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US4292397A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for preparing dry planographic plates with plasma

Assignee: Shin-Etsu Chemical Co Ltd
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Filing: 1980-04-17
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Granted: 1981-09-29
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Expires: 2000-04-17
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Abstract

Abstract The invention provides a novel planographic printing plate suitable for dry planographic printing without supply of dampening water and a method for the preparation thereof. The inventive printing plate has, on one surface of a base plate, a layer of an organopolysiloxane composed of the areas where fresh surface of the organopolysiloxane is exposed bare as the ink-repellent non-image areas and the areas where the surface of the organopolysiloxane layer has been subjected to the treatment with low temperature plasma to be oleophilic or ink-receptive as the image areas of the printing plate. According to the inventive method, the pattern-wise exposure of the organopolysiloxane layer to the plasma atmosphere is performed by first providing a pattern-wise layer of a plasma resistant protective resist layer on the organopolysiloxane layer followed by the plasma treatment and removal of the resist layer. In an improved embodiment of the invention, a layer of an abrasion-resistant ink-receptive material is provided on the organopolysiloxane layer in the plasma-treated areas so that the durability of the printing plate is remarkably improved. Further, incorporation of a metachromatic substance susceptible to plasma treatment, e.g. a dye subject to color change by the plasma treatment, in the organopolysiloxane or in an undercoating primer layer facilitates determination of the end point of the plasma treatment.

Inventors

  • 👤 Satoshi Takeuchi
  • 👤 Masanori Akada
  • 👤 Hitoshi Fujii
  • 👤 Takashi Toida
  • 👤 Minoru Takamizawa
  • 👤 Yoshio Inoue

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 21:46
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/075; G03F7/0752

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 91 words
A method for the preparation of a planographic printing plate which comprises the steps of: (a) providing a layer of an organopolysiloxane on one surface of a base plate, (b) providing a pattern-wise protective resist layer on the surface of the organopolysiloxane layer, (c) subjecting at least the superficial layer of the organopolysiloxane in the areas where no protective resist layer is provided thereon to a chemical treatment with chemical species activated in a plasma state to render the superficial layer oleophilic and ink-receptive, and (d) removing the protective resist layer.
Claim 2
Independent Claim 91 words
A method for the preparation of a planographic printing plate which comprises the steps of: (a) providing a layer of an organopolysiloxane on one surface of a base plate, (b) providing a pattern-wise protective resist layer on the surface of the organopolysiloxane layer, (c) subjecting at least the superficial layer of the organopolysiloxane in the areas where no protective resist layer is provided thereon to a chemical treatment with chemical species activated in a plasma state to render the superficial layer oleophilic and ink-receptive, and (d) removing the protective resist layer.
Claim 3
Dependent Claim 22 words
The method as claimed in claim 1 wherein the organopolysiloxane layer provided on one surface of the base plate contains a filler.
Claim 4
Dependent Claim 19 words
The method as claimed in claim 1 wherein the pattern-wise protective resist layer is formed with a photosensitive material.
Claim 5
Dependent Claim 16 words
The method as claimed in claim 3 wherein the photosensitive material is a photocurable organopolysiloxane composition.
Claim 6
Dependent Claim 30 words
The method as claimed in claim 4 wherein the photocurable organopolysiloxane composition is a liquid having a surface tension in the range from 18 to 25 dynes/cm at 20° C.
Claim 7
Dependent Claim 23 words
The method as claimed in claim 3 wherein said photosensitive material comprises an organopolysiloxane in an amount from 1 to 15% by weight.
Claim 8
Dependent Claim 14 words
The method as claimed in claim 6 wherein the organopolysiloxane is a photocurable organopolysiloxane.
Claim 9
Dependent Claim 19 words
The method as claimed in claim 1 wherein the pattern-wise protective resist layer is formed with a non-photosensitive material.
Claim 10
Dependent Claim 18 words
The method as claimed in claim 1 wherein the pattern-wise protective resist layer contains a plasma-resistant inorganic filler.
Claim 11
Dependent Claim 37 words
The method as claimed in claim 1 wherein the organopolysiloxane layer provided on one surface of the base plate contains a metachromatic substance susceptible to the chemical treatment with the chemical species activated in a plasma state.
Claim 12
Dependent Claim 46 words
The method as claimed in claim 1 wherein the base plate is provided on one surface thereof with a layer of a metachromatic substance susceptible to the chemical treatment with the chemical species activated in a plasma state as an undercoating layer of the organopolysiloxane layer.
Claim 13
Independent Claim 138 words
A method for the preparation of a planographic printing plate which comprises the steps of: (a) providing a layer of an organopolysiloxane on one surface of a base plate, (b) providing a pattern-wise protective resist layer on the surface of the organopolysiloxane layer, (c) subjecting at least the superficial layer of the organopolysiloxane in the areas where no protective resist layer is provided thereon to a chemical treatment with chemical species activated in a plasma state to render the superficial layer oleophilic and ink-receptive, (d) removing the protective resist layer, and (e) providing a layer of an abrasion-resistant ink-receptive material firmly bonded on to the surface of the organopolysiloxane layer in the areas where at least the superficial layer of the organopolysiloxane has been subjected to the chemical treatment with the chemical species activated in a plasma state.
Claim 14
Independent Claim 138 words
A method for the preparation of a planographic printing plate which comprises the steps of: (a) providing a layer of an organopolysiloxane on one surface of a base plate, (b) providing a pattern-wise protective resist layer on the surface of the organopolysiloxane layer, (c) subjecting at least the superficial layer of the organopolysiloxane in the areas where no protective resist layer is provided thereon to a chemical treatment with chemical species activated in a plasma state to render the superficial layer oleophilic and ink-receptive, (d) removing the protective resist layer, and (e) providing a layer of an abrasion-resistant ink-receptive material firmly bonded on to the surface of the organopolysiloxane layer in the areas where at least the superficial layer of the organopolysiloxane has been subjected to the chemical treatment with the chemical species activated in a plasma state.
Claim 15
Independent Claim 142 words
A method for the preparation of a planographic printing plate which comprises the steps of: (a) providing a layer of an organopolysiloxane on one surface of a base plate, (b) providing a pattern-wise protective resist layer on the surface of the organopolysiloxane layer, (c) subjecting at least the superficial layer of the organopolysiloxane in the areas where no protective resist layer is provided thereon to a chemical treatment with chemical species activated in a plasma state to render the superficial layer oleophilic and ink-receptive, (d) providing a layer of an abrasion-resistant ink-receptive material on both of the pattern-wise protective resist layer and the organopolysiloxane layer having been subjected to the chemical treatment with the chemical species activated in a plasma state, and (e) removing the layer of the protective resist layer together with the layer of the abrasion-resistant ink-receptive material formed thereon.
Claim 16
Independent Claim 142 words
A method for the preparation of a planographic printing plate which comprises the steps of: (a) providing a layer of an organopolysiloxane on one surface of a base plate, (b) providing a pattern-wise protective resist layer on the surface of the organopolysiloxane layer, (c) subjecting at least the superficial layer of the organopolysiloxane in the areas where no protective resist layer is provided thereon to a chemical treatment with chemical species activated in a plasma state to render the superficial layer oleophilic and ink-receptive, (d) providing a layer of an abrasion-resistant ink-receptive material on both of the pattern-wise protective resist layer and the organopolysiloxane layer having been subjected to the chemical treatment with the chemical species activated in a plasma state, and (e) removing the layer of the protective resist layer together with the layer of the abrasion-resistant ink-receptive material formed thereon.

References Cited (Backward Citations)

US3387991A Cited
US3632386A Cited
US4072769A Cited
US4036136A Cited
US4225663A Cited
US4137365A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-09-28 1985-03-30 1985-09-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-09-28 1989-03-30 1989-09-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-09-28 1993-03-30 1993-09-29 $7700.00 Window Closed / Lapsed

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