US4279804A
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Piperidine compounds and their use as stabilizers for synthetic polymers
Assignee: Ciba Geigy SpA
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Filing: 1979-03-13
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Granted: 1981-07-21
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Expires: 1999-03-13
Abstract
Abstract New piperidine compounds of the formula <IMAGE> (I) in which the radicals have the meanings indicated in the specification and which are stabilizers against light, heat and oxidation for synthetic polymers.
Inventors
- 👤 Giuseppe Cantatore
- 👤 Paolo Cassandrini
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 09:53
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3442
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
382 words
Compound of formula ##STR20## in which: R 1 represents hydrogen, --0°, --CN, a linear or branched alkyl containing 1 to 20 carbon atoms, an alkenyl or alkinyl containing 2 to 20 carbon atoms, benzyl, benzyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms, hydroxybenzyl, hydroxybenzyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms; or a --COR 14 , --COOR 14 , --CH 2 COOR 14 or --CONR 14 R 15 radical in which R 14 , R 15 , which can be equal or different, represent a linear or branched alkyl containing 1 to 20 carbon atoms, an alkenyl containing 2 to 20 carbon atoms, a cycloalkyl containing 5 to 12 carbon atoms, phenyl, phenyl substituted by 1 to 3 alkyls containing 1 to 8 carbon atoms, hydroxyphenyl, hydroxyphenyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms, an aralkyl containing 7 to 12 carbon atoms, or when bonded to N they can be hydrogen, or together with the N to which they are bonded they can form from five to eight membered nitrogenous containing heterocyclic rings or ##STR21## radical in which R 16 is hydrogen or methyl, and R 17 is --OH, --OR 14 , --OCOR 14 or --CONR 14 R 15 , in which R 14 and R 15 are always as heretofore defined; or a ##STR22## radical; R 2 , R 3 , R 6 , R 7 , which can be equal or different, represent an alkyl containing 1 to 6 C atoms; R 4 , R 5 , which can be equal or different, represent hydrogen or an alkyl containing 1 to 6 C atoms; R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , which can be equal or different, represent hydrogen or an alkyl containing 1 to 6 carbon atoms; n is zero or 1; A represents >C═O, >C═S, or >CH--R 18 in which R 18 is hydrogen, an alkyl containing 1 to 20 carbon atoms, a cycloalkyl containing 5 to 12 carbon atoms, phenyl, a hydroxyphenyl, a hydroxyphenyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms, benzyl, or benzyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms.
Claim 2
Dependent Claim
382 words
Compound of formula ##STR20## in which: R 1 represents hydrogen, --0°, --CN, a linear or branched alkyl containing 1 to 20 carbon atoms, an alkenyl or alkinyl containing 2 to 20 carbon atoms, benzyl, benzyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms, hydroxybenzyl, hydroxybenzyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms; or a --COR 14 , --COOR 14 , --CH 2 COOR 14 or --CONR 14 R 15 radical in which R 14 , R 15 , which can be equal or different, represent a linear or branched alkyl containing 1 to 20 carbon atoms, an alkenyl containing 2 to 20 carbon atoms, a cycloalkyl containing 5 to 12 carbon atoms, phenyl, phenyl substituted by 1 to 3 alkyls containing 1 to 8 carbon atoms, hydroxyphenyl, hydroxyphenyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms, an aralkyl containing 7 to 12 carbon atoms, or when bonded to N they can be hydrogen, or together with the N to which they are bonded they can form from five to eight membered nitrogenous containing heterocyclic rings or ##STR21## radical in which R 16 is hydrogen or methyl, and R 17 is --OH, --OR 14 , --OCOR 14 or --CONR 14 R 15 , in which R 14 and R 15 are always as heretofore defined; or a ##STR22## radical; R 2 , R 3 , R 6 , R 7 , which can be equal or different, represent an alkyl containing 1 to 6 C atoms; R 4 , R 5 , which can be equal or different, represent hydrogen or an alkyl containing 1 to 6 C atoms; R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , which can be equal or different, represent hydrogen or an alkyl containing 1 to 6 carbon atoms; n is zero or 1; A represents >C═O, >C═S, or >CH--R 18 in which R 18 is hydrogen, an alkyl containing 1 to 20 carbon atoms, a cycloalkyl containing 5 to 12 carbon atoms, phenyl, a hydroxyphenyl, a hydroxyphenyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms, benzyl, or benzyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms.
Claim 3
Dependent Claim
89 words
Compounds as claimed in claim 1, in which R 1 represents hydrogen or a C 1 -C 6 alkyl; R 2 , R 3 , R 6 , R 7 represent methyl or ethyl; R 4 , R 5 represent hydrogen or methyl; R 8 , R 9 , R 10 , R 11 , R 12 , R 13 represent hydrogen or methyl; n is zero or 1, A is >C═O, >C═S, >CH 2 , >CHR 18 in which R 18 is a C 1 -C 6 alkyl.
Claim 4
Dependent Claim
10 words
A compound as claimed in claim 1 of formula ##STR23##
Claim 5
Dependent Claim
10 words
A compound as claimed in claim 1 of formula ##STR24##
Claim 6
Dependent Claim
10 words
A compound as claimed in claim 1 of formula ##STR25##
Claim 7
Dependent Claim
10 words
A compound as claimed in claim 1 of formula ##STR26##
Claim 8
Dependent Claim
10 words
A compound as claimed in claim 1 of formula: ##STR27##
Claim 9
Dependent Claim
10 words
A compound as claimed in claim 1 of formula: ##STR28##
Claim 10
Dependent Claim
10 words
A compound as claimed in claim 1 of formula: ##STR29##
Claim 11
Dependent Claim
10 words
A compound as claimed in claim 1 of formula: ##STR30##
Claim 12
Dependent Claim
10 words
A compound as claimed in claim 1 of formula: ##STR31##
Claim 13
Dependent Claim
10 words
A compound as claimed in claim 1 of formula: ##STR32##
Claim 14
Dependent Claim
47 words
Polymer compositions stabilised against light, heat and oxidation, comprising a synthetic polymer and a stabilising compound of formula (I) as claimed in claim 1, in a quantity of 0.01 to 5%, and preferably 0.1 to 1% by weight, with respect to the weight of the synthetic polymer.
Claim 15
Dependent Claim
21 words
Compositions as claimed in claim 13, which also comprise other normal additives for synthetic polymers in addition to the new stabilisers.
Claim 16
Dependent Claim
17 words
Compositions as claimed in claim 13, wherein the synthetic polymer is high density or low density polyethylene.
Claim 17
Dependent Claim
12 words
Compositions as claimed in claim 13, wherein the synthetic polymer is polypropylene.
References Cited (Backward Citations)
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1984-07-20 | 1985-01-19 | 1985-07-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-07-20 | 1989-01-19 | 1989-07-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-07-20 | 1993-01-19 | 1993-07-21 | $7700.00 | Window Closed / Lapsed |