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US4297440A Expired / Lapsed US ⏱️ 0.0 years remaining

Color photographic light-sensitive element

Assignee: Fujifilm Holdings Corp
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Filing: 1980-11-25
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Granted: 1981-10-27
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Expires: 2000-11-25
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Abstract

Abstract A color photographic light-sensitive element is described comprising a support having thereon a silver halide emulsion layer containing therein a 3-anilino-5-pyrazolone magenta color-forming coupler represented by formula (I) <IMAGE> (I) wherein X represents a halogen atom or an alkoxy group; Ar represents an aryl group; R1 represents hydrogen, a halogen atom, an alkyl group, an alkoxy group or an alkylthio group; Y represents a non-metallic atomic group forming a 5-membered or 6-membered ring together with the <IMAGE> group, except that Y does not include a carbonyl group; and Z represents hydrogen or a coupling-off group. The magenta color images obtained after color development processing of the color photographic light-sensitive element have an excellent light-fastness, and the formation of yellow stain in the unexposed areas thereof is prevented.

Inventors

  • 👤 Kozo Aoki
  • 👤 Satoru Sawada
  • 👤 Yoshiharu Yabuki
  • 👤 Nobuo Furutachi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 07:11
CPC Classifications
C; C07; C07D; C07D207/00; C07D207/02; C07D207/18; C07D207/22; C07D207/24; C07D207/26; C07D207/263; C07D207/27; C07D231/00; C07D231/02; C07D231/10; C07D231/14; C07D231/38; G; G03; G03C; G03C7/00; G03C7/30; G03C7/32; G03C7/36; G03C7/38; G03C7/384

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 104 words
A color photographic light-sensitive element comprising a support having thereon a silver halide emulsion layer containing therein a 3-anilino-5-pyrazolone magenta color forming coupler represented by formula (I) ##STR14## is present at the 4- or 5-position of the anilino group; X represents a halogen atom or an alkoxy group; Ar represents an aryl group; R 1 represents hydrogen, a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; Y represents a non-metallic atomic group forming a 5-membered or 6-membered ring together with the ##STR15## group, except that Y does not include a carbonyl group; and Z represents hydrogen or a coupling-off group.
Claim 2
Dependent Claim 104 words
A color photographic light-sensitive element comprising a support having thereon a silver halide emulsion layer containing therein a 3-anilino-5-pyrazolone magenta color forming coupler represented by formula (I) ##STR14## is present at the 4- or 5-position of the anilino group; X represents a halogen atom or an alkoxy group; Ar represents an aryl group; R 1 represents hydrogen, a halogen atom, an alkyl group, an alkoxy group, or an alkylthio group; Y represents a non-metallic atomic group forming a 5-membered or 6-membered ring together with the ##STR15## group, except that Y does not include a carbonyl group; and Z represents hydrogen or a coupling-off group.
Claim 3
Dependent Claim 74 words
A color photographic light-sensitive element as in claim 1, wherein X represents a chlorine atom, a bromine atom, or an alkoxy group having from 1 to 22 carbon atoms, which may be substituted with one or more substituents selected from a halogen atom, a nitro group, a cyano group, an alkoxy group, an aryloxy group, an alkylcarbonyl group, an alkoxycarbonyl group, an acylamine group, a sulfonamido group, a hydroxy group, and a mercapto group.
Claim 4
Dependent Claim 13 words
A color photographic light-sensitive element as in claim 1, wherein Z represents hydrogen.
Claim 5
Dependent Claim 15 words
A color photographic light-sensitive element as in claim 1, wherein Z represents a coupling-off group.
Claim 6
Dependent Claim 81 words
A color photographic light-sensitive element as in claim 1, wherein Z represents hydrogen, a thiocyano group, an acyloxy group, an aryloxy group, an alkoxy group, a halogen atom, an arylazo group, an aryltriazolyl group, an alkylthio group, an arylthio group, a heterocyclic thio group, an aralkoxycarbonyloxy group, an alkoxycarbonyloxy group, an aryloxycarbonyloxy group, a cycloalkylthio group, a cycloalkoxy group, an imido group, an imidazolyl group, a pyrazolyl group, a triazolyl group, an acylamino group, a sulfonamido group or a cycloamino group.
Claim 7
Dependent Claim 66 words
A color photographic light-sensitive element as in claim 1, wherein Ar represents a phenyl group which may be substituted with one or more substituents selected from a halogen atom, a cyano group, an alkyl group, an alkoxy group, an acylamino group, a sulfamoyl group, a sulfonamido group, an alkoxycarbonyl group, an alkylthio group, an alkylsulfonyl group, a carbamoyl group, a nitro group and a trifluoromethyl group.
Claim 8
Dependent Claim 50 words
A color photographic light-sensitive element as in claim 1, wherein the nucleus represented by the formula of ##STR16## is selected from the group consisting of ##STR17## wherein R 2 represents hydrogen, an alkyl group, an alkylcarbonyl group, an alkoxycarbonyl group, an alkylsulfonyl group, an N-alkylcarbamoyl group, or an N-arylcarbamoyl group.
Claim 9
Dependent Claim 351 words
A color photographic light-sensitive element as in claim 1, wherein said 5- or 6-membered ring may be substituted with one or more substituents selected from a straight chain or branched chain alkyl group having from 1 to 22 carbon atoms, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, an aralkyl group having from 7 to 32 carbon atoms, a carboxy group, an alkoxy group having from 1 to 22 carbon atoms, a halogen atom, a cyano group, an aryl group having from 6 to 32 carbon atoms, an alkylcarbonyl group having from 2 to 22 carbon atoms, an arylcarbonyl group having from 7 to 32 carbon atoms, an alkoxycarbonyl group having from 2 to 22 carbon atoms, an aryloxycarbonyl group having from 7 to 32 carbon atoms, an alkylcarbonyloxy group having from 2 to 22 carbon atoms, an arylcarbonyloxy group having from 7 to 32 carbon atoms, an N-alkylsulfamoyl group having from 1 to 36 carbon atoms, an N,N-dialkylsulfamoyl group, an N-arylsulfamoyl group having from 6 to 32 carbon atoms, an N-aryl-N-alkylsulfamoyl group, an N-alkylcarbamoyl group having from 1 to 36 carbon atoms, an N,N-dialkylcarbamoyl group, an N-arylcarbamoyl group having from 6 to 32 carbon atoms, an N-aryl-N-alkylcarbamoyl group, an alkaneamido group having from 2 to 22 carbon atoms, an aromatic cyclic amido group having from 7 to 32 carbon atoms, a diacylamino group having from 3 to 32 carbon atoms, an N-alkylureido group having from 1 to 22 carbon atoms, an N,N-dialkylureido group having from 2 to 36 carbon atoms, an N-alkanesulfonamido group having from 1 to 22 carbon atoms, an N-aromatic cyclic sulfonamido group having from 6 to 32 carbon atoms, an alkylthio group having from 1 to 22 carbon atoms, an N-alkylamino group having from 1 to 32 carbon atoms, an N,N-dialkylamino group, an alkoxycarbonylamino group having from 2 to 22 carbon atoms, an aryloxycarbonylamino group having from 7 to 32 carbon atoms, an alkylsulfonyloxy group having from 1 to 22 carbon atoms, an arylsulfonyloxy group having from 6 to 32 carbon atoms, an alkylsulfonyl group having from 1 to 22 carbon atoms, and a hydroxy group.
Claim 10
Dependent Claim 104 words
A color photographic light-sensitive element as in claim 1, wherein said magenta color-forming coupler is represented by formula (II) ##STR18## wherein Z represents hydrogen or a coupling-off group; the lactam ring is present at the 4- or 5-position of the anilino group; R 3 represents hydrogen, an alkyl group, an alkenyl group, an aralkyl group, an alkoxy group, an alkylthio group, an alkylsulfonyl group, an alkylcarbonyl group, or an alkylcarbamoyl group; and R 4 represents hydrogen, a chlorine atom, a cyano group, an alkaneamido group, an alkanesulfonamido group, an alkoxycarbonyl group, an alkylcarbamoyl group, an alkoxycarbonylamino group, an alkylsulfonyl group or an alkylthio group.
Claim 11
Dependent Claim 22 words
A color photographic ilght-sensitive element as in claim 1, wherein said silver halide emulsion layer is a green-sensitive silver halide emulsion layer.
Claim 12
Dependent Claim 52 words
A color photographic light-sensitive element as in claim 1, wherein said silver halide emulsion layer containing said magenta color-forming coupler represented by formula (I) is a green-sensitive silver halide emulsion layer, and said color photographic light-sensitive element further includes a red-sensitive silver halide emulsion layer and a blue-sensitive silver halide emulsion layer.
Claim 13
Dependent Claim 68 words
A color photographic light-sensitive element as in claim 1, wherein said silver halide emulsion layer containing said magenta color-forming coupler represented by formula (I) is a green-sensitive silver halide emulsion layer, and said color photographic light-sensitive element additionally includes a red-sensitive silver halide emulsion layer containing a phenolic or naphtholic cyan color-forming coupler, and a blue-sensitive silver halide emulsion layer containing a benzoylacetanilide or pivaloylacetanilide yellow color-forming coupler.

References Cited (Backward Citations)

US2311082A Cited
US3684514A Cited
US3928044A Cited
US3935015A Cited
US4220470A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-10-26 1985-04-27 1985-10-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-10-26 1989-04-27 1989-10-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-10-26 1993-04-27 1993-10-27 $7700.00 Window Closed / Lapsed

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