US4281206A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of conducting reactions in a trickle-type reactor
Assignee: Wintershall Dea International AG
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Filing: 1975-01-30
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Granted: 1981-07-28
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Expires: 1995-01-30
Abstract
Abstract Trickle-type fixed-bed catalytic reactions are improved, prior to starting or resuming an on-stream period, by purging air from the catalyst bed and reaction zone by downward flow of an inert gas therethrough, flooding the purged reaction zone by flowing a liquid upwardly through the catalyst bed to cover same, then removing the liquid and instituting the on-stream period by introducing gaseous and liquid reactants at the upper end of the catalyst bed to flow downwardly therethrough.
Inventors
- 👤 Gunter Brandes
- 👤 Johannes Wollner
- 👤 Wilhelm Neier
- 👤 Werner Webers
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 05:29
CPC Classifications
C; C07; C07C; C07C45/00; C07C45/61; C07C45/67; C07C45/68; C07C45/72; C07C45/73; B; B01; B01J; B01J31/00; B01J31/02; B01J31/06; B01J31/08; B01J31/10; B01J8/00; B01J8/02; C07C29/00; C07C29/03; C07C29/04; B01J2208/00; B01J2208/00008; B01J2208/00539; B01J2208/0061; B01J2231/00; B01J2231/30; B01J2231/32; B01J2231/323
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
134 words
In a process for carrying out reactions between gaseous and liquid reactants which, during an onstream period, pass downwardly through a reaction zone containing a fixed bed of particulate catalyst having an average particle size not greater than about 2.0 mm, the improvement which comprises treating the catalyst prior to initiating an onstream period said treatment comprising removing air from said reaction zone by passing a gas devoid of free oxygen downwardly through said reaction zone and said catalyst bed, interrupting the flow of said gas and introducing a liquid to flow upwardly through said catalyst bed and cover same and then removing said liquid from said reaction zone and substantially simultaneously introducing said gaseous and liquid reactants into said reaction zone to flow downwardly through said catalyst bed thereby initiating the onstream period.
Claim 2
Dependent Claim
134 words
In a process for carrying out reactions between gaseous and liquid reactants which, during an onstream period, pass downwardly through a reaction zone containing a fixed bed of particulate catalyst having an average particle size not greater than about 2.0 mm, the improvement which comprises treating the catalyst prior to initiating an onstream period said treatment comprising removing air from said reaction zone by passing a gas devoid of free oxygen downwardly through said reaction zone and said catalyst bed, interrupting the flow of said gas and introducing a liquid to flow upwardly through said catalyst bed and cover same and then removing said liquid from said reaction zone and substantially simultaneously introducing said gaseous and liquid reactants into said reaction zone to flow downwardly through said catalyst bed thereby initiating the onstream period.
Claim 3
Dependent Claim
14 words
The process of claim 1 in which the gas devoid of oxygen is nitrogen.
Claim 4
Dependent Claim
14 words
The process of claim 1 in which the gas devoid of oxygen is hydrogen.
Claim 5
Dependent Claim
16 words
The process of claim 1 in which the gas devoid of oxygen is said gaseous reactant.
Claim 6
Dependent Claim
36 words
The process of claim 1 in which the liquid is passed upwardly through said bed at a rate between about 1 and 3 m 3 of liquid per m 2 of bed cross-sectional area per hour.
Claim 7
Dependent Claim
18 words
The process of claim 5 in which the liquid passed upwardly through said bed is said liquid reactant.
Claim 8
Dependent Claim
36 words
The process of claim 1 in which the gas devoid of oxygen is passed downwardly through the catalyst bed at a rate of about 3 standard liter per cm 2 of bed cross-sectional area per hour.
Claim 9
Dependent Claim
18 words
The process of claim 1 in which the particles have an average size no greater than 1.5 mm.
Claim 10
Dependent Claim
19 words
The process of claim 1 in which the gaseous reactant is hydrogen and the liquid reactant is a ketone.
Claim 11
Dependent Claim
19 words
The process of claim 1 in which the gaseous reactant is an olefin and the liquid reactant is water.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-07-27 | 1985-01-26 | 1985-07-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-07-27 | 1989-01-26 | 1989-07-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-07-27 | 1993-01-26 | 1993-07-28 | $7700.00 | Window Closed / Lapsed |