Abstract Solid carbon material having extremely high flexural strength can be produced by introducing a sufficient amount of functional group to satisfy the undernoted general equation into a pitch having a H/C atomic ratio of 0.8 at most, thereby obtaining precursory carbon material; shaping said precursory carbon material into a desired article without using any binding material; and carbonizing or further graphitizing said article; wherein the general equation is ##EQU1## where, H/C is the hydrogen-to-carbon atomic ratio of the pitch, R is a numeral ranging from 0.2 to 0.3, and f is the percent by weight of at least one of oxygen, sulfur and halogen contained in the total functional groups introduced into the precursory carbon material on the basis of the weight thereof.
In a method for producing solid carbon material having a high bending strength and a low porosity which comprises preparing a precursory carbon material having a hydrogen-to-carbon ratio of from 0.4 to 0.6 by the sequential steps: introducing functional groups containing oxygen into a pitch used as a raw material having a maximum hydrogen-to-carbon atomic ratio of 0.8; shaping said precursory carbon material into a desired article without using any binding material; and carbonizing and graphitizing said article after said shaping in an inert atmosphere; the improvement comprising so introducing said functional groups into the pitch so as to satisfy the following equation, ##EQU3## where H/C is the hydrogen-to-carbon atomic ratio of the said pitch, R is a value ranging from 0.2 to 0.3, and f is the percent by weight oxygen introduced into the precursory carbon material on the basis of the weight thereof, whereby the said solid carbon material has a maximum effective porosity of 7 percent and a bending strength of at least 900 kg/cm 2 .
Claim 2
Dependent Claim
170 words
In a method for producing solid carbon material having a high bending strength and a low porosity which comprises preparing a precursory carbon material having a hydrogen-to-carbon ratio of from 0.4 to 0.6 by the sequential steps: introducing functional groups containing oxygen into a pitch used as a raw material having a maximum hydrogen-to-carbon atomic ratio of 0.8; shaping said precursory carbon material into a desired article without using any binding material; and carbonizing and graphitizing said article after said shaping in an inert atmosphere; the improvement comprising so introducing said functional groups into the pitch so as to satisfy the following equation, ##EQU3## where H/C is the hydrogen-to-carbon atomic ratio of the said pitch, R is a value ranging from 0.2 to 0.3, and f is the percent by weight oxygen introduced into the precursory carbon material on the basis of the weight thereof, whereby the said solid carbon material has a maximum effective porosity of 7 percent and a bending strength of at least 900 kg/cm 2 .