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US4302269A Expired / Lapsed US ⏱️ 0.0 years remaining

Process of forming a fiber reinforced, stampable thermoplastic laminate

Assignee: Honeywell International Inc
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Filing: 1979-10-10
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Granted: 1981-11-24
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Expires: 1999-10-10
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Abstract

Abstract Fiber reinforced thermoplastic laminate is formed by extruding first and second sheets of thermoplastic resin containing nonsiliceous fibers. A layer of nonsiliceous fibers is applied to one side of the first sheet. The second sheet is laminated to the first sheet and the layer of nonsiliceous fibers at a temperature ranging from the melting point of the thermoplastic resin to about 650° F.

Inventors

  • 👤 Albert H. Steinberg
  • 👤 Lowell G. Ward

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 07:36
CPC Classifications
B; B32; B32B; B32B37/00; B32B37/14; B32B37/15; B32B37/153; B29; B29C; B29C48/00; B29C48/022; B29C70/00; B29C70/02; B29C70/021; B29C70/025; B29C70/04; B29C70/28; B29C70/40; B29C70/50; B29C70/504; B29C48/03; B29C48/07; B29C48/08; B29K; B29K2105/00; B29K2105/06; B29K2105/12; Y; Y10; Y10T; Y10T428/00; Y10T428/25; Y10T428/252

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 208 words
A continuous process of forming a nonsiliceous fiber reinforced, stampable thermoplastic laminate consisting essentially of: (a) extruding a first sheet of thermoplastic resin containing about 5 to 35% by weight nonsiliceous fibers on an extruded basis; (b) embedding a layer of nonsiliceous fibers into one side of said first sheet; (c) extruding a second sheet of thermoplastic resin containing about 5 to 35% by weight of nonsiliceous fibers on an extruded basis; and (d) laminating, in a lamination zone, said second sheet to said first sheet and said layer of nonsiliceous fibers without substantially impairing the integrity of or rearranging said nonsiliceous fibers of said first and second sheets, wherein said lamination zone comprises a set of three heated rolls, said first sheet and said layer of nonsiliceous fibers being in the form of a prelaminate and being passed serially around the first and second of said heated rolls and then between the second and third rolls, advancing said second sheet to the nip formed by the second and third rolls and onto said prelaminate and laminating said prelaminate and said second sheet between said second and third rolls, the lamination being conducted at a temperature ranging from the melting point of the resin to about 650° F.
Claim 2
Dependent Claim 208 words
A continuous process of forming a nonsiliceous fiber reinforced, stampable thermoplastic laminate consisting essentially of: (a) extruding a first sheet of thermoplastic resin containing about 5 to 35% by weight nonsiliceous fibers on an extruded basis; (b) embedding a layer of nonsiliceous fibers into one side of said first sheet; (c) extruding a second sheet of thermoplastic resin containing about 5 to 35% by weight of nonsiliceous fibers on an extruded basis; and (d) laminating, in a lamination zone, said second sheet to said first sheet and said layer of nonsiliceous fibers without substantially impairing the integrity of or rearranging said nonsiliceous fibers of said first and second sheets, wherein said lamination zone comprises a set of three heated rolls, said first sheet and said layer of nonsiliceous fibers being in the form of a prelaminate and being passed serially around the first and second of said heated rolls and then between the second and third rolls, advancing said second sheet to the nip formed by the second and third rolls and onto said prelaminate and laminating said prelaminate and said second sheet between said second and third rolls, the lamination being conducted at a temperature ranging from the melting point of the resin to about 650° F.
Claim 3
Dependent Claim 15 words
The process of claim 1 wherein said first sheet further comprises a particulate mineral filler.
Claim 4
Dependent Claim 15 words
The process of claim 2 wherein said second sheet further comprises a particulate mineral filler.
Claim 5
Dependent Claim 61 words
The process of claim 3 wherein said thermoplastic resin is nylon 6 resin, said first sheet comprises, by weight basis of the extruded sheet, 20 to 30% nonsiliceous fiber, 5 to 35% mineral filler and 0.5 to 1.5% talc as a nucleating agent and said laminating step is conducted at a temperature in the range of about 450° to 550° F.
Claim 6
Dependent Claim 12 words
The process of claim 4 wherein said mineral filler comprises glass beads.
Claim 7
Dependent Claim 29 words
The process of claim 1 wherein said thermoplastic resin is nylon 6 and said second and third rolls are maintained at a maximum surface temperature of about 350° F.
Claim 8
Dependent Claim 22 words
The process of claim 6 wherein said first roll is maintained at a surface temperature below the melting point of said resin.
Claim 9
Dependent Claim 35 words
The process of claim 1 wherein said prelaminate is additionally heated during contact with said first and second rolls by means of an infrared heater before reaching said nip of said second and third rolls.
Claim 10
Dependent Claim 23 words
The process of claim 3 wherein each of said first and second sheets contains 0.1 to 1.0% by weight of a coupling aid.
Claim 11
Dependent Claim 31 words
The process of claim 1, wherein said nonsiliceous fibers of said first and second sheets are selected from the group consisting of nylon, polyester, carbon, graphite, boron, cellulose and mixtures thereof.
Claim 12
Dependent Claim 29 words
The process of claim 1, wherein said layer of nonsiliceous fibers is composed of fibers from the group consisting of nylon, polyester, carbon, graphite, boron, cellulose and mixtures thereof.
Claim 13
Dependent Claim 24 words
The process of claim 1 wherein each of said first and second sheets has a fiber content 50-80% by weight of which is siliceous.
Claim 14
Dependent Claim 30 words
The process of claim 1, wherein said layer of nonsiliceous fibers is comprised of a plurality of mats, at least one of which contains about 50-80% by weight siliceous fiber.
Claim 15
Dependent Claim 146 words
A continuous process of forming a nonsiliceous fiber reinforced, stampable nylon 6 laminate consisting essentially of the steps of: (a) extruding a first sheet of nylon 6 resin containing by weight on an extruded basis about 5 to 35% nonsiliceous fibers, 5 to 35% mineral filler and 0.5 to 1.5% talc as a nucleating agent; (b) embedding a layer of nonsiliceous fibers into one side of said first sheet; (c) extruding a second sheet of thermoplastic resin containing about 5 to 35% by weight of nonsiliceous fibers on an extruded basis, and further comprising a particulate mineral filler; (d) laminating said second sheet to said first sheet and said layer of nonsiliceous fibers without substantially impairing the integrity of or rearranging said nonsiliceous fibers of said first and second sheets, the lamination being conducted in a temperature range of from about 450° F. to 550° F.
Claim 16
Dependent Claim 146 words
A continuous process of forming a nonsiliceous fiber reinforced, stampable nylon 6 laminate consisting essentially of the steps of: (a) extruding a first sheet of nylon 6 resin containing by weight on an extruded basis about 5 to 35% nonsiliceous fibers, 5 to 35% mineral filler and 0.5 to 1.5% talc as a nucleating agent; (b) embedding a layer of nonsiliceous fibers into one side of said first sheet; (c) extruding a second sheet of thermoplastic resin containing about 5 to 35% by weight of nonsiliceous fibers on an extruded basis, and further comprising a particulate mineral filler; (d) laminating said second sheet to said first sheet and said layer of nonsiliceous fibers without substantially impairing the integrity of or rearranging said nonsiliceous fibers of said first and second sheets, the lamination being conducted in a temperature range of from about 450° F. to 550° F.
Claim 17
Dependent Claim 12 words
The process of claim 14 wherein said mineral filler comprises glass beads.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-11-23 1985-05-25 1985-11-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-11-23 1989-05-25 1989-11-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-11-23 1993-05-25 1993-11-24 $7700.00 Window Closed / Lapsed

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