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US4284524A Expired / Lapsed US ⏱️ 0.0 years remaining

Alkaline dishwasher detergent

Assignee: Procter and Gamble Co
•
Filing: 1980-06-30
•
Granted: 1981-08-18
•
Expires: 2000-06-30
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Abstract

Abstract Alkaline dishwasher detergent composition having a specific low level of a polyacetal carboxylate for improved hard water filming performance, especially in the presence of precipitating builders. The detergent composition is substantially free of highly alkaline materials and other organic builders.

Inventors

  • 👤 Lawrence A. Gilbert

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 06:18
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/395; C11D3/3955; C11D3/16; C11D3/37; C11D3/3703; C11D3/3711; C11D3/3953

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 419 words
An automatic dishwashing composition providing optimum cleaning; spotting and filming; and physical characteristics consisting essentially of: (1) from about 20% to about 60% of a detergency builder selected from the group consisting of alkali metal tripolyphosphates, pyrophosphates, orthophosphates, carbonates and mixtures thereof; (2) from about 10% to about 30% alkali metal silicate solids providing from about 5% to about 15% of SiO 2 ; (3) a material selected from the group consisting of sodium and potassium dichloroisocyanurates; dichloroisocyanuric acid; 1,3-dichloro-5,5-dimethylhydantoin; N,N'-dichlorobenzoylene urea; paratoluene sulfodichloroamide; trichloromelamine; N-chloroammeline; N-chlorosuccinimide; N,N'-dichloroazodicarbonamide; N-chloroacetyl urea; N,N'-dichlorobiuret; chlorinated dicyandiamide; sodium hypochlorite; calcium hypochlorite; lithium hypochlorite; chlorinated trisodium phosphate; and mixtures thereof; to provide available chlorine at a level of from about 0.5% to about 3%; (4) from about 1% to about 9.5% of a low foaming nonionic surfactant; selected from the group consisting of (a) the condensation product of 1 mole of a saturated or unsaturated, straight or branched chain alcohol or fatty acid containing from about 10 to about 20 carbon atoms with from about 4 to about 50 moles of ethylene oxide; (b) polyethylene glycols having molecular weights of from about 1,400 to about 30,000; (c) the condensation products of 1 mole of alkyl phenol wherein the alkyl chain contains from about 8 to about 18 carbon atoms and from about 4 to about 50 moles of ethylene oxide; (d) polyoxypropylene, polyoxyethylene condensates having the formula HO(C.sub.2 H.sub.4 O).sub.x (C.sub.3 H.sub.6 O).sub.y (C.sub.2 H.sub.4 O).sub.x H where y equals at least 15 and (C 2 H 4 O) x+x equals 20% to 90% of the total weight of the compound and the molecular weight is from about 2,000 to about 10,000; (e) the compounds of (a) which are capped with propylene oxide, butylene oxide, and/or short chain alcohols, and/or short chain fatty acids; and (f) mixtures thereof; (5) from about 1% to about 30% of a stabilized water-soluble polymer consisting essentially of polyacetal carboxylate segments having the structure ##STR8## wherein M is selected from the group consisting of alkali metal, ammonium tetraalkyl ammonium and alkanol amine groups having from 1 to about 4 carbon atoms in the alkyl and alkanol chains; n averages at least 4; and the total number of polyacetal carboxylate segments are at least 50% by weight of the total polymer; said composition having a pH of from about 9 to 10.9 at 2,500 ppm and being substantially free of materials having a pH of 12 or more at a concentration of 1% in water and other organic chelating builders.
Claim 2
Dependent Claim 419 words
An automatic dishwashing composition providing optimum cleaning; spotting and filming; and physical characteristics consisting essentially of: (1) from about 20% to about 60% of a detergency builder selected from the group consisting of alkali metal tripolyphosphates, pyrophosphates, orthophosphates, carbonates and mixtures thereof; (2) from about 10% to about 30% alkali metal silicate solids providing from about 5% to about 15% of SiO 2 ; (3) a material selected from the group consisting of sodium and potassium dichloroisocyanurates; dichloroisocyanuric acid; 1,3-dichloro-5,5-dimethylhydantoin; N,N'-dichlorobenzoylene urea; paratoluene sulfodichloroamide; trichloromelamine; N-chloroammeline; N-chlorosuccinimide; N,N'-dichloroazodicarbonamide; N-chloroacetyl urea; N,N'-dichlorobiuret; chlorinated dicyandiamide; sodium hypochlorite; calcium hypochlorite; lithium hypochlorite; chlorinated trisodium phosphate; and mixtures thereof; to provide available chlorine at a level of from about 0.5% to about 3%; (4) from about 1% to about 9.5% of a low foaming nonionic surfactant; selected from the group consisting of (a) the condensation product of 1 mole of a saturated or unsaturated, straight or branched chain alcohol or fatty acid containing from about 10 to about 20 carbon atoms with from about 4 to about 50 moles of ethylene oxide; (b) polyethylene glycols having molecular weights of from about 1,400 to about 30,000; (c) the condensation products of 1 mole of alkyl phenol wherein the alkyl chain contains from about 8 to about 18 carbon atoms and from about 4 to about 50 moles of ethylene oxide; (d) polyoxypropylene, polyoxyethylene condensates having the formula HO(C.sub.2 H.sub.4 O).sub.x (C.sub.3 H.sub.6 O).sub.y (C.sub.2 H.sub.4 O).sub.x H where y equals at least 15 and (C 2 H 4 O) x+x equals 20% to 90% of the total weight of the compound and the molecular weight is from about 2,000 to about 10,000; (e) the compounds of (a) which are capped with propylene oxide, butylene oxide, and/or short chain alcohols, and/or short chain fatty acids; and (f) mixtures thereof; (5) from about 1% to about 30% of a stabilized water-soluble polymer consisting essentially of polyacetal carboxylate segments having the structure ##STR8## wherein M is selected from the group consisting of alkali metal, ammonium tetraalkyl ammonium and alkanol amine groups having from 1 to about 4 carbon atoms in the alkyl and alkanol chains; n averages at least 4; and the total number of polyacetal carboxylate segments are at least 50% by weight of the total polymer; said composition having a pH of from about 9 to 10.9 at 2,500 ppm and being substantially free of materials having a pH of 12 or more at a concentration of 1% in water and other organic chelating builders.
Claim 3
Dependent Claim 18 words
The composition of claim 1 containing from about 5% to about 25% of carbonate, orthophosphate, or mixtures thereof.
Claim 4
Dependent Claim 25 words
The composition of claim 1 which is completely free of materials having a pH of 12 or more at a concentration of 1% in water.
Claim 5
Dependent Claim 18 words
The composition of claim 3 containing from about 3% to about 8% of a low foaming nonionic surfactant.
Claim 6
Dependent Claim 15 words
The composition of claim 3 containing from about 20% to about 35% of sodium tripolyphosphate.
Claim 7
Dependent Claim 17 words
The composition of claim 3 wherein the available chlorine is in the form of sodium dichloroisocyanurate dihydrate.
Claim 8
Dependent Claim 18 words
The composition of claim 1 which is completely free of organic chelating builders other than the polyacetal carboxylate.
Claim 9
Dependent Claim 20 words
The composition of claim 7 containing the polyacetal carboxylate at a level of from about 2% to less than 20%.
Claim 10
Dependent Claim 16 words
The composition of claim 8 containing from about 5% to about 15% of the polyacetal carboxylate.

References Cited (Backward Citations)

US4144226A Cited
US4146495A Cited
UST995003I4 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-08-17 1985-02-16 1985-08-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-08-17 1989-02-16 1989-08-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-08-17 1993-02-16 1993-08-18 $7700.00 Window Closed / Lapsed

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