US4288619A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the recovery of α-hydroxy- and α-amino-carboxylic acids from sugar-containing media
Assignee: Roquette Freres SA
•
Filing: 1979-08-30
•
Granted: 1981-09-08
•
Expires: 1999-08-30
Abstract
Abstract The invention relates to a process for the recovery of alpha -hydroxy- and alpha -amino-carboxylic acids from sugary media containing them. According to the process of the invention: in a first phase, the mixture from which it is proposed to recover the alpha -hydroxy- or alpha -amino-carboxylic acid and which contains the latter in the form of its calcium salt is contacted with a cationic resin in the calcium form for a sufficient time to reach optimal adsorption of said calcium salt and then, in a second phase, the previously saturated resin is eluted by resorting to water. The process according to the invention enables the quantitative production of a pure calcium salt.
Inventors
- 👤 Francis Devos
- 👤 Michel Huchette
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 04:34
CPC Classifications
C; C12; C12P; C12P13/00; C12P13/04; C12P13/20; C07; C07C; C07C51/00; C07C51/42; C07C51/47; C12P13/14; C12P7/00; C12P7/40; C12P7/56; C12P7/58
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
115 words
Process for recovering α-hydroxy- and α-amino-carboxylic acids in the form of their calcium salts from sugary media containing them, wherein: in the first step, said sugary media containing an α-hydroxy- or α-amino-carboxylic acid in the form of its calcium salt is contacted with a cationic resin in the calcium form for a sufficient time to achieve an optimal adsorption of said calcium salt and then, in a second step, the previously saturated resin is eluted by water to provide first fractions enriched in sugar and then latter fractions enriched essentially in an α-hydroxy- or α-aminocarboxylic acid in the form of its calcium salt, recovering thus the said acid in the form of its calcium salt.
Claim 2
Dependent Claim
115 words
Process for recovering α-hydroxy- and α-amino-carboxylic acids in the form of their calcium salts from sugary media containing them, wherein: in the first step, said sugary media containing an α-hydroxy- or α-amino-carboxylic acid in the form of its calcium salt is contacted with a cationic resin in the calcium form for a sufficient time to achieve an optimal adsorption of said calcium salt and then, in a second step, the previously saturated resin is eluted by water to provide first fractions enriched in sugar and then latter fractions enriched essentially in an α-hydroxy- or α-aminocarboxylic acid in the form of its calcium salt, recovering thus the said acid in the form of its calcium salt.
Claim 3
Dependent Claim
36 words
Process according to claim 1, wherein the time of contact between the mixture to be treated and the resin corresponds to a flow rate comprised between 0.2 volume and 5 volumes per volume of adsorbing resin.
Claim 4
Dependent Claim
26 words
Process according to claim 2, wherein the time of contact corresponds to a flow rate comprised between 0.5 volume to 1.5 volume per volume of resin.
Claim 5
Dependent Claim
27 words
Process according to claim 1, wherein both the mixtures subjected to treatment and the elution water are used at a temperature comprised between 20° and 100° C.
Claim 6
Dependent Claim
15 words
Process according to claim 4, wherein the temperature is comprised between 75° and 85° C.
Claim 7
Dependent Claim
42 words
Process according to claim 1, wherein the cationic resin if of the sulphonated styrene-divinyl-benzene type in its calcium form of a grain size range comprised between 0.1 and 1 mm, the cross-linking ratio of said resin being comprised between 2 and 10%.
Claim 8
Dependent Claim
21 words
Process according to claim 6, wherein the grain size range of the cationic resin is comprised between 0.2 and 0.6 mm.
Claim 9
Dependent Claim
19 words
Process according to claim 6, wherein the cross-linking ratio of the cationic resin is comprised between 3 and 5%.
Claim 10
Dependent Claim
32 words
Process according to claim 1, wherein it is applied to the recovery of calcium gluconate from sugary media containing it and which have been used for its preparation by specific biochemical oxidation.
Claim 11
Dependent Claim
32 words
Process according to claim 1, wherein it is applied to the recovery of calcium xylonate from sugary media containing it and which have been used for its preparation by specific biochemical oxidation.
Claim 12
Dependent Claim
32 words
Process according to claim 1, wherein it is applied to the recovery of calcium lactate from sugary media containing it and which have been used for its preparation by specific biochemical oxidation.
Claim 13
Dependent Claim
21 words
Process according to claim 1, wherein it is applied to the recovery of calcium glutamate from sugary manufacturing media containing it.
Claim 14
Dependent Claim
20 words
Process according to claim 1, wherein it is applied to the recovery of calcium aspartate from sugary media containing it.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-09-07 | 1985-03-09 | 1985-09-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-09-07 | 1989-03-09 | 1989-09-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-09-07 | 1993-03-09 | 1993-09-08 | $7700.00 | Window Closed / Lapsed |