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US4292391A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide development accelerators

Assignee: Agfa Gevaert NV
•
Filing: 1980-02-06
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Granted: 1981-09-29
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Expires: 2000-02-06
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Abstract

Abstract Pyrazolo [3,4-d] pyrimidine, and derivatives thereof, can be added to either a silver halide emulsion, or to a hydroquinone (litho) developer to accelerate development and reduce the induction period.

Inventors

  • 👤 Joseph D. Overman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 01:46
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/10; G03C5/00; G03C5/26; G03C5/29; G03C5/305

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 287 words
In a process for developing a photographic light-sensitive material for the graphic arts which comprises image-wise exposing and infectiously developing a photographic film comprising a support having coated thereon a silver halide emulsion layer, in an infectious developing solution comprising (1) hydroquinone or a hydroquinone derivative, (2) an alkali, (3) an alkali metal bromide, (4) an alkali metal sulfite, (5) an aldehyde/alkali metal bisulfite adduct, and (6) an antifoggant, the improvement comprising incorporating into the emulsion or into the developer an accelerator in amount sufficient to reduce the induction period of said photographic film; said accelerator being a compound selected from the group consisting of: (a) a pyrazolo pyrimidine of the structure ##STR6## wherein R 1 and R 2 =H, OH, or NH 2 , with the proviso that when R 1 =OH, R 2 must be H or NH 2 , and R 3 =H or --O(CH 2 ) n --OH, wherein n is an integer from 1 to 3; (b) a substituted purine of the structure: ##STR7## wherein R 1 =OH or NH 2 ; R 2 =H, NH 2 , or OH with the proviso that when R 1 =OH, R 2 =H or NH 2 , and when R 1 =NH 2 , R 2 =H; R 3 =H, OH, NH 2 , or CH 3 with the proviso that when R 3 =OH, R 1 and R 2 may be OH; when R 3 =NH 2 , R 1 must be OH and R 2 must be H; and when R 3 =CH 3 , R 1 and R 2 must be OH. (c) a 4-aza-benzimidaziole of the structure: ##STR8## wherein R=H or NH 2 ; (d) 8-azaguanine ##STR9## (e) phthalazine ##STR10##
Claim 2
Dependent Claim 287 words
In a process for developing a photographic light-sensitive material for the graphic arts which comprises image-wise exposing and infectiously developing a photographic film comprising a support having coated thereon a silver halide emulsion layer, in an infectious developing solution comprising (1) hydroquinone or a hydroquinone derivative, (2) an alkali, (3) an alkali metal bromide, (4) an alkali metal sulfite, (5) an aldehyde/alkali metal bisulfite adduct, and (6) an antifoggant, the improvement comprising incorporating into the emulsion or into the developer an accelerator in amount sufficient to reduce the induction period of said photographic film; said accelerator being a compound selected from the group consisting of: (a) a pyrazolo pyrimidine of the structure ##STR6## wherein R 1 and R 2 =H, OH, or NH 2 , with the proviso that when R 1 =OH, R 2 must be H or NH 2 , and R 3 =H or --O(CH 2 ) n --OH, wherein n is an integer from 1 to 3; (b) a substituted purine of the structure: ##STR7## wherein R 1 =OH or NH 2 ; R 2 =H, NH 2 , or OH with the proviso that when R 1 =OH, R 2 =H or NH 2 , and when R 1 =NH 2 , R 2 =H; R 3 =H, OH, NH 2 , or CH 3 with the proviso that when R 3 =OH, R 1 and R 2 may be OH; when R 3 =NH 2 , R 1 must be OH and R 2 must be H; and when R 3 =CH 3 , R 1 and R 2 must be OH. (c) a 4-aza-benzimidaziole of the structure: ##STR8## wherein R=H or NH 2 ; (d) 8-azaguanine ##STR9## (e) phthalazine ##STR10##
Claim 3
Dependent Claim 23 words
The process of claim 1 wherein the photographic film is an exposed litho film, and the accelerator is incorporated into the developer solution.
Claim 4
Dependent Claim 26 words
The process of claim 2 wherein the accelerator is incorporated into the developer solution in quantities within the range of 0.0005 to 2 g/liter of solution.
Claim 5
Dependent Claim 25 words
The process of claim 1 wherein the accelerator is incorporated into the emulsion in quantities of 1×10 -2 to 5 millimoles/1.5 moles of silver halide.
Claim 6
Dependent Claim 280 words
In a process for developing a photographic light-sensitive material for the graphic arts which comprises image-wise exposing and developing a photographic film comprising a support having coated thereon a silver halide emulsion layer, in a noninfectious developing solution comprising (1) hydroquinone or a hydroquinone derivative, (2) an alkali, (3) an alkali metal bromide, (4) an alkali metal sulfite, and (5) an antifoggant, the improvement comprising incorporating into the emulsion or into the developer and accelerator in amount sufficient to reduce the induction period of said photographic film; said accelerator being a compound selected from the group consisting of: (a) a pyrazolo pyrimidine of the structure ##STR11## wherein R 1 and R 2 =H, OH, or NH 2 , with the proviso that when R 1 =OH, R 2 must be H or NH 2 , and R 3 =H or --O(CH 2 ) n --OH, wherein n is an integer from 1 to 3; (b) a substituted purine of the structure: ##STR12## wherein R 1 =OH or NH 2 ; R 2 =H, NH 2 , or OH with the proviso that when R 1 =OH, R 2 =H or NH 2 , and when R 1 =NH 2 , R 2 =H; R 3 =H, OH, NH 2 , or CH 3 with the proviso that when R 3 =OH, R 1 and R 2 may be OH; when R 3 =NH 2 , R 1 must be OH and R 2 must be H; and when R 3 =CH 3 , R 1 and R 2 must be OH. (c) a 4-aza-benzimidazole of the structure: ##STR13## wherein R=H or NH 2 ; (d) 8-azaguanine ##STR14## (e) phthalazine ##STR15##
Claim 7
Dependent Claim 280 words
In a process for developing a photographic light-sensitive material for the graphic arts which comprises image-wise exposing and developing a photographic film comprising a support having coated thereon a silver halide emulsion layer, in a noninfectious developing solution comprising (1) hydroquinone or a hydroquinone derivative, (2) an alkali, (3) an alkali metal bromide, (4) an alkali metal sulfite, and (5) an antifoggant, the improvement comprising incorporating into the emulsion or into the developer and accelerator in amount sufficient to reduce the induction period of said photographic film; said accelerator being a compound selected from the group consisting of: (a) a pyrazolo pyrimidine of the structure ##STR11## wherein R 1 and R 2 =H, OH, or NH 2 , with the proviso that when R 1 =OH, R 2 must be H or NH 2 , and R 3 =H or --O(CH 2 ) n --OH, wherein n is an integer from 1 to 3; (b) a substituted purine of the structure: ##STR12## wherein R 1 =OH or NH 2 ; R 2 =H, NH 2 , or OH with the proviso that when R 1 =OH, R 2 =H or NH 2 , and when R 1 =NH 2 , R 2 =H; R 3 =H, OH, NH 2 , or CH 3 with the proviso that when R 3 =OH, R 1 and R 2 may be OH; when R 3 =NH 2 , R 1 must be OH and R 2 must be H; and when R 3 =CH 3 , R 1 and R 2 must be OH. (c) a 4-aza-benzimidazole of the structure: ##STR13## wherein R=H or NH 2 ; (d) 8-azaguanine ##STR14## (e) phthalazine ##STR15##
Claim 8
Dependent Claim 23 words
The process of claim 5 wherein the photographic film is an exposed litho film, and the accelerator is incorporated into the developer solution.
Claim 9
Dependent Claim 26 words
The process of claim 6 wherein the accelerator is incorporated into the developer solution in quantities within the range of 0.0005 to 2 g/liter of solution.
Claim 10
Dependent Claim 25 words
The process of claim 5 wherein the accelerator is incorporated into the emulsion in quantities of 1×10 -2 to 5 millimoles/1.5 moles of silver halide.

References Cited (Backward Citations)

US2743180A Cited
US3161515A Cited
US3185570A Cited
US3554757A Cited
US3969117A Cited
US3782945A Cited
US3785822A Cited
US3899331A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-09-28 1985-03-30 1985-09-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-09-28 1989-03-30 1989-09-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-09-28 1993-03-30 1993-09-29 $7700.00 Window Closed / Lapsed

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