US4276475A
Expired / Lapsed
US
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Novel photometric system
Assignee: Waters Technologies Corp
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Filing: 1979-04-16
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Granted: 1981-06-30
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Expires: 1999-04-16
Abstract
Abstract Novel photometric apparatus advantageously having a conical shaped flow-cell comprising a light source proximate the narrow end and a photosensitive detector at the wider end of the cell. The flow-cell adequately compensates for a lens effect that has been discovered to be a substantial factor in electro-magnetic energy absorption studies on liquid streams.
Inventors
- 👤 Kenneth E. Nelson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 15:07
CPC Classifications
G; G01; G01N; G01N21/00; G01N21/01; G01N21/03; G01N21/05
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
261 words
Apparatus for measuring the amount of light absorbed by a portion of a flowing liquid, comprising: a sample cell for transporting said flowing liquid along the longitudinal dimension of said cell, said cell including a wall extending generally longitudinally, a light entrance window at one longitudinal end of said cell, and a light exit window at the other longitudinal end of said cell; a light source for generating a light beam; masking means including a mask with an aperture positioned between said light source and said entrance window of said cell for optically shaping said beam so that the portion of said beam that enters said cell through said window is transmitted through said cell without contacting said cell wall for a predetermined maximum liquid-lensing condition, thereby assuring that wall contact does not occur under any expected condition, said maximum condition corresponding to when the liquid in said cell has a distribution of refractive index that causes the greatest expected divergent spreading of said beam by refraction, detection means positioned beyond said exit window for measuring substantially all of the light emerging from said window, said detection means including a photoelectric element onto which said emerging light beam is incident, whereby the amount of light detected by said apparatus is independent of the amount by which said beam is bent by refraction within said cell because all of said beam entering said cell and not absorbed by said liquid also emerges from said cell and is detected, thereby making said apparatus independent of variations in the refractive index of said liquid.
Claim 2
Dependent Claim
261 words
Apparatus for measuring the amount of light absorbed by a portion of a flowing liquid, comprising: a sample cell for transporting said flowing liquid along the longitudinal dimension of said cell, said cell including a wall extending generally longitudinally, a light entrance window at one longitudinal end of said cell, and a light exit window at the other longitudinal end of said cell; a light source for generating a light beam; masking means including a mask with an aperture positioned between said light source and said entrance window of said cell for optically shaping said beam so that the portion of said beam that enters said cell through said window is transmitted through said cell without contacting said cell wall for a predetermined maximum liquid-lensing condition, thereby assuring that wall contact does not occur under any expected condition, said maximum condition corresponding to when the liquid in said cell has a distribution of refractive index that causes the greatest expected divergent spreading of said beam by refraction, detection means positioned beyond said exit window for measuring substantially all of the light emerging from said window, said detection means including a photoelectric element onto which said emerging light beam is incident, whereby the amount of light detected by said apparatus is independent of the amount by which said beam is bent by refraction within said cell because all of said beam entering said cell and not absorbed by said liquid also emerges from said cell and is detected, thereby making said apparatus independent of variations in the refractive index of said liquid.
Claim 3
Dependent Claim
70 words
The apparatus of claim 1 further comprising a second cell for holding a reference liquid, said second cell including a wall and entrance and exit windows, said masking means including means to shape said beam so that the portion of the beam entering said second cell is transmitted therethrough without contacting the cell walls, and said detection means including means for measuring substantially all light emerging from said second cell.
Claim 4
Dependent Claim
44 words
The apparatus of claim 1 wherein said sample and reference cells have parallel longitudinal axes and said light entrance windows of said cells each include a lens surface for bending said beam emerging from said mask into the general direction of parallel cell axes.
Claim 5
Dependent Claim
24 words
The apparatus of claim 3 wherein said entrance windows comprise a single element and said lens surfaces are a common surface on said element.
Claim 6
Dependent Claim
78 words
The apparatus of claim 1 wherein said mask is positioned with respect to said light source and said aperture is sized so that light emerges from said aperture at less than a predetermined angle with respect to the longitudinal centerline of said cell and said cell is shaped so that light entering said cell with an inclination of no more than said predetermined angle passes through said cell without contacting said cell wall, for said predetermined liquid-lensing condition.
Claim 7
Dependent Claim
19 words
The apparatus of claim 5 wherein said mask is substantially closer to said light source than to said cell.
Claim 8
Dependent Claim
44 words
The apparatus of claim 1 wherein said masking means includes means for shaping said beam so that light of a pre-selected wavelength that enters said cell through said window is transmitted through said cell without contacting said cell wall for said predetermined liquid-lensing condition.
Claim 9
Dependent Claim
26 words
A photometer as defined in claim 1 wherein said light source and said measuring means are so selected that said photometer is an ultra-violet absorbance detector.
Claim 10
Dependent Claim
27 words
A photometer as defined in claim 1 wherein said sample has a volume of less than 32 microliters and a maximum diameter of less than 2 millimeters.
Claim 11
Dependent Claim
28 words
A photometer as defined in claim 8 wherein said sample cell has a volume of less than 32 microliters and a maximum diameter of less than 2 millimeters.
Claim 12
Dependent Claim
27 words
A photometer as defined in claim 8 wherein said flow cell comprises walls devergent at an angle of at least 1° from the axis of said flowpath.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-06-29 | 1984-12-29 | 1985-06-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-06-29 | 1988-12-29 | 1989-06-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-06-29 | 1992-12-29 | 1993-06-30 | $7700.00 | Window Closed / Lapsed |