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US4289738A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for removing H2 S from sour gases with generation of a Claus feed gas

Assignee: Dow Chemical Co
•
Filing: 1980-07-22
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Granted: 1981-09-15
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Expires: 2000-07-22
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Abstract

Abstract Sour industrial gases containing carbon dioxide and hydrogen sulfide are treated with amines to remove the CO 2 and H 2 S. The amine absorbent containing or loaded with H 2 S and CO 2 is regenerated and the off-gas containing concentrated amounts of H 2 S and CO 2 is treated in a second amine absorber to produce an amine absorbent loaded with H 2 S. This amine is then regenerated to provide an off-gas containing a high ratio of H 2 S to CO 2 which makes it suitable for use as the feed gas to a sulfur recovery unit such as a Claus plant. The process is automatically controlled so that the concentration of H 2 S in the second amine absorber is built up to and controlled at a desired set point so that the off-gas has the required H 2 S/CO 2 ratio.

Inventors

  • 👤 Roscoe L. Pearce
  • 👤 Charles W. Martin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 06:00
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/52; B01D53/526

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 278 words
A process for treating a sour gas to prepare a fuel gas with relatively low amounts of hydrogen sulfide, and simultaneously prepare (1) a side stream of relatively pure carbon dioxide and (2) a side stream of a gas suitable for the feed to a Claus process having the required H 2 S/CO 2 ratio which comprises (A) feeding a gas containing CO 2 and low amounts of H 2 S to a first amine absorber containing an aqueous amine solution to produce a first off gas useful as a fuel gas containing lower amounts of H 2 S, a major portion of the CO 2 and a first rich amine, (B) feeding said rich amine loaded with H 2 S and CO 2 from said first amine absorber to a first amine regenerator wherein said amine is regenerated to produce a lean amine and a second off gas containing essentially CO 2 and relatively large amounts of H 2 S and said lean amine is recycled back to said first absorber, (C) feeding said second off-gas to a second amine absorber to produce a third off-gas containing substantially pure CO 2 and a second rich amine, (D) feeding said second rich amine loaded with H 2 S from said second absorber to said first regenerator together with said first rich amine from said first absorber, and (E) feeding a proportion of said second rich amine to a second amine regenerator wherein said amine is regenerated to produce an off gas suitable for the feed of a sulfur recovery process wherein the flow to said second amine regenerator is automatically controlled to provide a suitable off gas composition.
Claim 2
Dependent Claim 278 words
A process for treating a sour gas to prepare a fuel gas with relatively low amounts of hydrogen sulfide, and simultaneously prepare (1) a side stream of relatively pure carbon dioxide and (2) a side stream of a gas suitable for the feed to a Claus process having the required H 2 S/CO 2 ratio which comprises (A) feeding a gas containing CO 2 and low amounts of H 2 S to a first amine absorber containing an aqueous amine solution to produce a first off gas useful as a fuel gas containing lower amounts of H 2 S, a major portion of the CO 2 and a first rich amine, (B) feeding said rich amine loaded with H 2 S and CO 2 from said first amine absorber to a first amine regenerator wherein said amine is regenerated to produce a lean amine and a second off gas containing essentially CO 2 and relatively large amounts of H 2 S and said lean amine is recycled back to said first absorber, (C) feeding said second off-gas to a second amine absorber to produce a third off-gas containing substantially pure CO 2 and a second rich amine, (D) feeding said second rich amine loaded with H 2 S from said second absorber to said first regenerator together with said first rich amine from said first absorber, and (E) feeding a proportion of said second rich amine to a second amine regenerator wherein said amine is regenerated to produce an off gas suitable for the feed of a sulfur recovery process wherein the flow to said second amine regenerator is automatically controlled to provide a suitable off gas composition.
Claim 3
Dependent Claim 47 words
The process as set forth in claim 1 wherein said first and second rich amines are automatically analyzed and compared for H 2 S content and the flow rate and H 2 S content of said second rich amine to said second amine regenerator is automatically controlled.
Claim 4
Dependent Claim 16 words
The process as set forth in claim 1 wherein the amine used is an alkanol amine.
Claim 5
Dependent Claim 14 words
The process as set forth in claim 3 wherein the amine used is methyldiethanolamine.

References Cited (Backward Citations)

US4001386A Cited
US3989811A Cited
US4025322A Cited
US4085199A Cited
US4210627A Cited
US4198387A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-09-14 1985-03-16 1985-09-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-09-14 1989-03-16 1989-09-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-09-14 1993-03-16 1993-09-15 $7700.00 Window Closed / Lapsed

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