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US4294585A Expired / Lapsed US ⏱️ 0.0 years remaining

Novel fuel composition for internal combustion engine

Assignee: Texaco Inc
•
Filing: 1980-09-22
•
Granted: 1981-10-13
•
Expires: 2000-09-22
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Abstract

Abstract A novel fuel composition contains ethanol or gasohol plus, as a corrosion inhibitor, a reaction product of aminotetrazole, formaldehyde, and an N-alkyl propylene diamine.

Inventors

  • 👤 Rodney L. Sung

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 11:46
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/22; C10L1/232; C07; C07D; C07D257/00; C07D257/02; C07D257/04; C07D257/06; C10L1/18; C10L1/182; C10L1/1822; C10L1/1824

Claims Analysis

Total Claims: 51
Claim 1
Independent Claim 101 words
A fuel composition for internal combustion engines comprising (a) a major portion of a fuel containing (i) at least one alcohol selected from the group consisting of ethanol and methanol and (ii) gasoline in amount of 0-50 volumes per volume of alcohol; and (b) a minor corrosion inhibiting amount of, as a corrosion inhibiting agent, a reaction product of (i) an aminotetrazole, (ii) a ketone or an aldehyde, and (iii) a C 3 -C 12 poly-primary amine bearing at least one free --NH 2 group and at least one --NHR' group wherein R' is a C 12 -C 18 hydrocarbon group.
Claim 2
Dependent Claim 101 words
A fuel composition for internal combustion engines comprising (a) a major portion of a fuel containing (i) at least one alcohol selected from the group consisting of ethanol and methanol and (ii) gasoline in amount of 0-50 volumes per volume of alcohol; and (b) a minor corrosion inhibiting amount of, as a corrosion inhibiting agent, a reaction product of (i) an aminotetrazole, (ii) a ketone or an aldehyde, and (iii) a C 3 -C 12 poly-primary amine bearing at least one free --NH 2 group and at least one --NHR' group wherein R' is a C 12 -C 18 hydrocarbon group.
Claim 3
Dependent Claim 18 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said fuel is an alcohol.
Claim 4
Dependent Claim 17 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said fuel is methanol.
Claim 5
Dependent Claim 17 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said fuel is ethanol.
Claim 6
Dependent Claim 19 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said fuel is a commercial ethanol.
Claim 7
Dependent Claim 21 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said fuel is a commercial ethanol containing acid.
Claim 8
Dependent Claim 22 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said fuel is a commercial ethanol containing acetic acid.
Claim 9
Dependent Claim 18 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said fuel is a gasohol.
Claim 10
Dependent Claim 18 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said fuel is substantially anhydrous.
Claim 11
Dependent Claim 22 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said fuel contains less than 0.3 v % water.
Claim 12
Dependent Claim 17 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said aminotetrazole is 5-amino-tetrazole.
Claim 13
Dependent Claim 17 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said aminotetrazole is 1-amino-tetrazole.
Claim 14
Dependent Claim 17 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said aminotetrazole is 2-amino-tetrazole.
Claim 15
Dependent Claim 17 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said aminotetrazole is 3-amino-tetrazole.
Claim 16
Dependent Claim 17 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said aldehyde is formaldehyde.
Claim 17
Dependent Claim 17 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said aldehyde is acetaldehyde.
Claim 18
Dependent Claim 17 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said aldehyde is benzaldehyde.
Claim 19
Dependent Claim 17 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said ketone is acetone.
Claim 20
Dependent Claim 19 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said ketone is methyl ethyl ketone.
Claim 21
Dependent Claim 17 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said ketone is acetophenone.
Claim 22
Dependent Claim 18 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said amine is a diamine.
Claim 23
Dependent Claim 22 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said amine is a diamine containing an --NHR group.
Claim 24
Dependent Claim 42 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said amine is R'--NH--R"--NH 2 , R" is alkylene, arylene, alkarylene, arylene, or cycloalkylene hydrocarbon and R is C 12 -C 18 alkyl, alkaryl, aralkyl, aryl, or cycloalkyl hydrocarbon.
Claim 25
Dependent Claim 32 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said amine is R'--NH--CH 2 CH 2 CH 2 NH 2 and R' is C 12 -C 18 alkyl.
Claim 26
Dependent Claim 39 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said aminotetrazole is 5-amino-tetrazole, said aldehyde is formaldehyde, and said amine is R'NHCH 2 CH 2 CH 2 NH 2 and R' is oleoyl or tallowyl.
Claim 27
Dependent Claim 34 words
A fuel composition for internal combustion engines as claimed in claim 1 wherein said corrosion inhibiting agent is present in minor corrosion inhibiting amount of 0.0001 w %-0.01 w % of said fuel composition.
Claim 28
Dependent Claim 64 words
A fuel composition for internal combustion engines comprising (a) a major portion of a fuel containing absolute ethanol, and (b) a minor corrosion inhibiting amount, 0.0001 w %-0.01 w % of said fuel composition, of as a corrosion inhibiting agent, a reaction product of 5-amino-tetrazole, formaldehyde, and R'NHCH 2 CH 2 CH 2 NH 2 wherein R' is C 12 -C 18 alkyl hydrocarbon.
Claim 29
Dependent Claim 64 words
A fuel composition for internal combustion engines comprising (a) a major portion of a fuel containing absolute ethanol, and (b) a minor corrosion inhibiting amount, 0.0001 w %-0.01 w % of said fuel composition, of as a corrosion inhibiting agent, a reaction product of 5-amino-tetrazole, formaldehyde, and R'NHCH 2 CH 2 CH 2 NH 2 wherein R' is C 12 -C 18 alkyl hydrocarbon.
Claim 30
Dependent Claim 49 words
A composition comprising a reaction product of (i) an aminotetrazole, (ii) a ketone or an aldehyde, and (iii) a C 3 -C 12 poly-primary amine bearing at least one free --NH 2 group and at least one --NHR' group wherein R' is a C 12 -C 18 hydrocarbon group.
Claim 31
Dependent Claim 49 words
A composition comprising a reaction product of (i) an aminotetrazole, (ii) a ketone or an aldehyde, and (iii) a C 3 -C 12 poly-primary amine bearing at least one free --NH 2 group and at least one --NHR' group wherein R' is a C 12 -C 18 hydrocarbon group.
Claim 32
Dependent Claim 12 words
A composition as claimed in claim 28 wherein said aminotetrazole is 5-amino-tetrazole.
Claim 33
Dependent Claim 12 words
A composition as claimed in claim 29 wherein said aminotetrazole is 1-amino-tetrazole.
Claim 34
Dependent Claim 12 words
A composition as claimed in claim 28 wherein said aminotetrazole is 2-amino-tetrazole.
Claim 35
Dependent Claim 12 words
A composition as claimed in claim 28 wherein said aminotetrazole is 3-amino-tetrazole.
Claim 36
Dependent Claim 12 words
A composition as claimed in claim 28 wherein said aldehyde is formaldehyde.
Claim 37
Dependent Claim 12 words
A composition as claimed in claim 28 wherein said aldehyde is acetaldehyde.
Claim 38
Dependent Claim 12 words
A composition as claimed in claim 28 wherein said aldehyde is benzaldehyde.
Claim 39
Dependent Claim 12 words
A composition as claimed in claim 28 wherein said ketone is acetone.
Claim 40
Dependent Claim 14 words
A composition as claimed in claim 28 wherein said ketone is methyl ethyl ketone.
Claim 41
Dependent Claim 11 words
Acomposition as claimed in claim 28 wherein said ketone is acetophenone.
Claim 42
Dependent Claim 13 words
A composition as claimed in claim 28 wherein said amine is a diamine.
Claim 43
Dependent Claim 17 words
A composition as claimed in claim 28 wherein said amine is a diamine containing an --NHR' group.
Claim 44
Dependent Claim 37 words
A composition as claimed in claim 28 wherein said amine is R'--NH--R"--NH 2 , R" is alkylene, arylene, alkarylene, arylene, or cycloalkylene hydrocarbon and R' is C 12 -C 18 alkyl, alkaryl, aralkyl, aryl, or cycloalkyl hydrocarbon.
Claim 45
Dependent Claim 27 words
A composition as claimed in claim 28 wherein said amine is R'--NH--CH 2 CH 2 CH 2 NH 2 and R' is C 12 -C 18 alkyl.
Claim 46
Dependent Claim 32 words
A composition as claimed in claim 28 wherein said aminotetrazole is 5-amino-tetrazole, said aldehyde is formaldehyde, and said amine is R'NHCH 2 CH 2 NH 2 and R' is oleoyl or tallowyl.
Claim 47
Dependent Claim 29 words
A composition as claimed in claim 28 wherein said corrosion inhibiting agent is present in minor corrosion inhibiting amount of 0.0001 w %-0.01 w % of said fuel composition.
Claim 48
Dependent Claim 28 words
A composition comprising a reaction product of 5-amino-tetrazole, formaldehyde, and R'NHCH 2 CH 2 CH 2 NH 2 wherein R' is a C 12 -C 18 alkyl hydrocarbon.
Claim 49
Dependent Claim 28 words
A composition comprising a reaction product of 5-amino-tetrazole, formaldehyde, and R'NHCH 2 CH 2 CH 2 NH 2 wherein R' is a C 12 -C 18 alkyl hydrocarbon.
Claim 50
Dependent Claim 14 words
##STR2## wherein R' is a C 12 -C 18 straight chain alkyl hydrocarbon group.
Claim 51
Dependent Claim 14 words
##STR2## wherein R' is a C 12 -C 18 straight chain alkyl hydrocarbon group.

References Cited (Backward Citations)

US3316176A Cited
US3752764A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-10-12 1985-04-13 1985-10-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-10-12 1989-04-13 1989-10-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-10-12 1993-04-13 1993-10-13 $7700.00 Window Closed / Lapsed

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