Copolymer having peroxy bonds in the molecule thereof and a process for producing the same

Claim 2

A copolymer having peroxy bonds in the molecule thereof, which copolymer is prepared by copolymerizing a diacyl type polymeric peroxide having the formula ##STR43## wherein R 1 is alkylene having 1 to 15 carbon atoms or phenylene, R 2 is alkylene having 2 to 10 carbon atoms, --(CHR 3 ,CH 2 O) l CHR 3 ,CH 2 wherein R 3 , is hydrogen or methyl and l is 1 to 10, ##STR44## and n is 2 to 10 with one or more monomers having the formula CHX.sub.1 ═CX.sub.2 X.sub.3 wherein X 1 is hydrogen, ##STR45## X 2 is hydrogen, --CH 3 , --Cl or --CN, X 3 is --Cl, --CN, ##STR46## or X 1 and X 3 together define ##STR47## in which R 3 and R 4 are alkyl having 1 to 18 carbon atoms or substituted alkyl having 1 to 18 carbon atoms with the provisos that (1) when X 1 and X 2 are both hydrogen, X 3 is ##STR48## (2) when X 1 is hydrogen and X 2 is --CH 3 , X 3 is ##STR49## (3) when X 1 is hydrogen and X 2 is --Cl or --CN, X 3 is --Cl, CN or --CH═CH 2 (4) when X 1 is ##STR50## X 2 is hydrogen, and X 3 is ##STR51## (5) when X 1 and X 3 together define ##STR52## X 2 is hydrogen, said copolymer consisting essentially of units of the formula --CHX 1 --CX 2 X 3 -- and ##STR53## wherein 1≦m≦n-1.

Claim 3

A copolymer as claimed in claim 1 having an average molecular weight of from 5,000 to 1,000,000, and having from 5 to 50 peroxy bonds per each 100,000 of the average molecular weight thereof.

Claim 4

A copolymer as claimed in claim 1 or claim 4 wherein said diacyl type polymeric peroxide is selected from the group consisting of ##STR54##

Claim 5

A copolymer as claimed in claim 3 in which said monomers are selected from the group consisting of styrene, vinyl chloride, vinylidene chloride, acrylonitrile, vinylidene cyanide, vinyl acetate, vinyl butyrate, vinyl stearate, vinyl toluene, vinyl pyridine, vinyl pyrrolidone, acrylic acid, methacrylic acid, methyl acrylate, ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, lauryl acrylate, stearyl acrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, methyl methacrylate, ethyl methacrylate, butyl methacrylate, 2-ethylhexyl methacrylate, lauryl methacrylate, stearyl methacrylate, 2-hydroxyethyl methacrylate, 2-hyroxypropyl methacrylate, glycidyl methacrylate, maleic anhydride, maleic acid, maleic acid esters, fumaric acid, fumaric acid esters, butadiene, isoprene and chloroisoprene.

Claim 6

A copolymer as claimed in claim 4 in which the amount of said diacyl type polymeric peroxide is from 0.5 to 10 parts by weight, per 100 parts by weight of said monomer.

Claim 7

A process for preparing a copolymer having peroxy bonds in the molecule thereof which comprises copolymerizing a diacyl type polymeric peroxide having the formula ##STR55## wherein R 1 is alkylene having 1 to 15 carbon atoms or phenylene, R 2 is alkylene having 2 to 10 carbon atoms, --(CHR 3 ,CH 2 O) l CHR 3 ,CH 2 wherein R 3 , is hydrogen or methyl and l is 1 to 10, ##STR56## and n is 2 to 10 with one or more monomers having the formula CHX.sub.1 ═CX.sub.2 X.sub.3 wherein X 1 is hydrogen, ##STR57## X 2 is hydrogen, --CH 3 , --Cl or --CN X 3 is --Cl, --CN, ##STR58## or X 1 and X 3 together define ##STR59## in which R 3 and R 4 are alkyl having 1 to 18 carbon atoms or substituted alkyl having 1 to 18 carbon atoms with the provisos that (1) when X 1 and X 2 are both hydrogen, X 3 is --Cl, --CN, ##STR60## (2) when X 1 is hydrogen and X 2 is --CH 3 , X 3 is ##STR61## (3) when X 1 is hydrogen and X 2 is --Cl or --CN, X 3 is --Cl, CN or --CH═CH 2 (4) when X 1 is ##STR62## X 2 is hydrogen, and X 3 is ##STR63## (5) when X 1 and X 3 together define ##STR64## X 2 is hydrogen, said copolymer consisting essentially of units of the formula --CHX 1 --CX 2 X 3 -- and ##STR65## wherein 1≦m≦n-1.

Claim 8

A process for preparing a copolymer having peroxy bonds in the molecule thereof which comprises copolymerizing a diacyl type polymeric peroxide having the formula ##STR55## wherein R 1 is alkylene having 1 to 15 carbon atoms or phenylene, R 2 is alkylene having 2 to 10 carbon atoms, --(CHR 3 ,CH 2 O) l CHR 3 ,CH 2 wherein R 3 , is hydrogen or methyl and l is 1 to 10, ##STR56## and n is 2 to 10 with one or more monomers having the formula CHX.sub.1 ═CX.sub.2 X.sub.3 wherein X 1 is hydrogen, ##STR57## X 2 is hydrogen, --CH 3 , --Cl or --CN X 3 is --Cl, --CN, ##STR58## or X 1 and X 3 together define ##STR59## in which R 3 and R 4 are alkyl having 1 to 18 carbon atoms or substituted alkyl having 1 to 18 carbon atoms with the provisos that (1) when X 1 and X 2 are both hydrogen, X 3 is --Cl, --CN, ##STR60## (2) when X 1 is hydrogen and X 2 is --CH 3 , X 3 is ##STR61## (3) when X 1 is hydrogen and X 2 is --Cl or --CN, X 3 is --Cl, CN or --CH═CH 2 (4) when X 1 is ##STR62## X 2 is hydrogen, and X 3 is ##STR63## (5) when X 1 and X 3 together define ##STR64## X 2 is hydrogen, said copolymer consisting essentially of units of the formula --CHX 1 --CX 2 X 3 -- and ##STR65## wherein 1≦m≦n-1.