Recovery of cerium from polymer dispersions

Claim 2

The process for removing cerium (III) from a stable, acidic, aqueous polymeric dispersion having a pH of less than about 5.0 which comprises contacting said dispersion with a strong acid cation exchange resin wherein said cation is selected from the group consisting of hydrogen and hydrogen in combination with sodium, potassium, lithium or ammonium ion thereby adsorbing said cerium (III) onto the resin and thereafter separating said resin along with adsorbed cerium (III) from said dispersion.

Claim 3

The process of claim 1 wherein the residual cerium (III) after separation of the dispersion and the resin is not greater than about 0.0015% by weight based on the dry solids contained in the dispersion.

Claim 4

The process of claim 1 wherein the polymeric portion of the dispersion is comprised of a starch graft copolymer.

Claim 5

The process of claim 3 wherein the residual cerium (III) after separation of the dispersion and the resin is not greater than about 0.0015% by weight based on the dry solids contained in the dispersion.

Claim 6

The process of claim 4 wherein the resin is in the combined hydrogen-cationic form and the cation is selected from the group consisting of sodium, potassium, lithium and ammonium.

Claim 7

The process of claim 5 wherein the pH of the dispersion is in the range from about 2.0 to about 4.5.

Claim 8

The process of claim 6 wherein the cation is sodium.

Claim 9

The process of claims 4, 5, 6 or 7 wherein the dispersion is both contacted with and separated from the resin by passage through a bed packed with said resin.

Claim 10

The process for removing cerium (III) adsorbed on a strong cation ion exchange resin from said resin which comprises contacting said resin under acidic conditions with a solution of a salt whereby an insoluble precipitate is formed from said adsorbed cerium (III) and thereafter separating said precipitate from said resin.

Claim 11

The process for removing cerium (III) adsorbed on a strong cation ion exchange resin from said resin which comprises contacting said resin under acidic conditions with a solution of a salt whereby an insoluble precipitate is formed from said adsorbed cerium (III) and thereafter separating said precipitate from said resin.

Claim 12

The process of claim 9 wherein the precipitate is a cerium (III) sulfate.

Claim 13

The process of claim 9 wherein the precipitate is cerium (III) oxalate.

Claim 14

The process of claim 10 wherein the precipitate is formed by contacting said resin with a solution of sodium sulfate which is at least about 0.36 molar in sodium sulfate.

Claim 15

The process of claim 10 wherein the solution is from about 0.5 molar to about 1.0 molar in sodium sulfate.

Claim 16

The process of claim 11 wherein the precipitate is formed by contacting said resin with a solution of sodium oxalate which is at least about 0.20 molar in sodium oxalate.

Claim 17

The process for simultaneously releasing adsorbed cerium (III) from a strong cation exchange resin in the combined hydrogen-sodium form and regenerating said resin which comprises contacting said resin with a solution of sodium sulfate in weak sulfuric acid, said solution being from about 0.5 to about 1.0 molar in sodium sulfate.

Claim 18

The process for simultaneously releasing adsorbed cerium (III) from a strong cation exchange resin in the combined hydrogen-sodium form and regenerating said resin which comprises contacting said resin with a solution of sodium sulfate in weak sulfuric acid, said solution being from about 0.5 to about 1.0 molar in sodium sulfate.

Claim 19

Process for the recovery of cerium (III) contained in a stable aqueous, acidic polymeric dispersion having a pH of less than about 5.0 and oxidation of said cerium (III) to cerium (IV) which comprises: contacting said aqueous dispersion with a strong acid cation exchange resin wherein said cation is selected from the group consisting of hydrogen ion and hydrogen ion in combination with sodium, potassium, lithium or ammonium ion thereby adsorbing said cerium (III) onto said resin, separating said resin along with adsorbed cerium (III) from said aqueous dispersion, contacting said separated resin under acidic conditions with a solution of a salt whereby an insoluble cerium (III) precipitate is formed from said adsorbed cerium (III), separating said precipitate from said resin, and oxidizing the cerium (III) contained in said precipitate to cerium (IV).

Claim 20

Process for the recovery of cerium (III) contained in a stable aqueous, acidic polymeric dispersion having a pH of less than about 5.0 and oxidation of said cerium (III) to cerium (IV) which comprises: contacting said aqueous dispersion with a strong acid cation exchange resin wherein said cation is selected from the group consisting of hydrogen ion and hydrogen ion in combination with sodium, potassium, lithium or ammonium ion thereby adsorbing said cerium (III) onto said resin, separating said resin along with adsorbed cerium (III) from said aqueous dispersion, contacting said separated resin under acidic conditions with a solution of a salt whereby an insoluble cerium (III) precipitate is formed from said adsorbed cerium (III), separating said precipitate from said resin, and oxidizing the cerium (III) contained in said precipitate to cerium (IV).

Claim 21

Process of claim 16 wherein the dispersion is a stable aqueous dispersion comprised of a starch graft copolymer, the precipitate is a sulfate salt and the oxidation step is carried out in an aqueous medium with a pH of at least about 6 using oxygen as the oxidizing agent.

Claim 22

A stable aqueous starch graft copolymer dispersion, substantially free of cerium (III), prepared by the process of claim 4.