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US4278329A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrochromic device with transmissive counter electrode

Assignee: AGC Inc
•
Filing: 1979-06-05
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Granted: 1981-07-14
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Expires: 1999-06-05
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Abstract

Abstract An improved counter electrode used in an electrochromic device is transmissive in both charge injection and extraction states and exhibits excellent reversibility whereby it is optimum as a counter electrode in a transmissive electrochromic device which is useful as a display device in its control of visible and infrared absorption by a window and the like.

Inventors

  • 👤 Kenzi Matsuhiro
  • 👤 Yasushi Masuda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 16:21
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/01; G02F1/15; G02F1/153; G02F1/155; G02F1/1514; G02F1/1523; G02F1/1524

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 123 words
In an electrochromic device comprising two transparent substrates, each having formed thereon a transparent conductive film which face each other; first and second electrochromic films which are formed on the transparent conductive films; an electrolyte containing ions capable of changing the optical properties of the electrochromic film and a sealant for sealing the electrolyte between the two substrates, wherein the improvement comprises: said first electrochromic film being formed of a substance whose optical properties in the range of visible light change in response to the injection and extraction of said ions; and said second electrochromic film being formed of a substance whose optical properties in the range of visible light do not change in response to the injection and extraction of said ions.
Claim 2
Dependent Claim 123 words
In an electrochromic device comprising two transparent substrates, each having formed thereon a transparent conductive film which face each other; first and second electrochromic films which are formed on the transparent conductive films; an electrolyte containing ions capable of changing the optical properties of the electrochromic film and a sealant for sealing the electrolyte between the two substrates, wherein the improvement comprises: said first electrochromic film being formed of a substance whose optical properties in the range of visible light change in response to the injection and extraction of said ions; and said second electrochromic film being formed of a substance whose optical properties in the range of visible light do not change in response to the injection and extraction of said ions.
Claim 3
Dependent Claim 53 words
An electrochromic device according to claim 1 wherein said second electrochromic film is a crystalline tungsten oxide film having porous structure formed by depositing by a vacuum evaporation in a vacuum degree of from 5×10 -4 to 2×10 -3 torr on the transparent conductive film and baking at from 350° to 450° C.
Claim 4
Dependent Claim 30 words
An electrochromic device according to claim 1 wherein said first electrochromic film is an amorphous film containing tungsten oxide and said second electrochromic is a crystalline film containing tungsten oxide.
Claim 5
Dependent Claim 97 words
An electrochromic device having a laminated structure comprising: a transparent substrate; a first electrochromic film made of a substance having the property that a reversible injection and extraction of anions and electrons does not change its optical properties in the range of visible light; an insulating film in which anions may be injected, but electrons may not be substantially injected; a second electrochromic film made of a substance having the property that a reversible injection and extraction of anions and electrons does change its optical properties in the range of visible light; and a transparent conductive film.
Claim 6
Dependent Claim 97 words
An electrochromic device having a laminated structure comprising: a transparent substrate; a first electrochromic film made of a substance having the property that a reversible injection and extraction of anions and electrons does not change its optical properties in the range of visible light; an insulating film in which anions may be injected, but electrons may not be substantially injected; a second electrochromic film made of a substance having the property that a reversible injection and extraction of anions and electrons does change its optical properties in the range of visible light; and a transparent conductive film.
Claim 7
Dependent Claim 32 words
An electrochromic device according to claim 4 wherein said first electrochromic film is a crystalline film containing tungsten oxide which has a porous structure being capable of injection and extraction of ions.
Claim 8
Dependent Claim 32 words
An electrochromic device according to claim 4 wherein said second electrochromic film is an amorphous film containing tungsten oxide which has a porous structure being capable of injection and extraction of ions.

References Cited (Backward Citations)

US4182551A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-07-13 1985-01-12 1985-07-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-07-13 1989-01-12 1989-07-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-07-13 1993-01-12 1993-07-14 $7700.00 Window Closed / Lapsed

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