US4276222A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of producing maleic anhydride
Assignee: Huntsman Corp
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Filing: 1979-12-26
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Granted: 1981-06-30
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Expires: 1999-12-26
Abstract
Abstract In the method for the preparation of maleic anhydride by oxidizing an aliphatic hydrocarbon in the presence of a phosphorus-vanadium-oxygen complex catalyst, the improvement which comprises employing a catalyst with enhanced surface adhesion thereby reducing attrition during preparation of the maleic anhydride.
Inventors
- 👤 Ramon A. Mount
- 👤 Warn D. Robinson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 10:08
CPC Classifications
C; C07; C07C; C07C51/00; C07C51/16; C07C51/21; C07C51/215; B; B01; B01J; B01J23/00; B01J23/002; B01J27/00; B01J27/14; B01J27/186; B01J27/195; B01J27/198; B01J2523/00
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
150 words
In a method for the preparation of maleic anhydride by oxidizing a reactant consisting essentially of a saturated aliphatic hydrocarbon having 4-10 carbon atoms in the presence of a phosphorus-vanadium-oxygen-containing complex catalyst prepared by the process comprising: (a) contacting vanadium and phosphorus compounds under conditions which will provide a catalyst precursor wherein greater than 50 atom % of the vanadium is in the tetravalent state; (b) recovering the catalyst precursor; (c) forming the catalyst precursor into agglomerates; and (d) calcining the catalyst precursor agglomerations at a temperature between about 300° C. and 600° C. the improvement comprising employing, as the catalyst, the product of the improved process wherein the catalyst precursor after being formed into agglomerates is wetted with an aqueous liquid in an amount sufficient to enhance surface adhesion and then dried prior to calcining whereby attrition of the catalyst during the oxidizing of the reactant is substantially reduced.
Claim 2
Dependent Claim
150 words
In a method for the preparation of maleic anhydride by oxidizing a reactant consisting essentially of a saturated aliphatic hydrocarbon having 4-10 carbon atoms in the presence of a phosphorus-vanadium-oxygen-containing complex catalyst prepared by the process comprising: (a) contacting vanadium and phosphorus compounds under conditions which will provide a catalyst precursor wherein greater than 50 atom % of the vanadium is in the tetravalent state; (b) recovering the catalyst precursor; (c) forming the catalyst precursor into agglomerates; and (d) calcining the catalyst precursor agglomerations at a temperature between about 300° C. and 600° C. the improvement comprising employing, as the catalyst, the product of the improved process wherein the catalyst precursor after being formed into agglomerates is wetted with an aqueous liquid in an amount sufficient to enhance surface adhesion and then dried prior to calcining whereby attrition of the catalyst during the oxidizing of the reactant is substantially reduced.
Claim 3
Dependent Claim
12 words
The method improvement of claim 1 wherein the aqueous liquid is water.
Claim 4
Dependent Claim
13 words
The method improvement of claim 1 wherein the aqueous liquid comprises an alcohol.
Claim 5
Dependent Claim
10 words
The method of claim 3 wherein the alcohol is methanol.
Claim 6
Dependent Claim
13 words
The method improvement of claim 1 wherein the aqueous liquid comprises a ketone.
Claim 7
Dependent Claim
10 words
The method of claim 5 wherein the ketone is acetone.
Claim 8
Dependent Claim
19 words
The method improvement of claim 1 wherein the catalyst precursor is wetted before and after being formed into agglomerates.
Claim 9
Dependent Claim
11 words
The method improvement of claim 1 wherein the agglomerates are granules.
Claim 10
Dependent Claim
12 words
The method improvement of claim 1 wherein the agglomerates are broken slugs.
Claim 11
Dependent Claim
11 words
The method improvement of claim 1 wherein the agglomerates are nodules.
Claim 12
Dependent Claim
11 words
The method improvement of claim 1 wherein the agglomerates are tablets.
Claim 13
Dependent Claim
11 words
The method improvement of claim 1 wherein the agglomerates are pills.
Claim 14
Dependent Claim
18 words
The method improvement of claim 1 wherein a surfactant is employed in the preparation of the catalyst precursor.
Claim 15
Dependent Claim
16 words
The method improvement of claim 1 wherein drying is accomplished at a temperature of 70°-250° C.
Claim 16
Dependent Claim
16 words
The method improvement of claim 1 wherein drying is accomplished at a temperature of 100°-150° C.
Claim 17
Dependent Claim
17 words
The method improvement of claim 1 wherein drying is accomplished at a temperature of about 125° C.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-06-29 | 1984-12-29 | 1985-06-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-06-29 | 1988-12-29 | 1989-06-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-06-29 | 1992-12-29 | 1993-06-30 | $7700.00 | Window Closed / Lapsed |