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US4296009A Expired / Lapsed US ⏱️ 0.0 years remaining

Wax-containing unsaturated polyester laminating composition with aromatic tertiary amine

Assignee: AOC LLC
•
Filing: 1980-01-07
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Granted: 1981-10-20
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Expires: 2000-01-07
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Abstract

Abstract Failure of free radical catalyzed unsaturated polyester laminating compositions containing wax for suppression of styrene evaporation, but not more than about 10 weight percent of non-reinforcing filler, to develop interlaminar adhesion as great as similar compositions without wax can be at least partially overcome by incorporating at least about 0.1 weight percent of a tertiary monoamine having a single aromatic group and two alkyl or hydroxyalkyl groups on the amino nitrogen.

Inventors

  • 👤 Edward J. Kerle
  • 👤 Terry R. Beaver

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 05:21
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/17; C08K5/18

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 118 words
In a laminating composition comprising (i) an ethylenically unsaturated polyester polymer, (ii) an ethylenically unsaturated curing agent comprising styrene, (iii) a free radical catalyst for the cure reaction of said polyester polymer and said curing agent and (iv) paraffin wax, the improvement for enhancing interlaminar adhesion in cured laminates prepared therefrom which comprises said composition (v) further comprising at least about 0.1 percent by weight of a tertiary monoamine having a single aromatic group and two alkyl or hydroxy alkyl groups joined to the amino nitrogen atom thereof and (vi) containing no more than about 10 percent by weight of non-reinforcing filler, where both percentages are based on the total weight of said polymer and said curing agent.
Claim 2
Dependent Claim 118 words
In a laminating composition comprising (i) an ethylenically unsaturated polyester polymer, (ii) an ethylenically unsaturated curing agent comprising styrene, (iii) a free radical catalyst for the cure reaction of said polyester polymer and said curing agent and (iv) paraffin wax, the improvement for enhancing interlaminar adhesion in cured laminates prepared therefrom which comprises said composition (v) further comprising at least about 0.1 percent by weight of a tertiary monoamine having a single aromatic group and two alkyl or hydroxy alkyl groups joined to the amino nitrogen atom thereof and (vi) containing no more than about 10 percent by weight of non-reinforcing filler, where both percentages are based on the total weight of said polymer and said curing agent.
Claim 3
Dependent Claim 12 words
A composition according to claim 1 wherein said aromatic group is phenyl.
Claim 4
Dependent Claim 14 words
A composition according to claim 2 wherein said amine is N,N-dimethylaniline, N,N-diethylaniline or N-methyl-N-ethylaniline.

References Cited (Backward Citations)

US3367994A Cited
DE2705966A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-10-19 1985-04-20 1985-10-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-10-19 1989-04-20 1989-10-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-10-19 1993-04-20 1993-10-20 $7700.00 Window Closed / Lapsed

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