
A process in accordance with claim 1, wherein the quantitative ratios of organic phase to aqueous phase are between 2:1 and 5:1.
Claim 15
Dependent Claim
19 words
A process in accordance with claim 1, wherein the reaction is completed in a further reactor within 5 seconds.
Claim 16
Dependent Claim
30 words
A process in accordance with claim 14, wherein a part of the reagents are reacted and conveyed to the further reactor wherein a further part of the reagents are reacted.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-12-14 | 1985-06-15 | 1985-12-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-12-14 | 1989-06-15 | 1989-12-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-12-14 | 1993-06-15 | 1993-12-15 | $7700.00 | Window Closed / Lapsed |