US4284738A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Ethylene-propylene block copolymerization process and product
Assignee: El Paso Products Co
•
Filing: 1980-08-11
•
Granted: 1981-08-18
•
Expires: 2000-08-11
Abstract
Abstract A process for the preparation of ethylene-propylene block copolymers at high catalyst productivity rates resulting in polymer products having improved impact strength-polymerized ethylene content relationship. The improvement is obtained by reacting preformed propylene prepolymer still containing active catalyst residues with ethylene and propylene in a vapor phase reaction zone in the presence of additional aluminum trialkyl catalyst component introduced to the reaction zone. The polymer produced by the process exhibits excellent physical and mechanical properties.
Inventors
- 👤 Edward A. Zukowski
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 21:16
CPC Classifications
C; C08; C08F; C08F297/00; C08F297/06; C08F297/08; C08F297/083; Y; Y10; Y10S; Y10S526/00; Y10S526/901; Y10S526/904
Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
187 words
A continuous sequential vapor phase block copolymerization process for the production of impact resistant ethylenepropylene polymers at high productivity rates, which comprises: (A) providing a preformed propylene polymer in finely divided form, said preformed polymer containing active catalyst residues and having been prepared by polymerizing propylene in the presence of a catalyst composition containing the components (a) an aluminum trialkyl or an aluminum trialkyl at least partially complexed with an electron donor compound, and (b) titanium tri- or tetrahalide supported on magnesium dihalide, or a complex of a titanium tri- or tetrahalide with an electron donor compound supported on magnesium dihalide, the components (a) and (b) being provided in a molar ratio of Al/Ti between about 10 and about 200; (B) introducing said preformed polymer, ethylene and propylene into at least one continuously agitated reaction zone, (C) introducing an additional quantity of component (a) to said reaction zone, said quantity ranging from about 5 to about 50% of the quantity in the preparation of the prepolymer; and (D) polymerizing said ethylene and propylene monomers in the vapor phase in the reaction zone onto said preformed propylene prepolymer.
Claim 2
Dependent Claim
187 words
A continuous sequential vapor phase block copolymerization process for the production of impact resistant ethylenepropylene polymers at high productivity rates, which comprises: (A) providing a preformed propylene polymer in finely divided form, said preformed polymer containing active catalyst residues and having been prepared by polymerizing propylene in the presence of a catalyst composition containing the components (a) an aluminum trialkyl or an aluminum trialkyl at least partially complexed with an electron donor compound, and (b) titanium tri- or tetrahalide supported on magnesium dihalide, or a complex of a titanium tri- or tetrahalide with an electron donor compound supported on magnesium dihalide, the components (a) and (b) being provided in a molar ratio of Al/Ti between about 10 and about 200; (B) introducing said preformed polymer, ethylene and propylene into at least one continuously agitated reaction zone, (C) introducing an additional quantity of component (a) to said reaction zone, said quantity ranging from about 5 to about 50% of the quantity in the preparation of the prepolymer; and (D) polymerizing said ethylene and propylene monomers in the vapor phase in the reaction zone onto said preformed propylene prepolymer.
Claim 3
Dependent Claim
26 words
A process according to claim 1, wherein the preformed propylene polymer is produced in a polymerization zone under sufficient pressure to maintain propylene in liquid phase.
Claim 4
Dependent Claim
14 words
A process according to claim 1, wherein the preformed propylene polymer is propylene homopolymer.
Claim 5
Dependent Claim
19 words
A process according to claim 1, wherein the preformed propylene polymer is a random copolymer of ethylene and propylene.
Claim 6
Dependent Claim
29 words
A process according to claim 1, wherein the ethylene and propylene monomers are introduced in a molar ratio of ethylene to propylene of from about 0.2 to about 0.4.
Claim 7
Dependent Claim
23 words
A process according to claim 1, wherein the aluminum trialkyl is one containing from 1 to 8 carbon atoms in the alkyl groups.
Claim 8
Dependent Claim
13 words
A process according to claim 1, wherein the aluminum trialkyl is triisobutyl aluminum.
Claim 9
Dependent Claim
13 words
A process according to claim 1, wherein the aluminum trialkyl is triethyl aluminum.
Claim 10
Dependent Claim
28 words
A process according to claim 1, wherein the electron donor compound of component (a) of the catalyst composition is an ester of a carboxylic acid or a diamine.
Claim 11
Dependent Claim
17 words
A process according to claim 9, wherein said electron donor is an ester of an aromatic acid.
Claim 12
Dependent Claim
11 words
A process according to claim 10, wherein the ester is methyl-p-toluate.
Claim 13
Dependent Claim
23 words
A process according to claim 1, wherein the molar ratio of trialkyl aluminum to electron donor ranges between about 1 and about 100.
Claim 14
Dependent Claim
17 words
A process according to claim 12, wherein the molar ratio is between about 2 and about 5.
Claim 15
Dependent Claim
27 words
The process of claim 1, wherein component (a) is prepared by prereacting the aluminum trialkyl with the electron donor for less than one hour prior to polymerization.
Claim 16
Dependent Claim
18 words
The process of claim 1, wherein the titanium tri- or tetrahalide is a titanium trichloride or titanium tetrachloride.
Claim 17
Dependent Claim
12 words
The process of claim 1, wherein the magnesium dihalide is magnesium dichloride.
Claim 18
Dependent Claim
27 words
The process of claim 1, wherein the electron donor compound of component (b) is a polyamine or an ester of an inorganic or an organic oxygenated acid.
Claim 19
Dependent Claim
17 words
The process of claim 17, wherein said electron donor is an ester of an aromatic carboxylic acid.
Claim 20
Dependent Claim
10 words
The process of claim 18, wherein the ester is ethylbenzoate.
Claim 21
Dependent Claim
21 words
The process of claim 1, wherein the magnesium to electron donor molar ratio of component (b) is at least about 1.
Claim 22
Dependent Claim
16 words
The process of claim 20, wherein said molar ratio is between about 2 and about 10.
Claim 23
Dependent Claim
28 words
The process of claim 1, wherein the titanium content expressed as titanium metal ranges between about 0.1 and about 20 weight percent in the supported catalyst component (b).
Claim 24
Dependent Claim
18 words
The process of claim 22, wherein the titanium content is between about 1 and about 3 weight percent.
Claim 25
Dependent Claim
24 words
A process according to claim 1, wherin step (D) is carried out at a temperature of from about 50° F. to about 210° F.
References Cited (Backward Citations)
US3401212A
Cited
US3318976A
Cited
US3514501A
Cited
US3917746A
Cited
US3732335A
Cited
US3830787A
Cited
US3953414A
Cited
US4051313A
Cited
US4115319A
Cited
US4128606A
Cited
US4149990A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-08-17 | 1985-02-16 | 1985-08-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-08-17 | 1989-02-16 | 1989-08-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-08-17 | 1993-02-16 | 1993-08-18 | $7700.00 | Window Closed / Lapsed |