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US4278445A Expired / Lapsed US ⏱️ 0.0 years remaining

Subsonic-velocity entrained-bed gasification of coal

Assignee: Avco Corp
•
Filing: 1979-05-31
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Granted: 1981-07-14
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Expires: 1999-05-31
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Abstract

Abstract A process and apparatus for gasification of carbonaceous matter, preferably coal, is disclosed. In one embodiment, a stream of previously produced char, preferably produced from coal or other fuel, together with an oxidizer and steam is introduced into a combustion stage. The combustion gas produced by the combustion passes into a mixing zone and thence with high turbulence into a gasification zone or stage at subsonic velocity. Pulverized carbonaceous matter, preferably coal, is introduced and dispersed in the combustion gas in the mixing zone. The temperature, velocity and velocity changes principally of the gas in the gasification zone or stage are controlled to provide a heating rate for the particles of pulverized carbonaceous matter of at least about 10 5 degrees Kelvin per second, and to effect rapid removal of volatile components from the immediate vicinity of the particles. Upon substantial gasification of the particles in the gasification stage, the resultant product stream may be quenched, the char removed, and preferably at least a portion thereof introduced into the combustion stage.

Inventors

  • 👤 David B. Stickler
  • 👤 Charles W. von Rosenberg, Jr.
  • 👤 Richard E. Gannon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 02:46
CPC Classifications
C; C10; C10J; C10J3/00; C10J3/46; C10J3/48; C10J3/50; C10J3/506; C10J3/466; C10J3/52; C10J3/526; C10J3/72; C10J3/74; C10J3/76; C10J3/82; C10J3/84; C10J2300/00; C10J2300/09; C10J2300/0913; C10J2300/093; C10J2300/0953; C10J2300/0959; C10J2300/0973; C10J2300/0976; C10J2300/16; C10J2300/1603; C10J2300/1606; C10J2300/18; C10J2300/1807; C10J2300/1861; C10J2300/1884; Y; Y10; Y10S; Y10S48/00; Y10S48/04

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 294 words
A process for the gasification of solid carbonaceous fuel comprising: (a) combusting carbonaceous matter and an oxidizer in a combustion stage whereby said carbonaceous matter and oxidizer are reacted and hot products of combustion including hot combustion gas are formed; (b) introducing steam into said combustion stage to provide an ingredient of said combustion gas; (c) introducing said combustion gas into a mixing stage through which said combustion gas flows at subsonic velocity and at a predetermined level of turbulence; (d) introducing and dispersing finely divided solid carbonaceous fuel in said combustion gas in said mixing stage to form a mixed flow of particles of dispersed solid carbonaceous fuel entrained in surrounding hot combustion gas; (e) introducing said mixed flow into a gasification stage having a duct and through which said mixed flow flows at subsonic velocity with a mean gas flow rate of 10-500 m/sec.; (f) providing one or a plurality of fluid-dynamic bulk gas accelerations and decelerations to said mixed flow whereby said particles are strongly moved with respect to said surrounding hot gas by forcing a velocity differential between said particles and said gas using the inertia of said particles and accelerations of said gas, said mixed flow having accelerations and decelerations and said hot gas having an initial temperature sufficient that said particles are subjected to an average heating rate of at least about 10 5 degrees Kelvin per second, said particles are at least partially gasified and reduced to char and a product gas is formed; (g) withdrawing from said gasification stage a product stream comprising said char and product gas; (h) separating said char from said product stream; and (i) returning at least part of said separated char to said combustion stage to provide carbonaceous matter for combustion.
Claim 2
Dependent Claim 294 words
A process for the gasification of solid carbonaceous fuel comprising: (a) combusting carbonaceous matter and an oxidizer in a combustion stage whereby said carbonaceous matter and oxidizer are reacted and hot products of combustion including hot combustion gas are formed; (b) introducing steam into said combustion stage to provide an ingredient of said combustion gas; (c) introducing said combustion gas into a mixing stage through which said combustion gas flows at subsonic velocity and at a predetermined level of turbulence; (d) introducing and dispersing finely divided solid carbonaceous fuel in said combustion gas in said mixing stage to form a mixed flow of particles of dispersed solid carbonaceous fuel entrained in surrounding hot combustion gas; (e) introducing said mixed flow into a gasification stage having a duct and through which said mixed flow flows at subsonic velocity with a mean gas flow rate of 10-500 m/sec.; (f) providing one or a plurality of fluid-dynamic bulk gas accelerations and decelerations to said mixed flow whereby said particles are strongly moved with respect to said surrounding hot gas by forcing a velocity differential between said particles and said gas using the inertia of said particles and accelerations of said gas, said mixed flow having accelerations and decelerations and said hot gas having an initial temperature sufficient that said particles are subjected to an average heating rate of at least about 10 5 degrees Kelvin per second, said particles are at least partially gasified and reduced to char and a product gas is formed; (g) withdrawing from said gasification stage a product stream comprising said char and product gas; (h) separating said char from said product stream; and (i) returning at least part of said separated char to said combustion stage to provide carbonaceous matter for combustion.
Claim 3
Dependent Claim 69 words
A process for the gasification of carbonaceous fuel according to claim 1 wherein said combustion gas, introduced into said gasification stage, has a temperature of 1900° to 2800° Kelvin, a pressure of 1 to 100 atmospheres and a velocity of 10 to 500 meters per second, and the Reynolds number of the flow of said hot combustion gas around said particles is in the range of 1 to 1000.
Claim 4
Dependent Claim 36 words
A process for the gasification of carbonaceous fuel according to claim 1 wherein said fluid-dynamic accelerations to said mixed flow are provided by a sequence of variations of contour of said duct of said gasification stage.
Claim 5
Dependent Claim 39 words
A process for the gasification of carbonaceous fuel according to claim 3 wherein said sequence of variations of contour is a sequence of variations of area, whereby said duct comprises a sequence of subsonic convergent nozzles and subsonic diffusers.
Claim 6
Dependent Claim 36 words
A process for the gasification of carbonaceous fuel according to claim 3 wherein said sequence of variations of contour is a sequence of variations of direction, whereby said duct comprises a sequence of bent duct segments.
Claim 7
Dependent Claim 32 words
A process for the gasification of carbonaceous fuel according to claim 2 wherein said product stream drops in temperature at rate sufficient to substantially prevent attaining equilibrium among the gas stream components.
Claim 8
Dependent Claim 297 words
A process for the gasification of solid carbonaceous fuel comprising: (a) combusting finely divided carbonaceous matter and an oxidizer in a combustion stage whereby said carbonaceous matter and oxidizer are reacted and products of combustion including combustion gas are formed; (b) introducing steam into said combustion stage; (c) introducing said combustion gas and steam under pressure to a mixing stage through which said combustion gas and steam pass at subsonic velocity and a predetermined high level of turbulence; (d) introducing and dispersing finely divided solid fuel in said turbulent combustion gas in said mixing stage; (e) introducing said turbulent combustion gas and steam containing said dispersed solid fuel to a gasification stage through which said combustion gas and steam containing said dispersed fuel flow at subsonic velocity and wherein said particles of dispersed fuel are strongly moved with respect to said combustion gas and steam by forcing a velocity differential between said particles and said gas using the inertia of said particles and bulk gas acceleration and deceleration, said combustion gas and steam upon introduction into said gasification stage having a temperature of 1900°-2800° Kelvin, a pressure of 1-100 atmospheres and a velocity of 20-500 meters per second and the Reynolds number of gas flow around the particles of said fuel is 1-1000 to provide with said bulk gas acceleration and deceleration an average heating rate of at least about 10 5 degrees Kelvin per second whereby said fuel is at least partially gasified and reduced to char and a product gas is formed; (f) withdrawing from said gasification stage a product stream comprising said char and product gas; (g) separating said char from said product stream; and (h) returning at least part of said separated char to said combustion stage to provide carbonaceous matter for combustion.
Claim 9
Dependent Claim 297 words
A process for the gasification of solid carbonaceous fuel comprising: (a) combusting finely divided carbonaceous matter and an oxidizer in a combustion stage whereby said carbonaceous matter and oxidizer are reacted and products of combustion including combustion gas are formed; (b) introducing steam into said combustion stage; (c) introducing said combustion gas and steam under pressure to a mixing stage through which said combustion gas and steam pass at subsonic velocity and a predetermined high level of turbulence; (d) introducing and dispersing finely divided solid fuel in said turbulent combustion gas in said mixing stage; (e) introducing said turbulent combustion gas and steam containing said dispersed solid fuel to a gasification stage through which said combustion gas and steam containing said dispersed fuel flow at subsonic velocity and wherein said particles of dispersed fuel are strongly moved with respect to said combustion gas and steam by forcing a velocity differential between said particles and said gas using the inertia of said particles and bulk gas acceleration and deceleration, said combustion gas and steam upon introduction into said gasification stage having a temperature of 1900°-2800° Kelvin, a pressure of 1-100 atmospheres and a velocity of 20-500 meters per second and the Reynolds number of gas flow around the particles of said fuel is 1-1000 to provide with said bulk gas acceleration and deceleration an average heating rate of at least about 10 5 degrees Kelvin per second whereby said fuel is at least partially gasified and reduced to char and a product gas is formed; (f) withdrawing from said gasification stage a product stream comprising said char and product gas; (g) separating said char from said product stream; and (h) returning at least part of said separated char to said combustion stage to provide carbonaceous matter for combustion.
Claim 10
Dependent Claim 299 words
A process for the gasification of solid carbonaceous fuel comprising: (a) combusting finely divided carbonaceous matter and an oxidizer in a combustion stage whereby said carbonaceous matter and oxidizer are reacted and hot products of combustion including combustion gas are formed; (b) introducing steam into said combustion stage; (c) introducing said combustion gas and steam under pressure to a mixing stage through which said combustion gas and steam pass at subsonic velocity and high turbulence; (d) introducing and dispersing finely divided solid fuel as particles in said turbulent combustion gas and steam in said mixing stage; (e) introducing said turbulent combustion gas and steam containing said particles of dispersed solid fuel to a gasification stage through which said combustion gas and steam containing said dispersed solid fuel flow at subsonic velocity with a mean gas flow rate of 10-500 m/sec. and wherein said particles of dispersed fuel are strongly moved with respect to said combustion gas and steam by forcing a velocity differential between said particles and said gas using the inertia of said particles and bulk gas acceleration and deceleration; (f) providing a sequence of subsonic gaseous accelerations and decelerations in said gasification stage augmenting the turbulence of said combustion gas and steam entering said gasification stage, said combustion gas and steam having an initial temperature, initial turbulence and augmented turbulence to provide an average heating rate of at least about 10 5 degrees Kelvin per second whereby said fuel is at least partially gasified and reduced to char and a product gas is formed; (g) withdrawing from said gasification stage a product stream comprising said char and product gas; (h) separating said char from said product stream; and (i) returning at least part of said separated char to said combustion stage to provide carbonaceous matter for combustion.
Claim 11
Dependent Claim 299 words
A process for the gasification of solid carbonaceous fuel comprising: (a) combusting finely divided carbonaceous matter and an oxidizer in a combustion stage whereby said carbonaceous matter and oxidizer are reacted and hot products of combustion including combustion gas are formed; (b) introducing steam into said combustion stage; (c) introducing said combustion gas and steam under pressure to a mixing stage through which said combustion gas and steam pass at subsonic velocity and high turbulence; (d) introducing and dispersing finely divided solid fuel as particles in said turbulent combustion gas and steam in said mixing stage; (e) introducing said turbulent combustion gas and steam containing said particles of dispersed solid fuel to a gasification stage through which said combustion gas and steam containing said dispersed solid fuel flow at subsonic velocity with a mean gas flow rate of 10-500 m/sec. and wherein said particles of dispersed fuel are strongly moved with respect to said combustion gas and steam by forcing a velocity differential between said particles and said gas using the inertia of said particles and bulk gas acceleration and deceleration; (f) providing a sequence of subsonic gaseous accelerations and decelerations in said gasification stage augmenting the turbulence of said combustion gas and steam entering said gasification stage, said combustion gas and steam having an initial temperature, initial turbulence and augmented turbulence to provide an average heating rate of at least about 10 5 degrees Kelvin per second whereby said fuel is at least partially gasified and reduced to char and a product gas is formed; (g) withdrawing from said gasification stage a product stream comprising said char and product gas; (h) separating said char from said product stream; and (i) returning at least part of said separated char to said combustion stage to provide carbonaceous matter for combustion.
Claim 12
Dependent Claim 29 words
The process as set forth in claim 8 wherein said product stream drops in temperature at a rate sufficient to substantially prevent attaining equilibrium among the gas stream constituents.
Claim 13
Dependent Claim 29 words
The process as set forth in claim 8 wherein the cross sectional area of said gasification stage is varied to define a sequence of subsonic nozzles and subsonic diffusers.
Claim 14
Dependent Claim 31 words
The process as set forth in claim 8 wherein gaseous products flowing through said gasification stage generally follow a longer course than said fuel as it flows through said gasification stage.
Claim 15
Dependent Claim 29 words
The process as set forth in claim 11 wherein the said variations in the walls of the gasification stage are caused to define a sequence of curved duct segments.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-07-13 1985-01-12 1985-07-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-07-13 1989-01-12 1989-07-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-07-13 1993-01-12 1993-07-14 $7700.00 Window Closed / Lapsed

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