US4275245A
Expired / Lapsed
US
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Process for obtaining halogenated diphenols
Assignee: General Electric Co
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Filing: 1979-07-16
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Granted: 1981-06-23
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Expires: 1999-07-16
Abstract
Abstract An improved process for obtaining halogenated diphenols which can be pure dihalodiphenols or predetermined, statistical mixtures comprising unreacted diphenol, monohalodiphenols and dihalodiphenols.
Inventors
- 👤 Victor Mark
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 04:07
CPC Classifications
C; C07; C07C; C07C37/00; C07C37/62; C07C315/00; C07C315/04; C07C39/00; C07C39/24; C07C39/367; C07C43/00; C07C43/02; C07C43/257; C07C43/295; C07C2601/00; C07C2601/12; C07C2601/14
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
176 words
A halogenated biphenol mixture having a significantly reduced quantity of trihalo substituted and tetrahalo substituted diphenol, said mixture containing predetermined, statistical quantities of unreacted diphenol, monohalodiphenol and dihalodiphenol, said halogenated diphenol being represented by the general formula: ##STR9## wherein Xm and Xn are chlorine, bromine and mixtures thereof with the proviso that either Xm or Xn is chlorine; Y is independently selected from the group consisting of C 1 -C 4 alkyl and hydrogen; m and n are each 0-2 with the proviso that m+n equal at least 0.1, but no more than 2.0; and, W is a member selected from the following group; (a) --CH 2 -- wherein r is an integer of 0-10 with the proviso that when both Xm and Xn are chlorine and m and n are each 1, r is or 2-10; ##STR10## wherein R is a member of the group consisting of C 1 -C 10 alkyl and C 6 -C 14 aryl; and, ##STR11## wherein R and R' can each independently be the same as R in (b) above.
Claim 2
Dependent Claim
176 words
A halogenated biphenol mixture having a significantly reduced quantity of trihalo substituted and tetrahalo substituted diphenol, said mixture containing predetermined, statistical quantities of unreacted diphenol, monohalodiphenol and dihalodiphenol, said halogenated diphenol being represented by the general formula: ##STR9## wherein Xm and Xn are chlorine, bromine and mixtures thereof with the proviso that either Xm or Xn is chlorine; Y is independently selected from the group consisting of C 1 -C 4 alkyl and hydrogen; m and n are each 0-2 with the proviso that m+n equal at least 0.1, but no more than 2.0; and, W is a member selected from the following group; (a) --CH 2 -- wherein r is an integer of 0-10 with the proviso that when both Xm and Xn are chlorine and m and n are each 1, r is or 2-10; ##STR10## wherein R is a member of the group consisting of C 1 -C 10 alkyl and C 6 -C 14 aryl; and, ##STR11## wherein R and R' can each independently be the same as R in (b) above.
Claim 3
Dependent Claim
12 words
The halogenated diphenol of claim 1 wherein said diphenol is 2,2-bis(4-hydroxyphenyl) propane.
Claim 4
Dependent Claim
10 words
The halogenated diphenol of claim 1 wherein W is (b).
Claim 5
Dependent Claim
10 words
The halogenated diphenol of claim 1 wherein W is (c).
Claim 6
Dependent Claim
17 words
The halogenated diphenol of claim 1 wherein Xm and Xn are each chlorine and m+n equal 2.0.
Claim 7
Dependent Claim
17 words
The halogenated diphenol of claim 1 wherein Xm is chlorine, Xn is bromine and m+n equal 2.0.
Claim 8
Dependent Claim
10 words
The halogenated diphenol of claim 5 wherein Y is hydrogen.
Claim 9
Dependent Claim
12 words
The halogenated diphenol of claim 5 wherein Y is CH 3 .
References Cited (Backward Citations)
DE2520317A1
Cited
US4075119A
Cited
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