US4297245A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Catalyst for the preparation of methane
Assignee: Texaco Inc
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Filing: 1977-11-21
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Granted: 1981-10-27
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Expires: 1997-11-21
Abstract
Abstract In accordance with certain of its aspects, this invention relates to a finely-divided, high surface area supported catalyst containing a metal of the platinum-palladium group and a metal of the iron group wherein each of said metals is substantially uniformly distributed throughout the body of said supported catalyst--and to the use of this catalyst to prepare methane by the reaction of hydrogen and hydrocarbons.
Inventors
- 👤 Burton H. Bartley
- 👤 John H. Estes
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 23:17
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/70; B01J23/89; C; C07; C07C; C07C4/00; C07C2523/00; C07C2523/38; C07C2523/40; C07C2523/42; C07C2523/70; C07C2523/74; C07C2523/745; C07C2523/89
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
78 words
A finely-divided, high surface area supported catalyst, particularly characterized by its ability to catalyze the production of methane by the reaction of hydrogen and a hydrocarbon containing at least two carbon atoms at a temperature of 300° C.-800° C. which consists essentially of a support, a metal of the platinum-palladium group and a metal of the iron group, each of said platinum-palladium group metal and said iron group metal being substantially distributed throughout the body of the catalyst.
Claim 2
Dependent Claim
78 words
A finely-divided, high surface area supported catalyst, particularly characterized by its ability to catalyze the production of methane by the reaction of hydrogen and a hydrocarbon containing at least two carbon atoms at a temperature of 300° C.-800° C. which consists essentially of a support, a metal of the platinum-palladium group and a metal of the iron group, each of said platinum-palladium group metal and said iron group metal being substantially distributed throughout the body of the catalyst.
Claim 3
Dependent Claim
100 words
A finely-divided, high surface area catalyst, particularly characterized by its ability to catalyze the production of methane by the reaction of hydrogen and a hydrocarbon containing at least two carbon atoms at a temperature of 300° C.-800° C. as claimed in claim 1 which consists essentially of a finely-divided, high surface area catalyst support, and deposited thereon 0.1-10 parts by weight of a metal of the platinum-palladium group and 1-30 parts by weight of a metal of the iron group, each of said platinum-palladium group metal and said iron group metal being substantially distributed throughout the body of the catalyst.
Claim 4
Dependent Claim
84 words
A finely-divided, high surface area supported catalyst, particularly characterized by its ability to catalyze the production of methane by the reaction of hydrogen and a hydrocarbon containing at least two carbon atoms at a temperature of 300° C.-800° C. as claimed in claim 1 wherein said metal of the iron group is deposited on said catalyst support bearing said metal of the platinum-palladium group, each of said platinum-palladium group metal and said iron group metal being substantially distributed throughout the body of the catalyst.
Claim 5
Dependent Claim
97 words
A finely-divided, high surface area catalyst, particularly characterized by its ability to catalyze the production of methane by the reaction of hydrogen and a hydrocarbon containing at least two carbon atoms at a temperature of 300° C.-800° C. as claimed in claim 1 which consists essentially of a finely-divided, high surface area silica catalyst support, 0.1-10 parts by weight of platinum deposited thereon, and 1-30 parts by weight of iron deposited on said catalyst support bearing platinum, each of said platinum-palladium group metal and said iron group metal being substantially distributed throughout the body of the catalyst.
Claim 6
Dependent Claim
94 words
A finely divided high surface area catalyst, particularly characterized by its ability to convert lower alkane hydrocarbons containing at least two carbon atoms, to effluent gas containing methane in amounts more than 50% by weight, the metal content containing essentially of (a) 0.01%-99.9% of total catalytic metal content of a metal of the platinum-palladium group and (b) 0.01%-99.9% of total catalytic metal content of iron, each of said platinum-palladium group metal and said iron being substantially distributed throughout the body of the catalyst, the mole ratio of iron to platinum-palladium group metal being 10-80:1.
Claim 7
Dependent Claim
94 words
A finely divided high surface area catalyst, particularly characterized by its ability to convert lower alkane hydrocarbons containing at least two carbon atoms, to effluent gas containing methane in amounts more than 50% by weight, the metal content containing essentially of (a) 0.01%-99.9% of total catalytic metal content of a metal of the platinum-palladium group and (b) 0.01%-99.9% of total catalytic metal content of iron, each of said platinum-palladium group metal and said iron being substantially distributed throughout the body of the catalyst, the mole ratio of iron to platinum-palladium group metal being 10-80:1.
Claim 8
Independent Claim
161 words
The method of preparing a finely-divided, high surface area supported catalyst, particularly characterized by its ability to catalyze the production of methane by the reaction of hydrogen and a hydrocarbon containing at least two carbon atoms at a temperature of 300° C.-800° C. which consists essentially of contacting finely-divided, high surface area catalyst support with a solution of a soluble compound of a metal of the platinum-palladium group, drying said catalyst support bearing said metal of the platinum-palladium group, calcining said catalyst support bearing said metal of the platinum-palladium group, contacting said catalyst support with a solution of a soluble compound of a metal of the iron group, drying said catalyst support bearing said metal of the iron group, and calcining said catalyst support bearing said metal of the iron group thereby forming a finely-divided high surface area catalyst in which each of the platinum-palladium group metal and the iron group metal is substantially distributed throughout the body of the catalyst.
Claim 9
Independent Claim
161 words
The method of preparing a finely-divided, high surface area supported catalyst, particularly characterized by its ability to catalyze the production of methane by the reaction of hydrogen and a hydrocarbon containing at least two carbon atoms at a temperature of 300° C.-800° C. which consists essentially of contacting finely-divided, high surface area catalyst support with a solution of a soluble compound of a metal of the platinum-palladium group, drying said catalyst support bearing said metal of the platinum-palladium group, calcining said catalyst support bearing said metal of the platinum-palladium group, contacting said catalyst support with a solution of a soluble compound of a metal of the iron group, drying said catalyst support bearing said metal of the iron group, and calcining said catalyst support bearing said metal of the iron group thereby forming a finely-divided high surface area catalyst in which each of the platinum-palladium group metal and the iron group metal is substantially distributed throughout the body of the catalyst.
Claim 10
Independent Claim
182 words
The method of preparing a finely-divided, high surface area supported catalyst, particularly characterized by its ability to catalyze the production of methane by the reaction of hydrogen and a hydrocarbon containing at least two carbon atoms at a temperature of 300° C.-800° C. which consists essentially of contacting finely-divided, high surface area catalyst support with a solution of a soluble compound of a metal of the iron group, drying said catalyst support bearing said metal of the iron group, calcining said catalyst support bearing said metal of the iron group, contacting said catalyst support bearing said metal of the iron group with a solution of a soluble compound of a metal of the platinum-palladium group, drying said catalyst support bearing said metal of the iron group and said metal of the platinum-palladium group, and calcining said catalyst support bearing said metal of the iron group and said metal of the platinum-palladium group thereby forming a finely-divided high surface area catalyst in which each of the platinum-palladium group metal and the iron group metal is substantially distributed throughout the body of the catalyst.
Claim 11
Independent Claim
182 words
The method of preparing a finely-divided, high surface area supported catalyst, particularly characterized by its ability to catalyze the production of methane by the reaction of hydrogen and a hydrocarbon containing at least two carbon atoms at a temperature of 300° C.-800° C. which consists essentially of contacting finely-divided, high surface area catalyst support with a solution of a soluble compound of a metal of the iron group, drying said catalyst support bearing said metal of the iron group, calcining said catalyst support bearing said metal of the iron group, contacting said catalyst support bearing said metal of the iron group with a solution of a soluble compound of a metal of the platinum-palladium group, drying said catalyst support bearing said metal of the iron group and said metal of the platinum-palladium group, and calcining said catalyst support bearing said metal of the iron group and said metal of the platinum-palladium group thereby forming a finely-divided high surface area catalyst in which each of the platinum-palladium group metal and the iron group metal is substantially distributed throughout the body of the catalyst.
References Cited (Backward Citations)
US2422671A
Cited
US2911357A
Cited
US3025247A
Cited
US3143511A
Cited
US3689254A
Cited
US3562346A
Cited
US3759823A
Cited
US3644198A
Cited
US3825487A
Cited
US3988334A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-10-26 | 1985-04-27 | 1985-10-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-10-26 | 1989-04-27 | 1989-10-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-10-26 | 1993-04-27 | 1993-10-27 | $7700.00 | Window Closed / Lapsed |