2-Hydroxy,alkoxy,methylolbenzophenone intermediate compounds for the manufacture of improved copolymerizable ultraviolet light absorber compounds

Abstract

Abstract This invention relates to 2-hydroxy,alkoxy,methylolbenzophenone intermediate compounds for the manufacture of copolymerizable ultraviolet light absorber compounds. The intermediates have the formula: ##STR1## where R is alkyl C 1 -C 8 , and n is 1 or 2. The intermediate compounds herein are prepared by converting a 2-hydroxy,alkoxy,benzophenone to the corresponding methylol derivative by a formylation reaction. In the preferred embodiments of the invention, the alkoxy group is methoxy in the 4-position, and methylol is a monomethylol group located at the 3- or 5- position of the phenyl ring containing the hydroxy group. The intermediates of this invention can be transformed into useful copolymerizable ultraviolet light absorber compounds by monoesterification with an α,β-unsaturated dicarboxylic acid anhydride to produce the corresponding polymerizable half-ester compound, or by esterification with an acryloyl halide to form corresponding acrylate compound. Copolymerization of such compounds with vinyl monomers provide improved ultraviolet light stable copolymers for industrial and commercial applications.

Inventors

• 👤 Eugene S. Barabas
• 👤 Prakish Mallya
• 👤 Stanley J. Gromelski

Bibliographic Details