US4305802A
Expired / Lapsed
US
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Compound chemically sensitive element
Assignee: Olympus Corp
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Filing: 1980-05-08
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Granted: 1981-12-15
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Expires: 2000-05-08
Abstract
Abstract A compound chemically sensitive element comprises a chemically sensitive assembly which is selectively sensitive to a specific ion or a specific substance in a material to be examined, and a pH sensor having an insulated gate field effect transistor structure, both of which are separately manufactured. The chemically sensitive assembly and the insulated gate of the pH sensor are electrochemically connected together by a conductive resin, thus improving the durability and the selectivity of the element. In this manner, limitations imposed upon the manufacture of MOS pH sensor is removed, permitting a wide variety of chemically sensitive films to be used.
Inventors
- 👤 Kiyozo Koshiishi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 23:43
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/414; G01N33/00; G01N33/48; G01N33/483; G01N33/487; G01N33/49; G01N33/492
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
115 words
A compound chemically sensitive element in which a potential difference developed across an interface between a solution to be examined and an ion sensitive assembly in accordance with the concentration of a specific ion contained in the solution is applied to an insulated gate of a pH sensor having an insulated gate field effect transistor structure, and in which a change in the source-drain current of the pH sensor is detected to determine the concentration of the specific ion in the solution, comprising an ion sensitive assembly, a pH sensor having an insulated gate field effect transistor structure, the sensor having an insulated gate and a conductive resin electrochemically connecting the assembly and insulated gate.
Claim 2
Dependent Claim
115 words
A compound chemically sensitive element in which a potential difference developed across an interface between a solution to be examined and an ion sensitive assembly in accordance with the concentration of a specific ion contained in the solution is applied to an insulated gate of a pH sensor having an insulated gate field effect transistor structure, and in which a change in the source-drain current of the pH sensor is detected to determine the concentration of the specific ion in the solution, comprising an ion sensitive assembly, a pH sensor having an insulated gate field effect transistor structure, the sensor having an insulated gate and a conductive resin electrochemically connecting the assembly and insulated gate.
Claim 3
Dependent Claim
22 words
A compound chemically sensitive element according to claim 1, in which the ion sensitive assembly comprises a film of soda aluminosilicate glass.
Claim 4
Dependent Claim
29 words
A compound chemically sensitive element according to claim 1, in which the ion sensitive assembly comprises a solid film formed by a mixture of silver chloride and silver sulfide.
Claim 5
Dependent Claim
22 words
A compound chemically sensitive element according to claim 1, in which the ion sensitive assembly comprises a solid film of lanthanum fluoride.
Claim 6
Dependent Claim
31 words
A compound chemically sensitive element according to claim 1, in which the ion sensitive assembly comprises a porous film of synthetic fibre impregnated with an ion exchange material and polyvinyl chloride.
Claim 7
Dependent Claim
113 words
A compound chemically sensitive element according to claim 1 in which the ion sensitive assembly comprises a semiconductor substrate of one of the p and n conductivity types, a pair of spaced apart surface layers of the other of the p and n conductivity type formed on the surface of the semi-conductor substrate, an insulated gate film comprising at least one layer extending on an upper surface of a channel region between the pair of spaced apart surface layers and on their upper surfaces; in which the conductive resin is in contact with the insulated film gate; and in which the ion sensitive assembly is a film in contact with the conductive resin.
Claim 8
Dependent Claim
43 words
A compound chemically sensitive element according to claim 1 having an intermediate layer disposed between the conductive resin and the ion sensitive assembly, the intermediate layer comprising a pair of electrodes in spaced and opposed relationship to each other interconnected by an electrolyte.
Claim 9
Dependent Claim
128 words
A compound chemically sensitive element according to claim 7 having a constant current source which has a positive and negative terminal, wherein the pair of electrodes are a silver electrode and a platinum electrode connected to the positive and negative terminal of the constant current source so as to form an oxygen electrode across which potential differences are developed in accordance with the amount of oxygen consumption at the chemically sensitive assembly in a manner corresponding to the concentration of a specific substance contained in a material to be examined and in which the potential differences applied to the insulated gate to cause a change in the source-drain current of the pH sensor, which change is detected to determine the concentration of the specific substance in the material.
Claim 10
Dependent Claim
21 words
A compound chemically sensitive element according to claim 8 in which the chemically sensitive assembly contains polyacryl amide and glucose oxidase.
Claim 11
Dependent Claim
19 words
A compound chemically sensitive element according to claim 1 or 7 in which the conductive resin contains silver particles.
Claim 12
Dependent Claim
90 words
A compound chemically sensitive element according to claim 7 in which the chemically sensitive assembly comprises a chemically sensitive film, a silver electrode disposed in contact with the chemically sensitive film, a platinum electrode disposed in spaced and opposing relationship with the silver electrode, and a conductive solid or gel-like electrolyte which fills the space between the platinum electrode and the chemically sensitive film and disposed in contact with the silver electrode, the platinum electrode being electrochemically connected to the insulated gate of the pH sensor through the conductive resin.
Claim 13
Dependent Claim
47 words
A compound chemically sensitive element according to claim 11 in which the chemically sensitive film comprises a gelled film formed of an impregnated polyacryl amide and glucose oxydase porous support, whereby the chemically sensitive film is selectively sensitive to glucose contained in the material to be examined.
Claim 14
Dependent Claim
66 words
A compound chemically sensitive element according to claim 1 or 11 in which the ion sensitive assembly or the chemically sensitive film is tubular in configuration to permit the solution or the material to be examined to flow therethrough, whereby the assembly or the film is selectively sensitive to the specific ion in the solution or to the specific substance in the material to be examined.
Claim 15
Dependent Claim
57 words
A compound chemically sensitive element according to claim 1 or 7 in which the pH sensor comprises an MOS transistor having a gate insulating layer formed by a silicon dioxide layer upon which is a H + sensitive layer which comprises a silicon nitride layer or an aluminium oxide layer which is selectively sensitive to hydrogen ion.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-12-14 | 1985-06-15 | 1985-12-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-12-14 | 1989-06-15 | 1989-12-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-12-14 | 1993-06-15 | 1993-12-15 | $7700.00 | Window Closed / Lapsed |