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US4289867A Expired / Lapsed US ⏱️ 0.0 years remaining

Organofunctional polysiloxane polymers and a method for preparing the same

Assignee: Wacker Chemical Corp
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Filing: 1980-01-30
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Granted: 1981-09-15
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Expires: 2000-01-30
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Abstract

Abstract This invention relates to sulfur containing polysiloxane polymers having units of the general formula (M).sub.x (T').sub.y wherein M represents an R 3 SiO 0 .5 unit in which R is a monovalent hydrocarbon radical or a halogenated monovalent hydrocarbon radical having from 1 to 18 carbon atoms, T' represents a unit of the formula (R"S).sub.z R'SiO.sub.1.5 in which R' is a divalent, trivalent or tetravalent hydrocarbon radical having from 2 to 18 carbon atoms or divalent, trivalent or tetravalent hydrocarbon radicals having at least one --C--S--C-- group, R" is hydrogen or R, x and y each represent a number greater than 1 and up to 20,000, in which the ratio of x to y may vary from 1:0.33 to 0.005:1 and z is 1, 2 or 3. These sulfur containing polysiloxane polymers are prepared by reacting in the presence of an acid catalyst a mixture containing (1) a hexaorganodisiloxane and (2) a silicon compound having the formula (R"S).sub.z R'Si(OR).sub.3 in which R, R' and R" are the same as above.

Inventors

  • 👤 Eugene R. Martin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 07:32
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/04; C08G77/22; C08G77/28; C08G77/06; C08G77/10

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 168 words
A process for preparing polysiloxane polymers which contain only (M) x (T') y structural units in which M is a unit of the formula R 3 SiO 0 .5 and T' represents a unit of the formula (R"S) z R' SiO 1 .5 which comprises reacting a hexaorganodisiloxane with a silicon compound of the formula [(R"S).sub.Z R'Si OR.sub.3 ](R"S).sub.z R'Si(OR).sub.3 in the presence of an acid catalyst having a pKa value less than 1.0, in which R is selected from the group consisting of monovalent hydrocarbon radicals and halogenated monovalent hydrocarbon radicals, R' is selected from the group consisting of divalent, trivalent and tetravalent hydrocarbon radicals having from 2 to 18 carbon atoms and divalent, trivalent and tetravalent hydrocarbon radicals having at least one --C--S--C--group, R" is selected from the group consisting of hydrogen, and R, x and y are each greater than 1 and up to 20,000, where the ratio of x to y may vary from 1:0.33 to 0.005:1 and z is 1, 2 or 3.
Claim 2
Dependent Claim 168 words
A process for preparing polysiloxane polymers which contain only (M) x (T') y structural units in which M is a unit of the formula R 3 SiO 0 .5 and T' represents a unit of the formula (R"S) z R' SiO 1 .5 which comprises reacting a hexaorganodisiloxane with a silicon compound of the formula [(R"S).sub.Z R'Si OR.sub.3 ](R"S).sub.z R'Si(OR).sub.3 in the presence of an acid catalyst having a pKa value less than 1.0, in which R is selected from the group consisting of monovalent hydrocarbon radicals and halogenated monovalent hydrocarbon radicals, R' is selected from the group consisting of divalent, trivalent and tetravalent hydrocarbon radicals having from 2 to 18 carbon atoms and divalent, trivalent and tetravalent hydrocarbon radicals having at least one --C--S--C--group, R" is selected from the group consisting of hydrogen, and R, x and y are each greater than 1 and up to 20,000, where the ratio of x to y may vary from 1:0.33 to 0.005:1 and z is 1, 2 or 3.
Claim 3
Dependent Claim 11 words
The process of claim 1, wherein the hexaorganodisiloxane is a hexaalkyldisiloxane.
Claim 4
Dependent Claim 10 words
The process of claim 2, wherein the hexaalkyldisiloxane is hexamethyldisiloxane.
Claim 5
Dependent Claim 17 words
The process of claim 1, wherein R is an alkyl radical and R' is a divalent radical.
Claim 6
Dependent Claim 9 words
The process of claim 1, wherein R" is hydrogen.
Claim 7
Dependent Claim 12 words
The process of claim 1, wherein R" is a monovalent hydrocarbon radical.
Claim 8
Dependent Claim 11 words
The process of claims 5 or 6, wherein z is 1.
Claim 9
Dependent Claim 11 words
The product prepared in accordance with the process of claim 1.

References Cited (Backward Citations)

US3794672A Cited
US4046795A Cited
US4133939A Cited
US4230816A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-09-14 1985-03-16 1985-09-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-09-14 1989-03-16 1989-09-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-09-14 1993-03-16 1993-09-15 $7700.00 Window Closed / Lapsed

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