US4278533A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Conditioner for flotation of oxidized coal
Assignee: Dow Chemical Co
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Filing: 1980-02-07
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Granted: 1981-07-14
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Expires: 2000-02-07
Abstract
Abstract Certain ether amines and their derivatives are useful to improve the recovery of clean coal in a froth flotation process. The presence of these ether amines and derivatives in the flotation medium is particularly effective to enhance the recovery of oxidized bituminous coal.
Inventors
- 👤 Robert E. Hefner, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 12:47
CPC Classifications
B; B03; B03D; B03D1/00; B03D1/02; B03D1/001; B03D1/004; B03D1/0043; B03D1/006; B03D1/008; B03D1/01; B03D2201/00; B03D2201/007; B03D2201/02; B03D2201/04; B03D2203/00; B03D2203/02; B03D2203/04; B03D2203/08
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
234 words
A froth flotation process for beneficiaing coal of flotation size which comprises floating the sized coal in a frothing aqueous medium comprising a fuel oil collector and an effective amount of a conditioner selected from the group consisting of (1) an ether amine or hydroxyalkylated ether amine represented by the formula I: ##STR7## wherein each R' is independently hydrogen or methyl, each R" is independently ##STR8## wherein T at each occurrence is independently hydrogen, methyl or ethyl, with the proviso that R" at each occurrence contains no more than 4 carbon atoms; v, w, y, and z are each independently 0 or 1; x is 2 or 3 and R is an aryl, alkaryl, alkyl, aralkyl, alkenyl or alkynyl having from 1 to about 22 carbon atoms; (2) a condensation product of a compound of formula I with an organic carboxylic acid or its ester in a molar ratio of at least about 1 mole acid or ester per mole of the ether amine or derivative; and (3) an acid derivative of the compound of formula I or its condensation product; with the proviso that if the conditioner employed in flotation is not a condensation product of the compound of formula I or an acid derivative thereof, then in formula I, y and z are both O and R is an alkyl-substituted phenyl or an alkenyl or alkyl having at least 10 carbon atoms.
Claim 2
Dependent Claim
234 words
A froth flotation process for beneficiaing coal of flotation size which comprises floating the sized coal in a frothing aqueous medium comprising a fuel oil collector and an effective amount of a conditioner selected from the group consisting of (1) an ether amine or hydroxyalkylated ether amine represented by the formula I: ##STR7## wherein each R' is independently hydrogen or methyl, each R" is independently ##STR8## wherein T at each occurrence is independently hydrogen, methyl or ethyl, with the proviso that R" at each occurrence contains no more than 4 carbon atoms; v, w, y, and z are each independently 0 or 1; x is 2 or 3 and R is an aryl, alkaryl, alkyl, aralkyl, alkenyl or alkynyl having from 1 to about 22 carbon atoms; (2) a condensation product of a compound of formula I with an organic carboxylic acid or its ester in a molar ratio of at least about 1 mole acid or ester per mole of the ether amine or derivative; and (3) an acid derivative of the compound of formula I or its condensation product; with the proviso that if the conditioner employed in flotation is not a condensation product of the compound of formula I or an acid derivative thereof, then in formula I, y and z are both O and R is an alkyl-substituted phenyl or an alkenyl or alkyl having at least 10 carbon atoms.
Claim 3
Dependent Claim
18 words
The process as described in claim 1 wherein the coal is a bituminous coal having an oxidized surface.
Claim 4
Dependent Claim
27 words
The process as described in claim 1 wherein R is a C 5 -C 18 alkyl or an alkyl-substituted phenyl having from 14 to 18 carbon atoms.
Claim 5
Dependent Claim
11 words
The process as described in claim 3 wherein R' is hydrogen.
Claim 6
Dependent Claim
28 words
The process as described in claim 4 wherein the conditioner is a condensation product of a compound of formula I with an organic carboxylic acid or its ester.
Claim 7
Dependent Claim
14 words
The process as described in claim 5 wherein y and z are each 1.
Claim 8
Dependent Claim
11 words
The process as described in claim 6 wherein w is 0.
Claim 9
Dependent Claim
22 words
The process as described in claim 1 wherein the frothing aqueous medium further comprises an effective amount of a conventional frothing agent.
Claim 10
Dependent Claim
15 words
The process as described in claim 8 wherein the frothing agent is methyl isobutyl carbinol.
Claim 11
Dependent Claim
28 words
The process as described in claim 8 wherein the frothing agent is a monomethylether of a polypropylene glycol of about 200 to about 600 weight average molecular weight.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-07-13 | 1985-01-12 | 1985-07-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-07-13 | 1989-01-12 | 1989-07-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-07-13 | 1993-01-12 | 1993-07-14 | $7700.00 | Window Closed / Lapsed |