US4283752A
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Ternary niobate dielectric compositions
Assignee: Corning Glass Works
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Filing: 1978-05-01
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Granted: 1981-08-11
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Expires: 1998-05-01
Abstract
Abstract A dielectric material which meets the temperature requirements for X7R grade capacitors consists of a fired ternary niobate composition. A dielectric constant of at least 2000 and a limited change in dielectric constant with temperature is present in compositions having the approximate formula: Pb.sub.x ·Ba.sub.y ·Sr.sub.z (Nb.sub.2 O.sub.6) where x, y and z represent the mole fractions of each of Pb, Ba and Sr which are in the ranges of X=0.1 to 0.4, y=0.1 to 0.4, z=0.4 to 0.5, the sum of x, y and z being 1. Modifications which increase these ranges include doping the ternary niobate composition with a rare earth and substitution of Ta 2 O 5 for Nb 2 O 5 . During preparation, the composition is heated in a cycle which produces a mixture of phases, primarily rhombohedral and tetragonal structures similar to those of PbNb 2 O 6 .
Inventors
- 👤 Margaret M. Layton
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 19:51
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/01; C04B35/495; C04B35/497; H; H01; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/06; H01G4/08; H01G4/12; H01G4/1209; H01G4/1254; Y; Y10; Y10T; Y10T29/00; Y10T29/43; Y10T29/435
Claims Analysis
Total Claims: 32
Claim 1
Independent Claim
67 words
A dielectric material consisting essentially of a fired ternary niobate composition having an approximate formula: Pb.sub.x ·Ba.sub.y ·Sr.sub.z (Nb.sub.2 O.sub.6) where x, y and z represent the mole fractions of each of Pb, Ba and Sr in said composition, the sum of x, y and z being 1, x is from 0.1 to 0.4 y is from 0.1 to 0.4 and z is from 0.4 to 0.5.
Claim 2
Dependent Claim
67 words
A dielectric material consisting essentially of a fired ternary niobate composition having an approximate formula: Pb.sub.x ·Ba.sub.y ·Sr.sub.z (Nb.sub.2 O.sub.6) where x, y and z represent the mole fractions of each of Pb, Ba and Sr in said composition, the sum of x, y and z being 1, x is from 0.1 to 0.4 y is from 0.1 to 0.4 and z is from 0.4 to 0.5.
Claim 3
Dependent Claim
26 words
The material recited in claim 1 which has been heated in a cycle which produces a mixture of phases including rhombohedral and tetragonal phase crystalline material.
Claim 4
Dependent Claim
39 words
The material recited in claim 2 wherein said composition is sintered in a cycle in which the temperature is increased to the sintering point in forty eight hours and thereafter cooled to room temperature throughout at least twenty-four hours.
Claim 5
Dependent Claim
20 words
A capacitor made of the dielectric material recited in claim 1 and having a dielectric constant of at least 2000.
Claim 6
Dependent Claim
29 words
The capacitor recited in claim 4 which has a change in dielectric constant with temperature which is +15% or less over the range from -55° C. to +125° C.
Claim 7
Dependent Claim
35 words
The material recited in claim 1 wherein MgZrO 3 is added to said composition in an amount from 0.005 to 1.0% by weight of said composition to improve the hot insulation resistance of said composition.
Claim 8
Dependent Claim
28 words
The material recited in claim 1 further consisting of CuO added to said composition in an amount sufficient to improve the life test characteristics of said fired composition.
Claim 9
Independent Claim
87 words
The method of making a dielectric material comprising: mixing compounds of Pb, Ba, Sr and Nb and heating the mixture in a cycle which produces a mixture including rhombohedral and tetragonal phase crystalline material, said compounds being mixed in proportions which produce the fired ternary niobate composition Pb x ·Ba y ·Sr z (Nb 2 O 6 ) where: x is from 0.1 to 0.4 y is from 0.1 to 0.4 z is from 0.4 to 0.5 and the sum of x, y and z is one.
Claim 10
Independent Claim
87 words
The method of making a dielectric material comprising: mixing compounds of Pb, Ba, Sr and Nb and heating the mixture in a cycle which produces a mixture including rhombohedral and tetragonal phase crystalline material, said compounds being mixed in proportions which produce the fired ternary niobate composition Pb x ·Ba y ·Sr z (Nb 2 O 6 ) where: x is from 0.1 to 0.4 y is from 0.1 to 0.4 z is from 0.4 to 0.5 and the sum of x, y and z is one.
Claim 11
Dependent Claim
45 words
The method recited in claim 8 wherein the step of heating said mixture in a cycle includes increasing the temperature to the sintering point in four-eight hours and thereafter cooling to room temperature throughout at least twenty-four hours to form a fired ternary niobate composition.
Claim 12
Dependent Claim
82 words
The method recited in claim 8 further comprising: forming a plurality of thin dielectric sheets of said material; applying a film of conductive material to at least two of said dielectric sheets in predetermined positions; and disposing said dielectric sheets with said films applied thereto in a stack to form a capacitor having a dielectric constant of at least 2000 and a change in dielectric constant with temperature which is 15% or less over the range from -55° C. to +125° C.
Claim 13
Dependent Claim
26 words
The method recited in claim 8 further comprising: adding MgZrO 3 to said compounds to improve the insulation resistance of the resulting fired ternary niobate composition.
Claim 14
Dependent Claim
25 words
The method recited in claim 11 wherein MgZrO 3 in the amount of 0.005-1.0% of the weight of said composition is added to said composition.
Claim 15
Dependent Claim
28 words
The method recited in claim 8 further comprising the step of adding CuO to said compounds to improve the life test characteristics of said fired ternary niobate composition.
Claim 16
Dependent Claim
131 words
A dielectric material consisting essentially of a fired ternary niobate composition having an approximate formula: Pb x ·A y ·B z ·Nb a Ta b O 6 x is from 0.15 to 0.65 y is from 0.001 to 0.85 z is from 0.001 to 0.55 where A and B are different from one another, A is selected from the group consisting of Ba, Ca and Cd, B is selected from the group consisting of Sr, Ca and Cd, x, y and z represent the mole fractions of each of Pb, A, and B in said composition, the sum of x, y and z being one, and a and b are the mole fractions of Nb and Ta, a and b being finite and the sum of a and b being 2.
Claim 17
Dependent Claim
131 words
A dielectric material consisting essentially of a fired ternary niobate composition having an approximate formula: Pb x ·A y ·B z ·Nb a Ta b O 6 x is from 0.15 to 0.65 y is from 0.001 to 0.85 z is from 0.001 to 0.55 where A and B are different from one another, A is selected from the group consisting of Ba, Ca and Cd, B is selected from the group consisting of Sr, Ca and Cd, x, y and z represent the mole fractions of each of Pb, A, and B in said composition, the sum of x, y and z being one, and a and b are the mole fractions of Nb and Ta, a and b being finite and the sum of a and b being 2.
Claim 18
Dependent Claim
23 words
The material recited in claim 14 wherein said composition is Pb x ·Ba y ·Sr z ·Nb a Ta b O 6 .
Claim 19
Dependent Claim
38 words
The material recited in claim 15 wherein an element from the group Ca and Cd is substituted for Ba or Sr in amounts up to a total of approximately 20 mole percent Ca and 10 mole percent Cd.
Claim 20
Dependent Claim
34 words
The material recited in claim 14 wherein Ta 2 O 5 is substituted for Nb 2 O 5 in the range of from 0.05% to 35% by mole of Nb 2 O 5 .
Claim 21
Dependent Claim
42 words
A capacitor made of the dielectric material recited in claim 14 and having a dielectric constant of at least 2000 and a change in dielectric constant with temperature which is 15% or less over the range from 55° C. to +125° C.
Claim 22
Dependent Claim
35 words
The material recited in claim 14 wherein MgZrO 3 is added to said composition in an amount from 0.005 to 1.0% by weight of said composition to improve the hot insulation resistance of said composition.
Claim 23
Dependent Claim
25 words
The dielectric material recited in claim 14 further consisting of CuO in an amount sufficient to improve the life test characteristics of said fired composition.
Claim 24
Dependent Claim
132 words
A dielectric material consisting essentially of a fired mixture of: Pb x ·Ba y ·Sr z (Nb 2 O 6 ) and a rare earth oxide selected from the group Nd 2 O 3 , Ce 2 O 3 and La 2 O 3 , wherein said composition is a mixture of from 97.0 to 99.75 mole percent of Pb x ·Ba y ·Sr z ·(Nb 2 O 6 ) and from 0.05 and to 3.00 mole percent of said rare earth oxide, where x, y and z represent the mole fractions of each of Pb, Ba and Sr in said composition, where x is from 0.15 to 0.65, y is from 0.001 to 0.85; z is from 0.001 to 0.55, and where the sum of x, y and z is one.
Claim 25
Dependent Claim
132 words
A dielectric material consisting essentially of a fired mixture of: Pb x ·Ba y ·Sr z (Nb 2 O 6 ) and a rare earth oxide selected from the group Nd 2 O 3 , Ce 2 O 3 and La 2 O 3 , wherein said composition is a mixture of from 97.0 to 99.75 mole percent of Pb x ·Ba y ·Sr z ·(Nb 2 O 6 ) and from 0.05 and to 3.00 mole percent of said rare earth oxide, where x, y and z represent the mole fractions of each of Pb, Ba and Sr in said composition, where x is from 0.15 to 0.65, y is from 0.001 to 0.85; z is from 0.001 to 0.55, and where the sum of x, y and z is one.
Claim 26
Dependent Claim
38 words
The material recited in claim 21 wherein an element from the group Ca and Cd is substituted for Ba or Sr in amounts up to a total of approximately 20 mole percent Ca and 10 mole percent Cd.
Claim 27
Dependent Claim
27 words
The material recited in claim 21 which has been heat treated in a cycle which produces a mixture of phases including rhombohedral and tetragonal phase crystalline material.
Claim 28
Dependent Claim
31 words
The material recited in claim 23 wherein said cycle includes increasing the temperature to the sintering point in four-eight hours and thereafter cooling to room temperature throughout at least twenty-four hours.
Claim 29
Dependent Claim
21 words
The material recited in claim 21 wherein said composition is a mixture of: Pb.sub.x Ba.sub.y Sr.sub.z Nb.sub.2 O.sub.6 and La.sub.2 O.sub.3.
Claim 30
Dependent Claim
42 words
A capacitor made of the dielectric material recited in claim 21 and having a dielectric constant of at least 2000 and a change in dielectric constant with temperature which is 15% or less over the range from -55° C. to +125° C.
Claim 31
Dependent Claim
35 words
The material recited in claim 21 wherein MgZrO 3 is added to said composition in an amount from 0.005 to 1.0% by weight of said composition to improve the hot insulation resistance of said composition.
Claim 32
Dependent Claim
24 words
The material recited in claim 21 further consisting of CuO in an amount sufficient to improve the life test characteristics of said fired mixture.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-08-10 | 1985-02-09 | 1985-08-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-08-10 | 1989-02-09 | 1989-08-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-08-10 | 1993-02-09 | 1993-08-11 | $7700.00 | Window Closed / Lapsed |