US4294590A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Removal of undesired gaseous components from hot waste gases
Assignee: Linde GmbH
•
Filing: 1979-11-09
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Granted: 1981-10-13
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Expires: 1999-11-09
Abstract
Abstract For removing undesired gaseous components, e.g., SO 2 , from hot combustion gases (from carbonaceous fuels) by scrubbing with a regenerable absorbent, the scrubbing is conducted with a liquid physical absorbent, e.g., dimethylformamide, at a temperature less than 0° C. The cooling requirements of the scrubbing process are supplied by an absorption type refrigeration unit. The hot combustion gases, prior to scrubbing, are cooled in indirect heat exchange, first with air in an upper temperature range cooling zone, and then with cold combustion gas purified by the scrubbing in a lower temperature range cooling zone. The resultant heated air is used in part as (a) air for combustion and in part as (b) an energy source for the operation of the refrigeration unit. A heat pump may be used to supplement the absorption type refrigeration unit. Other aspects include, for example, special regenerator design and absorbent regeneration steps.
Inventors
- 👤 Gerhard Linde
- 👤 Peter Haeussinger
- 👤 Claus Schliebener
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 21:11
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; B01D53/507; B01D53/14; B01D53/1456; B01D53/1481; C; C01; C01B; C01B17/00; C01B17/48; C01B17/50; C01B17/60; C01B17/69; C01B17/90; Y; Y02; Y02P; Y02P20/00; Y02P20/10; Y02P20/129
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
135 words
In a process for removing undesired gaseous components from hot combustion gases by scrubbing with a regenerable absorbent, the improvement which comprises: conducting the scrubbing with a liquid physical absorbent at a temperature less than 0° C. and supplying cooling requirements of the scrubbing process by means of an absorption-type refrigeration unit, cooling the combustion gases prior to scrubbing, in indirect heat exchange with gas streams to be heated, the indirect heat exchange being performed in an upper temperature range and a subsequent lower temperature range and using air as said gas stream to be heated in the upper temperature range of the indirect heat exchange, resultant heated air being used in part as (a) preheated air of combustion and in part as (b) an energy source for the operation of the absorption-type refrigeration unit.
Claim 2
Dependent Claim
135 words
In a process for removing undesired gaseous components from hot combustion gases by scrubbing with a regenerable absorbent, the improvement which comprises: conducting the scrubbing with a liquid physical absorbent at a temperature less than 0° C. and supplying cooling requirements of the scrubbing process by means of an absorption-type refrigeration unit, cooling the combustion gases prior to scrubbing, in indirect heat exchange with gas streams to be heated, the indirect heat exchange being performed in an upper temperature range and a subsequent lower temperature range and using air as said gas stream to be heated in the upper temperature range of the indirect heat exchange, resultant heated air being used in part as (a) preheated air of combustion and in part as (b) an energy source for the operation of the absorption-type refrigeration unit.
Claim 3
Dependent Claim
27 words
A process according to claim 1, wherein cold combustion gas purified by the scrubbing is used in the lower temperature range as said stream to be heated.
Claim 4
Dependent Claim
32 words
A process according to claim 2, wherein the temperature boundary between the upper and lower temperature range zones is above the temperature of the air used for cooling the hot combustion gases.
Claim 5
Dependent Claim
35 words
A process according to claim 2, wherein the heated air following its use as an energy source for the operation of the absorption type refrigeration unit is mixed with the resultant purified, heated waste gas.
Claim 6
Dependent Claim
19 words
A process according to claim 2, the heat exchange for cooling the combustion gas taking place in reversible regenerators.
Claim 7
Dependent Claim
26 words
A process according to claim 5, separate regenerators being provided for each of the upper and the adjoining lower temperature range zones of the heat exchange.
Claim 8
Dependent Claim
62 words
A process according to claim 6, wherein each of the regenerators associated with the upper temperature range zone comprises two axially sequential packings separated by a partition, one of said packings always being traversed by the combustion gas to be cooled, and the other simultaneously by the air to be heated, and the packings being periodically reversed between combustion gas and air.
Claim 9
Dependent Claim
60 words
A process according to claim 6, wherein pairs of regenerators comprising axially sequential packings and periodically reversed between the flows of gases to be cooled and to be heated are used for the lower temperature range, the gases passing through the two packings of each particular regenerator always in opposite directions, either from the middle to the ends or vice-versa.
Claim 10
Dependent Claim
55 words
A process according to claim 8, wherein the regenerator of each pair fed with combustion gas precooled in the upper temperature range, is traversed from the middle to the ends and the other regenerator, fed with the cold purified combustion gas to be heated, is traversed from the ends to the middle by said media.
Claim 11
Dependent Claim
51 words
A process according to claim 2, for removing sulfur dioxide from combustion gases containing SO 2 , SO 3 and H 2 O further comprises separating sulfuric acid formed during precooling in the upper temperature range zone from the precooled combustion gas before the latter enters the lower temmperature range zone.
Claim 12
Dependent Claim
28 words
A process according to claim 10, the combustion gases precooled in the upper temperature range zone of the heat exchange being compressed before entering the lower temperature range.
Claim 13
Dependent Claim
50 words
A process according to claim 1, wherein the absorption type refrigeration unit is operated with an ammonia-water mixture and the ammonia acting as the coolant cools both the regenerated absorbent, and the purified waste gas flowing from the head of the scrubbing column, and said ammonia coolant is evaporated thereby.
Claim 14
Dependent Claim
33 words
A process according to claim 1, further comprising a heat pump system, said system removing heat from at least the physical absorbent and transferring said heat to the coolant of the absorption system.
Claim 15
Dependent Claim
25 words
A process according to claim 13, wherein the absorption type refrigeration unit is operated by a water-ammonia mixture and the heat pump system by ammonia.
Claim 16
Dependent Claim
62 words
A process according to claim 14, wherein the ammonia of the heat pump system condensed by the evaporating ammonia of the absorption cooling equipment following expansion is evaporated in heat exchange against both (a) the absorbent to be cooled and to be fed into a scrubbing column, and (b) purified waste gas to be removed from the top of the scrubbing column.
Claim 17
Dependent Claim
19 words
A process according to claim 15, wherein the ammonia of the heat pump system is evaporated at subatmospheric pressure.
Claim 18
Dependent Claim
11 words
A process according to claim 1, wherein dimethylformamide is the absorbent.
Claim 19
Dependent Claim
29 words
A process according to claim 17, comprising regenerating the absorbent in two separate stages, co-dissolved carbon dioxide being expelled in the first stage and sulfur dioxide in the second.
Claim 20
Dependent Claim
31 words
A process according to claim 18, characterized in that the carbon dioxide is expelled by means of a stripping gas and the sulfur dioxide at sub-atmospheric pressure and with heat applied.
Claim 21
Dependent Claim
33 words
A process according to claim 17, further comprising removing any sulfuric acid formed from residual H 2 O and residual sulfur trioxide or SO 3 from oxidized sulfur dioxide from the regenerated absorbent.
Claim 22
Dependent Claim
14 words
A process according to claim 20, wherein the sulfuric acid is removed by neutralization.
Claim 23
Dependent Claim
13 words
A process according to claim 21, wherein neutralization is carried out with ammonia.
Claim 24
Dependent Claim
14 words
A process according to claim 21, wherein the neutralization is conducted with calcium oxide.
Claim 25
Dependent Claim
15 words
A process according to claim 20, wherein dimethylformamide is separated from sulfuric acid by distillation.
Claim 26
Dependent Claim
28 words
A process according to claim 24, wherein residual dimethylformamide is removed from sulfuric acid concentrated by distillation by extracting the dimethylformamide with a solvent immiscible with sulfuric acid.
Claim 27
Dependent Claim
14 words
A process according to claim 25, wherein the solvent is a polar, organic solvent.
Claim 28
Dependent Claim
17 words
A process according to claim 26, wherein the extraction is carried out in the presence of water.
Claim 29
Dependent Claim
14 words
A process according to claim 26, wherein the solvent is chloroform, toluene, or benzene.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-10-12 | 1985-04-13 | 1985-10-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-10-12 | 1989-04-13 | 1989-10-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-10-12 | 1993-04-13 | 1993-10-13 | $7700.00 | Window Closed / Lapsed |