Reaction products of a polyglycidyl ether of a polyphenol and an amino acid and aqueous solubilized products therefrom

Claim 2

A curable, carboxyl-containing precondensate prepared by reacting at a temperature from about 200° to about 350° F. (1) a polyglycidyl ether of a polyphenol with (2) an amino-substituted aromatic carboxylic acid selected from the class consisting of anthranilic acid, p-aminobenzoic acid, m-aminobenzoic acid, 3-amino-p-toluic acid, 3-amino-salicylic acid, 3-amino-4-methoxybenzoic acid, 6-amino-m-toluic acid, 3-amino-4-chlorobenzoic acid, 2-amino-5-nitrobenzoic acid, 2-nitro-5-aminobenzoic acid and 5-amino-isophthalic acid; said precondensate having an acid number of at least 15.

Claim 3

The precondensate of claim 1 wherein the polyglycidyl ether of a polyphenol is a glycidyl polyether of 2,2-bis(4-hydroxyphenyl)propane.

Claim 4

The precondensate of claim 1 wherein the amino-substituted aromatic carboxylic acid is selected from the class consisting of anthranilic acid, p-aminobenzoic acid and m-aminobenzoic acid.

Claim 5

The precondensate of claim 3 wherein the amino-substituted aromatic carboxylic acid is p-aminobenzoic acid.

Claim 6

A curable composition comprising the polycondensate of claim 1 and a polyamide.

Claim 7

An anionic aqueous composition comprising water and an at least partially base neutralized reaction product of: (a) a polyglycidyl ether of a polyphenol having a 1,2-epoxy equivalency greater than 1.0; and (b) an aromatic amino acid selected from the class consisting of an anthranilic acid, p-amino benzoic acid, m-amino benzoic acid, 3-amino-p-toluic acid, 3-amino-4-methoxy benzoic acid, 6-amino-m-toluic acid, 3-amino-4-chloro-benzoic acid, 2-amino-5-nitro benzoic acid, 2-nitro-5-amino benzoic acid, 5-amino isophthalic acid; said reaction product having unreacted carboxylic acid groups which are neutralized with base to form anionic salt groups.

Claim 8

An anionic aqueous composition comprising water and an at least partially base neutralized reaction product of: (a) a polyglycidyl ether of a polyphenol having a 1,2-epoxy equivalency greater than 1.0; and (b) an aromatic amino acid selected from the class consisting of an anthranilic acid, p-amino benzoic acid, m-amino benzoic acid, 3-amino-p-toluic acid, 3-amino-4-methoxy benzoic acid, 6-amino-m-toluic acid, 3-amino-4-chloro-benzoic acid, 2-amino-5-nitro benzoic acid, 2-nitro-5-amino benzoic acid, 5-amino isophthalic acid; said reaction product having unreacted carboxylic acid groups which are neutralized with base to form anionic salt groups.

Claim 9

The aqueous composition of claim 6 wherein the equivalent ratio of epoxy groups in said polyglycidyl ether to amine groups in said amino acid is between 1:0.20 and 1:1.25.

Claim 10

The aqueous composition of claim 6 wherein said reaction product is at least partially neutralized with a volatile base.

Claim 11

The aqueous composition of claim 8 wherein said base is an amine.

Claim 12

The aqueous composition of claim 6 wherein said polyphenol is bisphenol A.

Claim 13

The aqueous composition of claim 6 wherein said amino acid is anthranilic acid.

Claim 14

The aqueous composition of claim 6 wherein said amino acid is p-aminobenzoic acid.

Claim 15

The aqueous composition of claim 6 wherein said amino acid is m-aminobenzoic acid.

Claim 16

An anionic aqueous composition comprising water and: (a) an at least partially base neutralized reaction product of: (1) a polyglycidyl ether of a polyphenol having a 1,2-epoxy equivalency of greater than 1.0; and (2) an aromatic amino acid selected from the class consisting of an anthranilic acid, p-amino benzoic acid, m-amino benzoic acid, 3-amino-p-toluic acid, 3-amino-4-methoxy benzoic acid, 6-amino-m-toluic acid, 3-amino-4-chloro-benzoic acid, 2-amino-5-nitro benzoic acid, 2-nitro-5-amino benzoic acid, 5-amino isophthalic acid; said reaction product having unreacted carboxylic acid groups which are neutralizable with base to form anionic salt groups; and (b) a resin selected from the group consisting of hydrocarbon resins, water-soluble acrylic resins, acrylic polymer emulsions, aqueous dispersions of amide-containing acrylic interpolymers, or combinations thereof.

Claim 17

An anionic aqueous composition comprising water and: (a) an at least partially base neutralized reaction product of: (1) a polyglycidyl ether of a polyphenol having a 1,2-epoxy equivalency of greater than 1.0; and (2) an aromatic amino acid selected from the class consisting of an anthranilic acid, p-amino benzoic acid, m-amino benzoic acid, 3-amino-p-toluic acid, 3-amino-4-methoxy benzoic acid, 6-amino-m-toluic acid, 3-amino-4-chloro-benzoic acid, 2-amino-5-nitro benzoic acid, 2-nitro-5-amino benzoic acid, 5-amino isophthalic acid; said reaction product having unreacted carboxylic acid groups which are neutralizable with base to form anionic salt groups; and (b) a resin selected from the group consisting of hydrocarbon resins, water-soluble acrylic resins, acrylic polymer emulsions, aqueous dispersions of amide-containing acrylic interpolymers, or combinations thereof.

Claim 18

The aqueous composition of claim 14 further containing a curing agent.

Claim 19

The aqueous composition of claim 14 wherein said composition based on total weight of (a) and (b) contains from about 5 to about 95 percent by weight of (a) and from about 95 to about 5 percent by weight of (b).

Claim 20

The aqueous composition of claim 14 wherein said resin is an acrylic polymer emulsion.

Claim 21

The aqueous composition of claim 14 wherein said resin is an aqueous dispersion of an amide-containing acrylic interpolymer.

Claim 22

The aqueous composition of claim 14 further containing a pigment or pigments.