US4304707A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Rust inhibiting coating compositions
Assignee: Zeneca Inc
•
Filing: 1980-06-30
•
Granted: 1981-12-08
•
Expires: 2000-06-30
Abstract
Abstract Paint formulations containing barium salts of hydroxy acids such as citric, tartaric, salicyclic, alizarine, quinizarine, and chloranilic in their anhydrous or hydrated forms are useful as primer coats for inhibiting rust for time periods equivalent to or better than those primers containing oxides and salts of lead. Barium salt mixtures, coprecipitated blends and barium salt coated substrates are particularly useful as paint additives.
Inventors
- 👤 Erich Kuehn
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 08:31
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/08; C09D5/082; C09D5/086; C23; C23F; C23F11/00; C23F11/08; C23F11/10; C23F11/12; C23F11/124; C23F11/126
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
207 words
In a corrosion-inhibiting coating composition for metallic surfaces which consists essentially of a film forming binder system selected from the group consisting of an acrylic resin, alkyd resin, epoxy resin, polyvinyl acetate, rubber latex and chlorinated rubber, and a corrosion-inhibiting agent; the improvement consisting of having dispersed therein, as said corrosion-inhibiting agent, a substantially water insoluble barium salt of an organic carbonyl group containing compound having 2-40 carbon atoms and at least one acidic hydrogen, said compound being selected from the group consisting of aliphatic and aromatic compounds having at least one hydroxyl group in the beta position to at least one carbonyl group when separated by saturated carbon linkages according to the following structure: ##STR2## at least one hydroxyl group in the gamma position to at least one carbonyl group when separated by an ethylenically unsaturated carbon linkage according to the following structure: ##STR3## and at least one hydroxyl group in the β, Δ or γ positions to at least one carbonyl group when separated by aromatic unsaturation according to the following structure: ##STR4## and wherein said carbonyl group is present as part of an aldo, keto, carboxyl, carboxy ester or amido group and wherein said barium salts are precipitated from solutions of basic barium compounds.
Claim 2
Dependent Claim
207 words
In a corrosion-inhibiting coating composition for metallic surfaces which consists essentially of a film forming binder system selected from the group consisting of an acrylic resin, alkyd resin, epoxy resin, polyvinyl acetate, rubber latex and chlorinated rubber, and a corrosion-inhibiting agent; the improvement consisting of having dispersed therein, as said corrosion-inhibiting agent, a substantially water insoluble barium salt of an organic carbonyl group containing compound having 2-40 carbon atoms and at least one acidic hydrogen, said compound being selected from the group consisting of aliphatic and aromatic compounds having at least one hydroxyl group in the beta position to at least one carbonyl group when separated by saturated carbon linkages according to the following structure: ##STR2## at least one hydroxyl group in the gamma position to at least one carbonyl group when separated by an ethylenically unsaturated carbon linkage according to the following structure: ##STR3## and at least one hydroxyl group in the β, Δ or γ positions to at least one carbonyl group when separated by aromatic unsaturation according to the following structure: ##STR4## and wherein said carbonyl group is present as part of an aldo, keto, carboxyl, carboxy ester or amido group and wherein said barium salts are precipitated from solutions of basic barium compounds.
Claim 3
Dependent Claim
159 words
A pigment for use in corrosion inhibiting surface coatings which comprises a particulate substrate having deposit thereon a substantially water insoluble barium salt of an organic carbonyl group containing compound having 20-40 carbon atoms and having at least one acidic hydrogen said compound selected from the group consisting of an aliphatic and aromatic compound having at least one hydroxyl group in a β position to at least one carbonyl group and separated by saturated carbon linkages according to the following structure: ##STR5## at least one hydroxyl group in the γ position to at least one carbonyl group when separated by an ethylenically unsaturated linkage according to the following structure: ##STR6## and at least one hydroxyl group in the β, Δ or γ positions to at least one carbonyl group when separated by aromatic unsaturation according to the following structure: ##STR7## and wherein said carbonyl group is present as part of an aldo, keto, carboxyl, carboxy ester or amido group.
Claim 4
Dependent Claim
159 words
A pigment for use in corrosion inhibiting surface coatings which comprises a particulate substrate having deposit thereon a substantially water insoluble barium salt of an organic carbonyl group containing compound having 20-40 carbon atoms and having at least one acidic hydrogen said compound selected from the group consisting of an aliphatic and aromatic compound having at least one hydroxyl group in a β position to at least one carbonyl group and separated by saturated carbon linkages according to the following structure: ##STR5## at least one hydroxyl group in the γ position to at least one carbonyl group when separated by an ethylenically unsaturated linkage according to the following structure: ##STR6## and at least one hydroxyl group in the β, Δ or γ positions to at least one carbonyl group when separated by aromatic unsaturation according to the following structure: ##STR7## and wherein said carbonyl group is present as part of an aldo, keto, carboxyl, carboxy ester or amido group.
Claim 5
Dependent Claim
21 words
A composition of claim 2 wherein said organic carbonyl group containing compound has a molecular weight in the range of 73-350.
Claim 6
Dependent Claim
46 words
A composition of claim 2 wherein said carbonyl group containing compound is selected from the group consisting of citric acid, tartaric acid, salicylic acid, alizarine, quinizarine, chloranilic acid, alizarine carboxylic acid, glutaric acid, glycolic acid, glyceraldehyde, glyceric acid, malic acid, gluconic acid and β-hydroxy propanoic acid.
Claim 7
Dependent Claim
13 words
A composition of claim 2 having at least 0.1 percent by weight barium.
Claim 8
Dependent Claim
24 words
A composition of claim 2 wherein said inert substrate is selected from clay, silica, alumina, aluminum trihydrate, carbon, glass, inorganic pigments and organic resins.
Claim 9
Dependent Claim
23 words
A composition of claim 6 wherein said substrate is aluminum trihydrate and said salt is a mixture of barium citrate and barium alizarate.
Claim 10
Dependent Claim
30 words
A process for inhibiting corrosion upon a metal surface which comprises treating the metal surface with a coating composition containing a corrosion inhibiting amount of the pigment of claim 2.
Claim 11
Dependent Claim
31 words
A coating composition of claim 1 wherein said barium salt is a barium salt of a compound selected from the group consisting of alizarine, quinizarine, chloranilic acid and alizarine carboxylic acid.
Claim 12
Dependent Claim
152 words
A coating composition of claim 9 further including another and different substantially water insoluble barium salt of an organic carbonyl group containing compound having 2-40 carbon atoms and at least one acidic hydrogen said compound selected from the group consisting of an aliphatic and aromatic compound having at least one hydroxyl group in the β position to at least one carbonyl group when separated by saturated carbon linkages according to the following structure: ##STR8## at least one hydroxyl group in the γ position to at least one carbonyl group when separated by an ethylenically unsaturated carbon linkage according to the following structure: ##STR9## and at least one hydroxyl group in the β, Δ or γ positions to at least one carbonyl group when separated by aromatic unsaturation according to the following structure: ##STR10## and wherein said carbonyl group is present as part of an aldo, keto, carboxyl, carboxy ester or amido group.
Claim 13
Dependent Claim
134 words
A pigment composition of claim 4 further including another and different substantially water insoluble barium salt of an organic carbonyl group containing compound having 2-40 carbon atoms and having at least one hydroxyl group in the Greek letter β position to at least one carbonyl group when separated by saturated carbon linkages according the following structure: ##STR11## at least one hydroxyl group in the γ position to at least one carbonyl group when separated by an ethylenically unsaturated linkage according to the following structure: ##STR12## and at least one hydroxyl group in the β, Δ or γ position to at least one carbonyl group when separated by aromatic unsaturation according to the following structure: ##STR13## and wherein said carbonyl group is present as part of an aldo, keto, carboxyl, carboxy ester or amido group.
References Cited (Backward Citations)
US2420127A
Cited
US2285752A
Cited
US2392102A
Cited
US2409950A
Cited
US2479988A
Cited
US2509786A
Cited
US2573878A
Cited
US2776917A
Cited
US3072572A
Cited
US3007880A
Cited
US3598616A
Cited
US3405072A
Cited
US3421908A
Cited
US3585159A
Cited
US3699052A
Cited
US3726694A
Cited
US3874883A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-12-07 | 1985-06-08 | 1985-12-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-12-07 | 1989-06-08 | 1989-12-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-12-07 | 1993-06-08 | 1993-12-08 | $7700.00 | Window Closed / Lapsed |