Novel disubstituted dichlorosilane and method for producing same

Claim 2

A disubstituted dichlorosilane having the general formula ##STR4## wherein R' is an alkyl group having 2˜3 carbon atoms and R" is an alkyl group having 8˜20 carbon atoms, or R' is an alkyl group having 4˜20 carbon atoms and R" is an alkyl group having 5˜20 carbon atoms which is different from R', or R' is phenethyl group and R" is cyclohexyl group.

Claim 3

A disubstituted dichlorosilane having the general formula ##STR5## defined in claim 1 wherein R' is alkyl group having 2 or 3 carbon atoms and R" is alkyl group has 8˜20 carbon atoms.

Claim 4

A disubstituted dichlorosilane having the general formula ##STR6## defined in claim 1 wherein R' and R" are different alkyl groups and R' has 4˜20 carbon atoms and R" has 5˜20 carbon atoms.

Claim 5

A disubstituted dichlorosilane defined in claims 3 wherein the difference of number of carbon atoms of R' and R" is 6 or more.

Claim 6

A disubstituted dichlorosilane defined in claim 1 having the general formula ##STR7##

Claim 7

Disubstituted dichlorosilanes as set forth in claim 1 which are produced by reacting dichlorosilane with an α-olefin or styrene in the presence of a homogenous complex catalyst selected from the group consisting of RhH(PPh 3 ) 4 , RhCl(CO)(PPh 3 ) 3 , RhCl(PPh 3 ) 3 , RuCl 2 (PPH 3 ) 3 , RuHCl(PPh 3 ) 3 [C 6 H 6 ], RuH 3 (PPh 3 ) 3 [Si(OCH 3 ) 3 ], RuH 3 (PPh 3 ) 3 [Si(OCH 3 ) 2 Pt], RuH(PPh 3 ) 3 [Si(C 2 H 5 ) 2 Cl], RuH 2 (PPh 3 ) 4 , NiCl 2 (PPh 3 ) 2 , PdCl 2 (PPh 3 ) 2 , and Pt (PPh 3 ) 4 , wherein Ph stands for a phenyl group, to form a monosubstituted dichlorosilane having the general formula R°HSiCl 2 (wherein R° is an alkyl having 2-20 carbon atoms, or phenethyl) and reacting said monosubstituted dichlorosilane with an α-olefin having carbon atoms of 2 to 20 (but different from the number of carbon atoms of R°) or cyclohexene (excepting the case where R° is alkyl) in the presence of chloroplatinic acid at a temperature of 30°-150° C.

Claim 8

Disubstituted dichlorosilanes having the general formula ##STR8## wherein R' is an alkyl group having 2 or 3 carbon atoms and R" is alkyl group having 8-20 carbon atoms which are produced by reacting dichlorosilane and ethylene or propylene in the presence of the catalyst of claim 6 at a temperature of 30°-200° C. for 0.1 to 60 hours to produce ethyldichlorosilane or propydichlorosilane compound and reacting said monosubstituted dichlorosilane with an α-olefin compound having 8-20 carbon atoms.

Claim 9

Disubstituted dichlorosilanes having the general formula ##STR9## wherein R' is an alkyl group having 2 or 3 carbon atoms and R" is an alkyl group having 8-20 carbon atoms which are produced by reacting dichlorosilane and an α-olefin compound having 8-20 carbon atoms in the presence of the catalyst of claim 6 at a temperature of 30°-200° C. for 0.1-60 hours to produce monoalkyldichlorosilane and said monosubstituted dichlorosilane is reacted with ethylene or propylene.

Claim 10

Disubstituted dichlorosilanes having the general formula ##STR10## wherein R' and R" are different alkyl groups and R' has 4-20 carbon atoms and R" has 5-20 carbon atoms which are produced by reacting a dichlorosilane with an α-olefin compound having 4-20 carbon atoms in the presence of the catalyst of claim 6 at a temperature of 30°-200° C. for 0.1-60 hours to produce a monosubstituted dichlorosilane compound with an α-olefin compound having 5 to 20 carbon atoms, but different numbers of carbon atoms from said monoalkyl substitute.

Claim 11

Disubstituted dichlorosilanes having the general formula ##STR11## wherein R' and R" are different alkyl groups and R' has 4-20 carbon atoms and R" has 5-20 carbon atoms produced by reacting a dichlorosilane and an α-olefin compound having 5-20 carbon atoms in the presence of the catalyst of claim 6 at a temperature of 30°-200° C. for 0.1-60 hours to produce a monoalkyldichlorosilane having 5 to 20 carbon atoms and the resulting monoalkyldichlorosilane is reacted with butene.

Claim 12

Cyclohexylphenethydichlorosilane having the general formula ##STR12## which is produced by reacting a dichlorosilane and styrene in the presence of the catalyst of claim 6 at a temperature of 30°-150° C. for 0.1-60 hours to produce a monophenethyldichlorosilane and reacting said monosubstitute with cyclohexene at a temperature of 80°-150° C. for 5-20 hours.