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US4281045A Expired / Lapsed US ⏱️ 0.0 years remaining

Multi-layer extruded article

Assignee: Kyoraku Co Ltd
•
Filing: 1979-11-29
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Granted: 1981-07-28
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Expires: 1999-11-29
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Abstract

Abstract A multi-layer extruded article useful for packaging materials, comprising a gas-barrier layer and a polyolefin layer laminated on at least one of the opposite sides of the gas-barrier layer, the gas-barrier layer being made of a mixture comprising a saponification product of an ethylene-vinyl acetate copolymer, a saponification product of an ethylene-vinyl acetate copolymer having a different ethylene content from the first saponification product, and a polyvinyl alcohol.

Inventors

  • 👤 Takehiko Sumi
  • 👤 Yoshinobu Oshige
  • 👤 Yoshio Koike
  • 👤 Kazuya Matsumoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 20:51
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/32; B32B27/06; B32B27/08; B32B2250/00; B32B2250/03; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1379; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31913; Y10T428/31928; Y10T428/31935; Y10T428/31938

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 186 words
A multi-layer extruded article comprising a gas-barrier layer and a polyolefin layer laminated on at least one of the opposite sides of the gas-barrier layer, the gas-barrier layer being made of a mixture comprising (a) a saponification product of an ethylene-vinyl acetate copolymer having an ethylene content of from 25 to 50 mol percent and a saponification degree of not less than 90 percent (Saponification Product A), (b) a saponification product of an ethylene-vinyl acetate copolymer having an ethylene content of from 60 to 98 mol percent and a saponification degree of not less than 20 percent (Saponification Product B), and (c) a polyvinyl alcohol having an average polymerization degree of from 300 to 3000 and a saponification degree of not less than 70 percent, wherein the ratio of the amounts of the aforementioned two saponification products (A:B) is in the range of from 98:2 to 50:50 by weight and wherein the amount of the polyvinyl alcohol is in the range of from 5 to 100 parts by weight per 100 parts by weight of the total weight of the two saponification products (A and B).
Claim 2
Dependent Claim 186 words
A multi-layer extruded article comprising a gas-barrier layer and a polyolefin layer laminated on at least one of the opposite sides of the gas-barrier layer, the gas-barrier layer being made of a mixture comprising (a) a saponification product of an ethylene-vinyl acetate copolymer having an ethylene content of from 25 to 50 mol percent and a saponification degree of not less than 90 percent (Saponification Product A), (b) a saponification product of an ethylene-vinyl acetate copolymer having an ethylene content of from 60 to 98 mol percent and a saponification degree of not less than 20 percent (Saponification Product B), and (c) a polyvinyl alcohol having an average polymerization degree of from 300 to 3000 and a saponification degree of not less than 70 percent, wherein the ratio of the amounts of the aforementioned two saponification products (A:B) is in the range of from 98:2 to 50:50 by weight and wherein the amount of the polyvinyl alcohol is in the range of from 5 to 100 parts by weight per 100 parts by weight of the total weight of the two saponification products (A and B).
Claim 3
Dependent Claim 33 words
The multi-layer extruded article according to claim 1, wherein the saponification product A is a saponification product of an ethylene-vinyl acetate copolymer which has a saponification degree of not less than 96 percent.
Claim 4
Dependent Claim 44 words
The multi-layer extruded article according to claim 1, wherein the saponification product B is a saponification product of an ethylene-vinyl acetate copolymer which has an ethylene content of from 70 to 95 mol percent and a saponification degree of not less than 50 percent.
Claim 5
Dependent Claim 22 words
The multi-layer extruded article according to claim 1, wherein the polyvinyl alcohol has an average polymerization degree of from 500 to 2000.
Claim 6
Dependent Claim 32 words
The multi-layer extruded article according to claim 1, wherein the polyolefin is one member selected from the group consisting of low-density polyethylene, medium-density polyethylene, high-density polyethylene, polypropylene, ethylene-propylene copolymers, polybutene-1 and polyheptene-1.
Claim 7
Dependent Claim 36 words
The multi-layer extruded article according to claim 1, which is formed in a three-layer construction comprising a gas-barrier layer as an intermediate layer and polyolefin layers respectively laminated on the opposite sides of the intermediate layer.
Claim 8
Dependent Claim 21 words
The multi-layer extruded article according to claim 1 or claim 6, wherein the extruded article is formed by the coextrusion process.

References Cited (Backward Citations)

US3282729A Cited
US3540962A Cited
US3931449A Cited
US3932692A Cited
US3949114A Cited
US4082854A Cited
US4151318A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-07-27 1985-01-26 1985-07-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-07-27 1989-01-26 1989-07-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-07-27 1993-01-26 1993-07-28 $7700.00 Window Closed / Lapsed

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