US4287233A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Manufacture of acicular cobalt-containing magnetic iron oxide
Assignee: Emtec Magnetics GmbH
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Filing: 1980-01-29
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Granted: 1981-09-01
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Expires: 2000-01-29
Abstract
Abstract A process for the manufacture of acicular magnetic iron oxide consisting of core of gamma-iron(III) oxide and a ferrite shell which contains, based on the total amount of magnetic material, from 0.2 to 12 per cent by weight of cobalt(II) ions and from 0.1 to 15 per cent by weight of iron(II) ions, wherein a precipitate of cobalt(II) hydroxide and iron (II) hydroxide is applied to acicular gamma-iron(III) oxide particles and the latter are heated at 100°-200° C.
Inventors
- 👤 Peter Rudolf
- 👤 Werner Steck
- 👤 Eberhard Koester
- 👤 Manfred Ohlinger
- 👤 Christof Jaeckh
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 08:57
CPC Classifications
G; G11; G11B; G11B5/00; G11B5/62; G11B5/68; G11B5/70; G11B5/706; G11B5/70626; G11B5/70642; G11B5/70652; G11B5/70657
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
170 words
A process for the manufacture of acicular magnetic iron oxide which consists of a core of gamma-iron (III) oxide surrounded by a ferrite shell containing, based on the amount of magnetic material, from 0.2 to 12% by weight of cobalt (II) ions and from 0.1 to 15% by weight of iron (II) ions, wherein one part by weight of acicular gamma-iron (III) oxide is suspended in not more than four parts by weight of water by vigorous stirring, aqueous solutions containing cobalt (II) ions and iron (II) ions and aqueous bases to bring the pH of the suspension to not less than 10 are added to this suspension at from 20° to 80° C. under an inert gas blanket, with continued stirring, and after the cobalt (II) hydroxide and iron (II) hydroxide precipitate has formed under the inert gas atmosphere the entire solid product is filtered off, washed neutral with water and heated in an inert gas atmosphere for from two to seven hours at from 130° to 180° C.
Claim 2
Dependent Claim
170 words
A process for the manufacture of acicular magnetic iron oxide which consists of a core of gamma-iron (III) oxide surrounded by a ferrite shell containing, based on the amount of magnetic material, from 0.2 to 12% by weight of cobalt (II) ions and from 0.1 to 15% by weight of iron (II) ions, wherein one part by weight of acicular gamma-iron (III) oxide is suspended in not more than four parts by weight of water by vigorous stirring, aqueous solutions containing cobalt (II) ions and iron (II) ions and aqueous bases to bring the pH of the suspension to not less than 10 are added to this suspension at from 20° to 80° C. under an inert gas blanket, with continued stirring, and after the cobalt (II) hydroxide and iron (II) hydroxide precipitate has formed under the inert gas atmosphere the entire solid product is filtered off, washed neutral with water and heated in an inert gas atmosphere for from two to seven hours at from 130° to 180° C.
Claim 3
Dependent Claim
169 words
A process for the manufacture of acicular magnetic iron oxide which consists of a core of gamma-iron (III) oxide surrounded by a ferrite shell containing, based on the amount of magnetic material, from 0.2 to 12% by weight of cobalt (II) ions and from 0.1 to 15% by weight of iron (II) ions, wherein one part by weight of acicular gamma-iron (III) oxide is suspended in not more than four parts by weight of water by vigorous stirring, aqueous solutions containing cobalt (II) ions and iron (II) ions and aqueous bases to bring the pH of the suspension to not less than 10 are added to this suspension at from 20° to 80° C. under an inert gas blanket, with continued stirring, and after the cobalt (II) hydroxide and iron (II) hydroxide precipitate has formed under the inert gas atmosphere the entire solid product is filtered off, washed neutral with water and heated in an oxidizing atmosphere for from one to three hours at from 110° and 150° C.
Claim 4
Dependent Claim
169 words
A process for the manufacture of acicular magnetic iron oxide which consists of a core of gamma-iron (III) oxide surrounded by a ferrite shell containing, based on the amount of magnetic material, from 0.2 to 12% by weight of cobalt (II) ions and from 0.1 to 15% by weight of iron (II) ions, wherein one part by weight of acicular gamma-iron (III) oxide is suspended in not more than four parts by weight of water by vigorous stirring, aqueous solutions containing cobalt (II) ions and iron (II) ions and aqueous bases to bring the pH of the suspension to not less than 10 are added to this suspension at from 20° to 80° C. under an inert gas blanket, with continued stirring, and after the cobalt (II) hydroxide and iron (II) hydroxide precipitate has formed under the inert gas atmosphere the entire solid product is filtered off, washed neutral with water and heated in an oxidizing atmosphere for from one to three hours at from 110° and 150° C.
Claim 5
Dependent Claim
185 words
A process for the manufacture of acicular magnetic iron oxide which consists of a core of gamma-iron (III) oxide surrounded by a ferrite shell containing, based on the amount of magnetic material, from 0.2 to 12% by weight of cobalt (II) ions and from 0.1 to 15% by weight of iron (II) ions, wherein one part by weight of acicular gamma-iron (III) oxide is suspended in not more than four parts by weight of water by vigorous stirring, an aqueous solution containing cobalt (II) ions is added to this suspension, followed by the addition of aqueous bases to bring the pH of the suspension to not less than 10, both additions being made at from 20° to 80° C., thereafter an aqueous solution containing iron (II) ions is introduced with continued stirring under an inert gas atmosphere, and after the cobalt (II) hydroxide and iron (II) hydroxide precipitate has formed under the inert gas atmosphere the entire solid product is filtered off, washed neutral with water and heated in an inert gas atmosphere for from two to seven hours at from 130° to 180° C.
Claim 6
Dependent Claim
185 words
A process for the manufacture of acicular magnetic iron oxide which consists of a core of gamma-iron (III) oxide surrounded by a ferrite shell containing, based on the amount of magnetic material, from 0.2 to 12% by weight of cobalt (II) ions and from 0.1 to 15% by weight of iron (II) ions, wherein one part by weight of acicular gamma-iron (III) oxide is suspended in not more than four parts by weight of water by vigorous stirring, an aqueous solution containing cobalt (II) ions is added to this suspension, followed by the addition of aqueous bases to bring the pH of the suspension to not less than 10, both additions being made at from 20° to 80° C., thereafter an aqueous solution containing iron (II) ions is introduced with continued stirring under an inert gas atmosphere, and after the cobalt (II) hydroxide and iron (II) hydroxide precipitate has formed under the inert gas atmosphere the entire solid product is filtered off, washed neutral with water and heated in an inert gas atmosphere for from two to seven hours at from 130° to 180° C.
Claim 7
Dependent Claim
184 words
A process for the manufacture of acicular magnetic iron oxide which consists of a core of gamma-iron (III) oxide surrounded by a ferrite shell containing, based on the amount of magnetic mateial, from 0.2 to 12% by weight of cobalt (II) ions and from 0.1 to 15% by weight of iron (II) ions, wherein one part by weight of acicular gamma-iron (III) oxide is suspended in not more than four parts by weight of water by vigorous stirring, an aqueous solution containing cobalt (II) ions is added to this suspension, followed by the addition of aqueous bases to bring the pH of the suspension to not less than 10, both additions being made at from 20° to 80° C., thereafter an aqueous solution containing iron (II) ions is introduced with continued stirring under an inert gas atmosphere, and after the cobalt (II) hydroxide and iron (II) hydroxide precipitate has formed under the inert gas atmosphere the entire solid product is filtered off, washed neutral with water and heated in an oxidizing atmosphere for from one to three hours at from 110° to 150° C.
Claim 8
Dependent Claim
184 words
A process for the manufacture of acicular magnetic iron oxide which consists of a core of gamma-iron (III) oxide surrounded by a ferrite shell containing, based on the amount of magnetic mateial, from 0.2 to 12% by weight of cobalt (II) ions and from 0.1 to 15% by weight of iron (II) ions, wherein one part by weight of acicular gamma-iron (III) oxide is suspended in not more than four parts by weight of water by vigorous stirring, an aqueous solution containing cobalt (II) ions is added to this suspension, followed by the addition of aqueous bases to bring the pH of the suspension to not less than 10, both additions being made at from 20° to 80° C., thereafter an aqueous solution containing iron (II) ions is introduced with continued stirring under an inert gas atmosphere, and after the cobalt (II) hydroxide and iron (II) hydroxide precipitate has formed under the inert gas atmosphere the entire solid product is filtered off, washed neutral with water and heated in an oxidizing atmosphere for from one to three hours at from 110° to 150° C.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-08-31 | 1985-03-02 | 1985-09-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-08-31 | 1989-03-02 | 1989-09-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-08-31 | 1993-03-02 | 1993-09-01 | $7700.00 | Window Closed / Lapsed |