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US4276083A Expired / Lapsed US ⏱️ 0.0 years remaining

Recovery of metal values from a metal bearing source of nickel and vanadium

Assignee: Honeywell UOP LLC
•
Filing: 1979-11-01
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Granted: 1981-06-30
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Expires: 1999-11-01
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Abstract

Abstract Metal values may be recovered from metal bearing sources which contain at least two metals, at least one of which is in the form of a sulfide, by treating the aforesaid source with a mild oxidant at an elevated temperature in the range of from about 600° to about 1500° C. whereby at least one metal value is converted to an oxide and at least one metal value is converted to the elemental state which contains a relatively minor amount of sulfur. Thereafter the metal compounds may be separated and recovered by conventional means.

Inventors

  • 👤 William K. Tolley
  • 👤 William C. Laughlin
  • 👤 William Rostoker

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 18:00
CPC Classifications
C; C22; C22B; C22B23/00; C22B23/005; C22B34/00; C22B34/20; C22B34/22; Y; Y10; Y10S; Y10S502/00; Y10S502/515; Y10S502/516

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 74 words
A process for the recovery of metal values from a metal bearing source containing nickel and vanadium, the nickel being in the form of a sulfide, which comprises treating said source with a mild oxidant selected from the group consisting of carbon dioxide, water, sulfur dioxide, and mixtures thereof at conditions to convert the nickel sulfide to metal and the vanadium to an oxide, and separating the resultant metallic nickel from the vanadium oxide.
Claim 2
Dependent Claim 74 words
A process for the recovery of metal values from a metal bearing source containing nickel and vanadium, the nickel being in the form of a sulfide, which comprises treating said source with a mild oxidant selected from the group consisting of carbon dioxide, water, sulfur dioxide, and mixtures thereof at conditions to convert the nickel sulfide to metal and the vanadium to an oxide, and separating the resultant metallic nickel from the vanadium oxide.
Claim 3
Dependent Claim 32 words
The process as set forth in claim 1 in which said treatment with said mild oxidant is effected at a temperature in the range of from about 600° to about 1500° C.
Claim 4
Dependent Claim 16 words
The process as set forth in claim 1 in which said mild oxidant is carbon dioxide.
Claim 5
Dependent Claim 15 words
The process as set forth in claim 1 in which said mild oxidant is water.
Claim 6
Dependent Claim 21 words
The process as set forth in claim 1 in which said metal bearing source comprises a hydrocarbon feed containing metal contaminants.
Claim 7
Dependent Claim 19 words
The process as set forth in claim 5 in which said metal contaminants comprise nickel sulfide and vanadium sulfide.
Claim 8
Dependent Claim 27 words
The process as set forth in claim 5 in which said nickel bearing source is treated to remove volatile substituents prior to treatment with said mild oxidant.
Claim 9
Dependent Claim 18 words
The process as set forth in claim 7 in which said volatile substituents are removed by solvent extraction.
Claim 10
Dependent Claim 19 words
The process as set forth in claim 7 in which said volatile substituents are removed by distillation and pyrolysis.
Claim 11
Dependent Claim 29 words
The process as set forth in claim 9 in which said pyrolysis is effected at a temperature in the range of from about 350° C. to about 550° C.
Claim 12
Dependent Claim 25 words
The process as set forth in claim 1 in which the separation of the metallic nickel from the vanadium oxide is effected by magnetic separation.
Claim 13
Dependent Claim 24 words
The process as set forth in claim 1 in which the separation of the metallic nickel from the vanadium oxide is effected by flotation.
Claim 14
Dependent Claim 24 words
The process as set forth in claim 1 in which the separation of the metallic nickel from the vanadium oxide is effected by elution.

References Cited (Backward Citations)

US4163709A Cited
US4203759A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-06-29 1984-12-29 1985-06-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-06-29 1988-12-29 1989-06-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-06-29 1992-12-29 1993-06-30 $7700.00 Window Closed / Lapsed

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