US4304883A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Unsaturated polyester resin composition for coating metal substrates
Assignee: Resonac Corp
•
Filing: 1980-07-16
•
Granted: 1981-12-08
•
Expires: 2000-07-16
Abstract
Abstract An unsaturated polyester resin composition for coating metal substrates, comprising an unsaturated alkyd component and a polymerizable vinyl monomer, said unsaturated alkyd component selected from the group consisting of: (a) compounds resulting from addition of mono-epoxy compounds possessing a β,γ-unsaturated ether to the carboxyl group of dicyclopentadiene-modified unsaturated alkyds, and (b) mixtures of dicyclopentadiene-modified unsaturated alkyds with unsaturated alkyds obtained by the ring-opening copolymerization of α,β-unsaturated dicarboxylic anhydrides and mono-epoxy compounds possessing a β, γ-unsaturated ether group.
Inventors
- 👤 Tadashi Fujii
- 👤 Kazuyuki Tanaka
- 👤 Tsutomu Toyoda
- 👤 Hirobumi Izumi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 21:08
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/66; C08G63/668; C08G63/676; C08G63/02; C08G63/12; C08G63/52; C08G63/54; C08G63/553; C08G63/56; C08G63/58; C09; C09D; C09D167/00; C09D167/06; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31681
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
76 words
An unsaturated polyester resin composition for coating metal substrates, comprising an unsaturated alkyd component and a polymerizable vinyl monomer, said unsaturated alkyd component selected from the group consisting of: (a) compounds resulting from addition of mono-epoxy compounds possessing a β,γ-unsaturated ether to the carboxyl group of dicyclopentadiene-modified unsaturated alkyds, and (b) mixtures of dicyclopentadiene-modified unsaturated alkyds with unsaturated alkyds obtained by the ring-opening copolymerization of α,β-unsaturated dicarboxylic anhydrides and mono-epoxy compounds possessing a β,γ-unsaturated ether group.
Claim 2
Dependent Claim
76 words
An unsaturated polyester resin composition for coating metal substrates, comprising an unsaturated alkyd component and a polymerizable vinyl monomer, said unsaturated alkyd component selected from the group consisting of: (a) compounds resulting from addition of mono-epoxy compounds possessing a β,γ-unsaturated ether to the carboxyl group of dicyclopentadiene-modified unsaturated alkyds, and (b) mixtures of dicyclopentadiene-modified unsaturated alkyds with unsaturated alkyds obtained by the ring-opening copolymerization of α,β-unsaturated dicarboxylic anhydrides and mono-epoxy compounds possessing a β,γ-unsaturated ether group.
Claim 3
Dependent Claim
37 words
A composition according to claim 1, wherein the mono-epoxy compound possessing a β,γ-unsaturated ether group is represented by the following general formula: ##STR2## wherein R, denotes a hydrocarbon group possessing a β,γ-unsaturated group and optionally including O.
Claim 4
Dependent Claim
19 words
A composition according to claim 2, wherein the mono-epoxy compound possessing a β,γ-unsaturated ether group is allyl glycidyl ether.
Claim 5
Dependent Claim
37 words
A composition according to claim 1, wherein the polymerizable vinyl monomer is used in an amount within the range of 20 to 100 parts by weight based on 100 parts by weight of the unsaturated alkyd component.
Claim 6
Dependent Claim
37 words
A composition according to claim 1, wherein the unsaturated alkyd composition is a compound resulting from the addition of a mono-epoxy compound possessing a β,γ-unsaturated ether group to the carboxy group of the dicyclopentadiene-modified unsaturated alkyd (a).
Claim 7
Dependent Claim
35 words
A composition according to claim 5, wherein the mono-epoxy compound possessing a β,γ-unsaturated ether group is added in an amount approximating its stoichiometric amount relative to the carboxy group remaining in the dicyclopentadiene-modified unsaturated alkyd.
Claim 8
Dependent Claim
23 words
A composition according to claim 6, wherein the unsaturated alkyd component (a) has an acid number within the range of 10 to 60.
Claim 9
Dependent Claim
43 words
A composition according to claim 1, wherein the unsaturated alkyd component is a mixture of the dicyclopentadiene-modified unsaturated alkyd (b) and an unsaturated alkyd obtained by the ring-opening copolymerization of an α,β-unsaturated dicarboxylic anhydride and a mono-epoxy compound possessing a β,γ-unsaturated ether group.
Claim 10
Dependent Claim
30 words
A composition according to claim 8, wherein the α,β-unsaturated dicarboxylic anhydride accounts for 50 to 40 mol% and the compound possessing a β,γ-unsaturated ether group for 50 to 60 mol%.
Claim 11
Dependent Claim
40 words
A composition according to claim 9, wherein the unsaturated alkyd obtained by the ring-opening copolymerization of the α,β-unsaturated dicarboxylic anhydride and the mono-epoxy compound possessing a β,γ-unsaturated ether group has an acid number within the range of 13 to 95.
Claim 12
Dependent Claim
40 words
A composition according to claim 10, wherein the unsaturated alkyd obtained by the ring-opening copolymerization of the α,β-unsaturated dicarboxylic anhydride and the mono-epoxy compound possessing a β,γ-unsaturated ether group has an acid number within the range of 5 to 50.
Claim 13
Independent Claim
63 words
A method for the manufacture of an unsaturated polyester resin composition for coating metal substrates, comprising the steps of causing a dicyclopentadiene-modified unsaturated alkyd to react with a mono-epoxy compound possessing a β,γ-unsaturated other group in the presence of a basic catalyst at temperatures within the range of 80° to 150° C. and mixing the resultant reaction product with a polymerizable vinyl monomer.
Claim 14
Independent Claim
63 words
A method for the manufacture of an unsaturated polyester resin composition for coating metal substrates, comprising the steps of causing a dicyclopentadiene-modified unsaturated alkyd to react with a mono-epoxy compound possessing a β,γ-unsaturated other group in the presence of a basic catalyst at temperatures within the range of 80° to 150° C. and mixing the resultant reaction product with a polymerizable vinyl monomer.
Claim 15
Dependent Claim
37 words
A method according to claim 12, wherein the mono-epoxy compound possessing a β,γ-unsaturated ether group is represented by the following general formula: ##STR3## wherein, R denotes a hydrocarbon group possessing a β,γ-unsaturated group and optionally including O.
Claim 16
Dependent Claim
19 words
A method according to claim 13, wherein the mono-epoxy compound possessing a β,γ-unsaturated ether group is allyl glycidyl ether.
Claim 17
Independent Claim
71 words
A method for the manufacture of an unsaturated polyester resin composition for coating metal substrates, which comprises the steps of subjecting an α,β-unsaturated dicarboxylic anhydride and a mono-epoxy compound possessing a β,γ-unsaturated ether group to a ring-opening copolymerization at temperatures within the range of 80° to 150° C., mixing the resultant unsaturated alkyd with a dicyclopentadiene-modified unsaturated alkyd, and mixing the resultant mixed unsaturated alkyd component with a polymerizable vinyl monomer.
Claim 18
Independent Claim
71 words
A method for the manufacture of an unsaturated polyester resin composition for coating metal substrates, which comprises the steps of subjecting an α,β-unsaturated dicarboxylic anhydride and a mono-epoxy compound possessing a β,γ-unsaturated ether group to a ring-opening copolymerization at temperatures within the range of 80° to 150° C., mixing the resultant unsaturated alkyd with a dicyclopentadiene-modified unsaturated alkyd, and mixing the resultant mixed unsaturated alkyd component with a polymerizable vinyl monomer.
Claim 19
Dependent Claim
37 words
A method according to claim 15, wherein the mono-epoxy compound possessing a β,γ-unsaturated ether group is represented by the following general formula: ##STR4## wherein R, denotes a hydrocarbon group possessing a β,γ-unsaturated group and optionally including O.
Claim 20
Dependent Claim
19 words
A method according to claim 16, wherein the mono-epoxy compound possessing a β,γ-unsaturated ether group is allyl glycidyl ether.
Claim 21
Dependent Claim
31 words
A method according to claim 15, wherein the mono-epoxy compound possessing a β,γ-unsaturated ether group accounts for 50 to 60 mol% and the α,β-unsaturated dicarboxylic anhydride for 50 to 40 mol%.
Claim 22
Dependent Claim
52 words
A method according to claim 15, wherein the unsaturated alkyd obtained by the ring-opening copolymerization of the α,β-unsaturated dicarboxylic anhydride and the mono-epoxy compound possessing a β,γ-unsaturated ether group is mixed with amount within the range of 5 to 50 percent by weight based on the weight of the dicyclopentadiene-modified unsaturated alkyd.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-12-07 | 1985-06-08 | 1985-12-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-12-07 | 1989-06-08 | 1989-12-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-12-07 | 1993-06-08 | 1993-12-08 | $7700.00 | Window Closed / Lapsed |