US4276227A
Expired / Lapsed
US
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Method of treating edible oil with alkali using interfacial surface mixer
Assignee: Procter and Gamble Co
•
Filing: 1980-03-07
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Granted: 1981-06-30
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Expires: 2000-03-07
Abstract
Abstract A method of treating edible oil comprising: driving a stream of about 70 to about 99.9 wt. % of an edible oil and about 0.1 to about 30 wt. % of a 0.01 to 6.5 Normal aqueous alkali solution, through an interfacial surface mixer at a predetermined mean droplet diameter of the aqueous alkali (phase) in said stream, which is related to a predetermined Reynolds number, said stream having a mixing temperature of from about 3 DEG C. to about 60 DEG C., and thereby mixing and reacting said oil and said alkali to provide a reacted aqueous alkali phase and a reacted oil phase, and then separating said reacted oil from said reacted aqueous alkali. The residence mixing and reacting time of the oil and alkali stream in the mixer is about five seconds: thus, the method of this invention is faster and more efficient than corresponding prior art oil alkali treatment processes. Neutral oil loss is reduced up to 80% and mixing energy required is reduced up to 98% over corresponding prior art. The predetermined alkaline solution phase droplet size generated in the mixer is calculated to be small enough to react with the oil and thereby provide the desired results, i.e., the refining of crude oil, the dewaxing of refined oil or the combined refining and dewaxing of crude oil. The droplet should however not be so small so as to generate an emulsion.
Inventors
- 👤 Charles E. Kirby
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 16:24
CPC Classifications
C; C11; C11B; C11B3/00; C11B3/02; C11B3/06
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
122 words
A method for refining, dewaxing or combined refining and dewaxing an impurity-containing edible oil, said method comprising the steps of: (a) forming a stream of from about 70 to about 99.9 wt. % of an impurity-containing edible oil and from about 0.1 to about 30 wt. % of a 0.01 to 6.5 Normal aqueous alkali solution; (b) driving the stream through an interfacial surface mixer at a temperature of from about 3° C. to about 60° C. so as to generate a mean droplet size in the alkali solution sufficiently small to mix with the oil, and to react with and remove the impurities therein, without forming an emulsion; and (c) separating the purified oil from the alkali solution after step (b).
Claim 2
Independent Claim
122 words
A method for refining, dewaxing or combined refining and dewaxing an impurity-containing edible oil, said method comprising the steps of: (a) forming a stream of from about 70 to about 99.9 wt. % of an impurity-containing edible oil and from about 0.1 to about 30 wt. % of a 0.01 to 6.5 Normal aqueous alkali solution; (b) driving the stream through an interfacial surface mixer at a temperature of from about 3° C. to about 60° C. so as to generate a mean droplet size in the alkali solution sufficiently small to mix with the oil, and to react with and remove the impurities therein, without forming an emulsion; and (c) separating the purified oil from the alkali solution after step (b).
Claim 3
Dependent Claim
30 words
A method according to claim 1 wherein step (b) comprises driving the stream through the interfacial surface mixer at a temperature of from about 23° C. to about 60° C.
Claim 4
Dependent Claim
13 words
A method according to claim 2 wherein the alkali solution comprises sodium hydroxide.
Claim 5
Dependent Claim
34 words
A method according to claim 1 wherein the edible oil is selected from the group consisting of safflower oil, soybean oil, palm oil, corn oil, peanut oil, cottonseed oil, coconut oil and sunflower oil.
Claim 6
Dependent Claim
13 words
A method according to claim 1 wherein the edible oil comprises sunflower oil.
Claim 7
Independent Claim
152 words
A method for dewaxing a wax-containing refined edible oil which has been tempered at a temperature of from about 20° C. to about 50° C. for at least about 12 hours, and then cooled to below about 20° C. for at least about 1 hour, said method comprising the steps of: (a) forming a stream of from about 70 to about 95 wt. % cooled oil and from about 5 to about 30 wt. % of a 0.01 to 0.5 Normal aqueous alkali solution; (b) driving the stream through an interfacial surface mixer at a temperature below about 20° C. so as to generate a mean droplet size in the alkali solution sufficiently small to mix with the oil, and to react with and remove the waxes therein, without forming an emulsion; and (c) separating the dewaxed oil from the alkali solution at a temperature below about 20° C. after step (b).
Claim 8
Independent Claim
152 words
A method for dewaxing a wax-containing refined edible oil which has been tempered at a temperature of from about 20° C. to about 50° C. for at least about 12 hours, and then cooled to below about 20° C. for at least about 1 hour, said method comprising the steps of: (a) forming a stream of from about 70 to about 95 wt. % cooled oil and from about 5 to about 30 wt. % of a 0.01 to 0.5 Normal aqueous alkali solution; (b) driving the stream through an interfacial surface mixer at a temperature below about 20° C. so as to generate a mean droplet size in the alkali solution sufficiently small to mix with the oil, and to react with and remove the waxes therein, without forming an emulsion; and (c) separating the dewaxed oil from the alkali solution at a temperature below about 20° C. after step (b).
Claim 9
Dependent Claim
25 words
A method according to claim 6 wherein step (b) comprises driving the stream through the interfacial surface mixer at a temperature below about 16° C.
Claim 10
Dependent Claim
25 words
A method according to claim 7 wherein step (c) comprises separating the refined oil from the alkali solution at a temperature below about 16° C.
Claim 11
Dependent Claim
27 words
A method according to claim 8 wherein the stream comprises from about 10 to about 25 wt. % of a 0.05 to 0.25 Normal sodium hydroxide solution.
Claim 12
Dependent Claim
52 words
A method according to claim 8 wherein the refined oil has been tempered at a temperature of from about 23° C. to about 40° C. for at least about 24 hours and then cooled to a temperature of from about 3° C. to about 16° C. for at least about 3 hours.
Claim 13
Dependent Claim
24 words
A method according to claim 6 wherein the refined oil is selected from the group consisting of safflower oil, corn oil and sunflower oil.
Claim 14
Dependent Claim
13 words
A method according to claim 6 wherein the refined oil comprises sunflower oil.
Claim 15
Independent Claim
176 words
A method for refining a wax-containing crude edible oil which has been tempered at a temperature of from about 23° C. to about 50° C. for at least about 24 hours and then cooled to a temperature of from about 3° C. to about 21° C. for at least about 5 hours, said method comprising the steps of: (a) forming a stream of from about 94 to about 99.9 wt. % cooled oil and from about 0.1 to about 6 wt. % of a 3.5 to 6.5 Normal aqueous alkali solution; (b) driving the stream through an interfacial surface mixer at a maximum temperature of about 38° C. so as to generate a mean droplet size in the alkali solution sufficiently small to mix with the oil, and to react with and remove the waxes therein, without forming an emulsion; and (c) heating the refined oil and alkali solution after step (b) to a temperature of from about 27° C. to about 60° C.; (d) separating the refined oil from the alkali solution after step (c).
Claim 16
Independent Claim
176 words
A method for refining a wax-containing crude edible oil which has been tempered at a temperature of from about 23° C. to about 50° C. for at least about 24 hours and then cooled to a temperature of from about 3° C. to about 21° C. for at least about 5 hours, said method comprising the steps of: (a) forming a stream of from about 94 to about 99.9 wt. % cooled oil and from about 0.1 to about 6 wt. % of a 3.5 to 6.5 Normal aqueous alkali solution; (b) driving the stream through an interfacial surface mixer at a maximum temperature of about 38° C. so as to generate a mean droplet size in the alkali solution sufficiently small to mix with the oil, and to react with and remove the waxes therein, without forming an emulsion; and (c) heating the refined oil and alkali solution after step (b) to a temperature of from about 27° C. to about 60° C.; (d) separating the refined oil from the alkali solution after step (c).
Claim 17
Dependent Claim
30 words
A method according to claim 13 wherein step (b) comprises driving the stream through the interfacial surface mixer at a temperature of from about 23° C. to about 32° C.
Claim 18
Dependent Claim
26 words
A method according to claim 14 wherein the stream comprises from about 0.25 to about 2.5 wt. % of 4.0 to 5.5 Normal sodium hydroxide solution.
Claim 19
Dependent Claim
46 words
A method according to claim 14 wherein the crude oil has been tempered at a temperature of from about 23° C. to about 40° C., and then cooled to a temperature of from about 3° C. to about 16° C. for at least about 12 hours.
Claim 20
Dependent Claim
24 words
A method according to claim 13 wherein the crude oil is selected from the group consisting of safflower oil, corn oil and sunflower oil.
Claim 21
Dependent Claim
13 words
A method according to claim 13 wherein the edible oil comprises sunflower oil.
Claim 22
Independent Claim
167 words
A method for refining and dewaxing a crude wax-containing edible oil which has been tempered at a temperature of from about 23° C. to about 50° C. for at least about 24 hours and then cooled to a temperature of from about 3° C. to about 21° C. for at least about 5 hours, said method comprising the steps of: (a) forming a stream of from about 94 to about 99.9 wt. % cooled oil and from about 0.1 to about 6 wt. % of a 2.5 to 6 Normal aqueous alkali solution; (b) driving the stream through an interfacial surface mixer at a temperature no higher than about 21° C. so as to generate a mean droplet size in the alkali solution sufficiently small to mix with the oil, and to react with and remove the waxes therein, without forming an emulsion; and (c) separating the refined and dewaxed oil from the alkali solution at a temperature no higher than about 21° C. after step (b).
Claim 23
Independent Claim
167 words
A method for refining and dewaxing a crude wax-containing edible oil which has been tempered at a temperature of from about 23° C. to about 50° C. for at least about 24 hours and then cooled to a temperature of from about 3° C. to about 21° C. for at least about 5 hours, said method comprising the steps of: (a) forming a stream of from about 94 to about 99.9 wt. % cooled oil and from about 0.1 to about 6 wt. % of a 2.5 to 6 Normal aqueous alkali solution; (b) driving the stream through an interfacial surface mixer at a temperature no higher than about 21° C. so as to generate a mean droplet size in the alkali solution sufficiently small to mix with the oil, and to react with and remove the waxes therein, without forming an emulsion; and (c) separating the refined and dewaxed oil from the alkali solution at a temperature no higher than about 21° C. after step (b).
Claim 24
Dependent Claim
30 words
A method according to claim 19 wherein step (b) comprises driving the stream through the interfacial surface mixer at a temperature of from about 3° C. to about 16° C.
Claim 25
Dependent Claim
27 words
A method according to claim 20 wherein step (c) comprises separating the refined and dewaxed oil from the alkali solution at a temperature below about 16° C.
Claim 26
Dependent Claim
27 words
A method according to claim 21 wherein the stream comprises from about 0.25 to about 5 wt. % of a 3.0 to 5.5 Normal sodium hydroxide solution.
Claim 27
Dependent Claim
46 words
A method according to claim 21 wherein the crude oil has been tempered at a temperature of from about 23° C. to about 40° C., and then cooled to a temperature of from about 3° C. to about 16° C. for at least about 12 hours.
Claim 28
Dependent Claim
24 words
A method according to claim 19 wherein the crude oil is selected from the group consisting of safflower oil, corn oil and sunflower oil.
Claim 29
Dependent Claim
13 words
A method according to claim 19 wherein the edible oil comprises sunflower oil.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-06-29 | 1984-12-29 | 1985-06-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-06-29 | 1988-12-29 | 1989-06-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-06-29 | 1992-12-29 | 1993-06-30 | $7700.00 | Window Closed / Lapsed |