Photographic compositions and elements spectrally sensitized with new methine dyes

Claim 2

In a radiation-sensitive silver-halide composition the improvement wherein said composition is spectrally sensitized by means of a methine dye comprising first and second nuclei joined by a methine linkage, at least said first nucleus comprising a heterocyclic nitrogen ring or ring system having a trialkylsilylalkyl group attached to a nitrogen atom thereof, said nitrogen atom being in conjugation with said methine linkage.

Claim 3

The radiation-sensitive silver-halide composition of claim 1 wherein each of said first and second nuclei of said methine dye comprises a heterocyclic nitrogen ring or ring system and each has a trialkylsilylalkyl group attached to a nitrogen atom thereof, each said nitrogen atom being in conjugation with said methine linkage.

Claim 4

A radiation-sensitive silver-halide composition containing a spectral sensiziting amount of a methine dye represented by the structure formula ##STR29## wherein: D represents atoms which complete a substituted or unsubstituted heterocyclic ring or fused heterocyclic ring system constituting a first nucleus; Z represents atoms to complete a methine dye, including a methine linkage, a second nucleus, and if necessary, an associated ion to maintain charge neutrality; R 1 , R 2 and R 3 are the same or different alkyl groups having from 1 to 3 carbon atoms; and n is an integer from 1 to 6.

Claim 5

A radiation-sensitive silver-halide composition containing a spectral sensiziting amount of a methine dye represented by the structure formula ##STR29## wherein: D represents atoms which complete a substituted or unsubstituted heterocyclic ring or fused heterocyclic ring system constituting a first nucleus; Z represents atoms to complete a methine dye, including a methine linkage, a second nucleus, and if necessary, an associated ion to maintain charge neutrality; R 1 , R 2 and R 3 are the same or different alkyl groups having from 1 to 3 carbon atoms; and n is an integer from 1 to 6.

Claim 6

The radiation-sensitive silver-halide composition of claim 3, wherein said methine dye is represented by the structural formula ##STR30## wherein: Q represents atoms which complete a substituted or unsubstituted fused heterocyclic ring system constituting said first nucleus; Z represents atoms to complete a methine dye, including said methine linkage, said second nucleus, and, if necessary, an associated ion to maintain charge neutrality; R 1 , R 2 , and R 3 are the same or different alkyl groups having from 1 to 3 carbon atoms; n is an integer from 1 to 6; and Y represents S, Se, O, or ##STR31## wherein R represents substituted or unsubstituted alkyl having from 1 to 5 carbon atoms or substituted or unsubstituted aryl.

Claim 7

The radiation-sensitive silver-halide composition of claim 1 wherein said first and second nuclei are the same or different and are chosen from the group consisting of a thiazole nucleus, an oxazole nucleus, a selenazole nucleus, a thiazoline nucleus, a quinoline nucleus, an indole nucleus, a pyridine nucleus, an imidazole nucleus, and an imidazole-quinoxaline nucleus.

Claim 8

The radiation-sensitive silver-halide composition of claim 1 wherein said second nucleus is selected from the group consisting of a 2-pyrazolin-5-one nucleus, a pyridimine nucleus, a rhodanine nucleus, a hydantoin nucleus, a thiohydantoin nucleus, and an oxazolidinedione nucleus.

Claim 9

In a radiation-sensitive silver-halide composition, the improvement wherein said composition is spectrally sensitized by means of a methine dye selected from the group consisting of: (1) 5,5',6,6'-tetrachloro-1,1-diethyl-3,3'-bis(3-trimethylsilylpropyl)benzimidazolocarbocyanine iodide; (2) 5,6-dichloro-1,3'-diethyl-3-(3-trimethylsilylpropyl)benzimidazolooxacarbocyanine iodide; (3) 5,6-dichloro-1,3'-diethyl-3-(3-trimethylsilylpropyl)benzimidazolothicarbocyanine iodide; (4) 5,6-dichloro-1,3'-diethyl-3-(3-trimethylsilylpropyl)-4',5'-benzobenzimidazolothiocarbocyanine iodide; (5) 5-{[5,6-dichloro-1-ethyl-3-)3-trimethylsilylpropyl)-2-benzimidazolinylidene]ethylidene}-3-ethylrhodanine; (6) 5-{[5,6-dichloro-1-ethyl-3-(3-trimethylsilylpropyl)-2-benzimidazolinylidene]ethylidene}-3-ethyl-2-thio-2,4-oxazolidinedione; (7) 3,3'-Bis(3-trimethylsilylpropyl)thiacarbocyanine iodide; (8) 9-methyl-3,3'-bis(3-trimethylsilylpropyl)thiacarbocyanine iodide; (9) 9-ethyl-3,3'-bis(3-trimethylsilylpropyl)thiacarbocyanine iodide; (10) 3,3'-bis(3-trimethylsilylpropyl)thiadicarbocyanine iodide; (11) 1'-ethyl-3-(3-trimethylsilylpropyl)thia-2'-cyanine iodide; (12) 3-ethyl-3'-(3-trimethylsilylpropyl)oxathiacarbocyanine iodide; (13) 3-ethyl-3'-(3-trimethylsilylpropyl)-4,5-benzothiacarbocyanine iodide; (14) 5-{[3-(3-trimethylsilylpropyl)-2-benzothiazolinylidene]ethylidene}-3-ethylrhodanine; (15) 2-(3,3-dicyanoallylidene)-3-(3-trimethylsilylpropyl)benzothiazoline; (16) 3,3'-bis(3-trimethylsilylpropyl)selenacarbocyanine iodide; (17) 3,3'-bis(3-trimethylsilylpropyl)selenadicarbocyanine iodide; (18) 1'-ethyl-3-(3-trimethylsilylpropyl)selena-2'-cyanine iodide; (19) 3-ethyl-3'-(3-trimethylsilylpropyl)oxaselenocarbocyanine iodide; and (20) 5,6-dichloro-1,3-diethyl-3'-(3-trimethylsilylpropyl)benzimidazoloselenacarbocyanine iodide.

Claim 10

In a radiation-sensitive silver-halide composition, the improvement wherein said composition is spectrally sensitized by means of a methine dye selected from the group consisting of: (1) 5,5',6,6'-tetrachloro-1,1-diethyl-3,3'-bis(3-trimethylsilylpropyl)benzimidazolocarbocyanine iodide; (2) 5,6-dichloro-1,3'-diethyl-3-(3-trimethylsilylpropyl)benzimidazolooxacarbocyanine iodide; (3) 5,6-dichloro-1,3'-diethyl-3-(3-trimethylsilylpropyl)benzimidazolothicarbocyanine iodide; (4) 5,6-dichloro-1,3'-diethyl-3-(3-trimethylsilylpropyl)-4',5'-benzobenzimidazolothiocarbocyanine iodide; (5) 5-{[5,6-dichloro-1-ethyl-3-)3-trimethylsilylpropyl)-2-benzimidazolinylidene]ethylidene}-3-ethylrhodanine; (6) 5-{[5,6-dichloro-1-ethyl-3-(3-trimethylsilylpropyl)-2-benzimidazolinylidene]ethylidene}-3-ethyl-2-thio-2,4-oxazolidinedione; (7) 3,3'-Bis(3-trimethylsilylpropyl)thiacarbocyanine iodide; (8) 9-methyl-3,3'-bis(3-trimethylsilylpropyl)thiacarbocyanine iodide; (9) 9-ethyl-3,3'-bis(3-trimethylsilylpropyl)thiacarbocyanine iodide; (10) 3,3'-bis(3-trimethylsilylpropyl)thiadicarbocyanine iodide; (11) 1'-ethyl-3-(3-trimethylsilylpropyl)thia-2'-cyanine iodide; (12) 3-ethyl-3'-(3-trimethylsilylpropyl)oxathiacarbocyanine iodide; (13) 3-ethyl-3'-(3-trimethylsilylpropyl)-4,5-benzothiacarbocyanine iodide; (14) 5-{[3-(3-trimethylsilylpropyl)-2-benzothiazolinylidene]ethylidene}-3-ethylrhodanine; (15) 2-(3,3-dicyanoallylidene)-3-(3-trimethylsilylpropyl)benzothiazoline; (16) 3,3'-bis(3-trimethylsilylpropyl)selenacarbocyanine iodide; (17) 3,3'-bis(3-trimethylsilylpropyl)selenadicarbocyanine iodide; (18) 1'-ethyl-3-(3-trimethylsilylpropyl)selena-2'-cyanine iodide; (19) 3-ethyl-3'-(3-trimethylsilylpropyl)oxaselenocarbocyanine iodide; and (20) 5,6-dichloro-1,3-diethyl-3'-(3-trimethylsilylpropyl)benzimidazoloselenacarbocyanine iodide.

Claim 11

A radiation-sensitive silver-halide photographic element comprising a support having thereon at least one layer comprising the radiation-sensitive silver halide composition of claims 1, 2, 3, 4, 5, 6, or 7.

Claim 12

A radiation-sensitive composition comprising silver halide and a spectrally sensitizing quantity of a methine dye comprising first and second nuclei joined by a methine linkage, at least said first nucleus comprising a heterocyclic nitrogen ring or ring system having a trialkylsilylalkyl group attached to a nitrogen atom thereof, said nitrogen atom being in conjugation with said methine linkage.

Claim 13

A radiation-sensitive composition comprising silver halide and a spectrally sensitizing quantity of a methine dye comprising first and second nuclei joined by a methine linkage, at least said first nucleus comprising a heterocyclic nitrogen ring or ring system having a trialkylsilylalkyl group attached to a nitrogen atom thereof, said nitrogen atom being in conjugation with said methine linkage.