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Chlorine dioxide generation process

Assignee: Rio Linda Chemical Co Inc
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Filing: 1980-05-30
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Granted: 1981-09-29
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Expires: 2000-05-30
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Abstract

Abstract The present invention is directed to a chlorine dioxide generation process. The Novel process of this invention utilizes concentrated hydrochloric acid solution reacted with concentrated sodium chlorite solution, without prior dilution of either reactant. Resulting in consistent high efficiency with respect to yield and chemical consumption.

Inventors

  • 👤 Bruce W. Hicks
  • 👤 Jerry D. Hicks

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 06:20
CPC Classifications
C; C01; C01B; C01B11/00; C01B11/02; C01B11/022; C01B11/023; C01B11/024

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 104 words
A continuous process for producing chlorine dioxide by the reaction of a chlorite in a strong hydrochloric acid solution which comprises: Maintaining a constant level in a single reactor, in the absence of dilution water, by continuously feeding an undiluted solution of sodium chlorite that is from 0.7 molar to 3.49 molar into the reactor, and continuously feeding an undiluted hydrochloric acid solution that is from 6 molar to 12 molar into the reactor wherein from 0.8 moles to 2 moles of hydrochloric acid is supplied per mole of sodium chlorite, continuously removing the excess solution containing the generated chlorine dioxide from the reactor.
Claim 2
Dependent Claim 104 words
A continuous process for producing chlorine dioxide by the reaction of a chlorite in a strong hydrochloric acid solution which comprises: Maintaining a constant level in a single reactor, in the absence of dilution water, by continuously feeding an undiluted solution of sodium chlorite that is from 0.7 molar to 3.49 molar into the reactor, and continuously feeding an undiluted hydrochloric acid solution that is from 6 molar to 12 molar into the reactor wherein from 0.8 moles to 2 moles of hydrochloric acid is supplied per mole of sodium chlorite, continuously removing the excess solution containing the generated chlorine dioxide from the reactor.
Claim 3
Dependent Claim 15 words
Process of claim 1 wherein the sodium chlorite is from 1.5 molar to 2.5 molar.
Claim 4
Dependent Claim 15 words
Process of claim 1 wherein the hydrochloric acid is from 9.5 molar to 10.5 molar.
Claim 5
Dependent Claim 21 words
Process of claim 1 wherein from 0.93 moles to 1.75 moles of hydrochloric acid is supplied per mole of sodium chlorite.
Claim 6
Dependent Claim 75 words
A process for producing chlorine dioxide by the reaction of a chlorite in a strong hydrochloric acid solution which comprises: reacting in the absence of dilution water an undiluted solution of sodium chlorite that is from 0.7 molar to 3.49 molar with an undiluted hydrochloric acid solution that is from 6 molar to 12 molar in a reactor wherein from 0.8 moles to 2 moles of hydrochloric acid is supplied per mole of sodium chlorite.
Claim 7
Dependent Claim 75 words
A process for producing chlorine dioxide by the reaction of a chlorite in a strong hydrochloric acid solution which comprises: reacting in the absence of dilution water an undiluted solution of sodium chlorite that is from 0.7 molar to 3.49 molar with an undiluted hydrochloric acid solution that is from 6 molar to 12 molar in a reactor wherein from 0.8 moles to 2 moles of hydrochloric acid is supplied per mole of sodium chlorite.

References Cited (Backward Citations)

AT210932B Cited
US3386915A Cited
US4013761A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-09-28 1985-03-30 1985-09-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-09-28 1989-03-30 1989-09-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-09-28 1993-03-30 1993-09-29 $7700.00 Window Closed / Lapsed

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