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US4274996A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermally stabilizing polymers of ethylene

Assignee: Phillips Petroleum Co
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Filing: 1979-11-01
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Granted: 1981-06-23
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Expires: 1999-11-01
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Abstract

Abstract A method for improving the thermal stability of polymer of ethylene having vinyl unsaturation in which the polymer is admixed with a stabilizing amount of a silane compound represented by the formulae R 2 SiA 2 and R 3 SiA' in which each R is the same or different and is selected from aryl, alkaryl, or aralkyl groups containing from 6 to about 24 carbon atoms, each A is the same or different and is selected from hydrogen, azido, halogen, hydroxy, alkoxy groups in which the alkyl radical contains from 1 to about 10 carbon atoms, and alkenyl of 2 to 6 carbon atoms and one A can be lower alkyl of 1 to 6 carbon atoms with the other A selected from among azido, halogen, hydroxy, and alkoxy, lower alkyl and alkenyl as described above, and A' is selected from among halogen, hydrogen and hydroxy groups. The composition of matter produced thereby. A composition of matter containing a polymer of ethylene and a thermally stabilizing amount of a silane represented by the formulae R 2 SiA 2 and R 3 SiA' in which each R is the same or different and is selected from aryl, alkaryl, or aralkyl groups containing from 6 to about 24 carbon atoms, each A is the same or different and is selected from hydrogen, azido, halogen, hydroxy, alkoxy groups in which the alkyl radical contains from 1 to about 10 carbon atoms, and alkenyl of 2 to 6 carbon atoms and one A can be lower alkyl of 1 to 6 carbon atoms with the other A selected from among azido, halogen, hydroxy, and alkoxy, lower alkyl and alkenyl as described above, and A' is selected from among halogen, hydrogen, and hydroxy groups.

Inventors

  • 👤 Gil R. Hawley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 11:54
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/54

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 151 words
A method for improving the thermal stability of polymers of ethylene having vinyl unsaturation, said method comprising admixing with said polymers of ethylene a thermally stabilizing amount of a silane compound represented by the formula R 2 SiA 2 or R 3 SiA' in which each R is the same or different and is selected from aryl, alkaryl, or aralkyl groups containing from 6 to about 24 carbon atoms, each A is the same or different and is selected from hydrogen, azido, halogen, hydroxy, alkoxy groups in which the alkyl radical contains from 1 to about 10 carbon atoms, and alkenyl of 2 to 6 carbon atoms also in which one A can be lower alkyl of 1 to 6 carbon atoms with the other A selected from among azido, halogen, hydroxy, alkoxy, lower alkyl and alkenyl as described above, and A' is selected from among halogen, hydrogen and hydroxy groups.
Claim 2
Independent Claim 151 words
A method for improving the thermal stability of polymers of ethylene having vinyl unsaturation, said method comprising admixing with said polymers of ethylene a thermally stabilizing amount of a silane compound represented by the formula R 2 SiA 2 or R 3 SiA' in which each R is the same or different and is selected from aryl, alkaryl, or aralkyl groups containing from 6 to about 24 carbon atoms, each A is the same or different and is selected from hydrogen, azido, halogen, hydroxy, alkoxy groups in which the alkyl radical contains from 1 to about 10 carbon atoms, and alkenyl of 2 to 6 carbon atoms also in which one A can be lower alkyl of 1 to 6 carbon atoms with the other A selected from among azido, halogen, hydroxy, alkoxy, lower alkyl and alkenyl as described above, and A' is selected from among halogen, hydrogen and hydroxy groups.
Claim 3
Dependent Claim 26 words
A method of claim 1 in which the amount of silane is in a range of about 0.05 to about 5 g per 100 g polymer.
Claim 4
Dependent Claim 39 words
A method of claim 1 wherein said ethylene polymers containing vinyl groups are homopolymers of ethylene or copolymers of ethylene with up to 20 mole percent of another aliphatic mono-1-olefin containing from about 3 to about 10 carbon atoms.
Claim 5
Dependent Claim 11 words
A thermally stabilized composition produced by the method of claim 1.
Claim 6
Dependent Claim 139 words
A composition of matter comprising a polymer of ethylene and a thermally stabilizing amount of a silane compound represented by the formula R 2 SiA 2 or R 3 SiA' in which each R is the same or different and is selected from aryl, alkaryl, or aralkyl groups containing from 6 to about 24 carbon atoms, each A is the same or different and is selected from hydrogen, azido, halogen, hydroxy, alkoxy groups in which the alkyl radical contains from 1 to about 10 carbon atoms, and alkenyl of 2 to 6 carbon atoms, and wherein one A being selected from lower alkyl of 1 to 6 carbon atoms the other A is selected from among azido, halogen, hydroxy, and alkoxy, lower alkyl and alkenyl as described above, and A' is selected from among halogen, hydrogen and hydroxy groups.
Claim 7
Dependent Claim 139 words
A composition of matter comprising a polymer of ethylene and a thermally stabilizing amount of a silane compound represented by the formula R 2 SiA 2 or R 3 SiA' in which each R is the same or different and is selected from aryl, alkaryl, or aralkyl groups containing from 6 to about 24 carbon atoms, each A is the same or different and is selected from hydrogen, azido, halogen, hydroxy, alkoxy groups in which the alkyl radical contains from 1 to about 10 carbon atoms, and alkenyl of 2 to 6 carbon atoms, and wherein one A being selected from lower alkyl of 1 to 6 carbon atoms the other A is selected from among azido, halogen, hydroxy, and alkoxy, lower alkyl and alkenyl as described above, and A' is selected from among halogen, hydrogen and hydroxy groups.
Claim 8
Dependent Claim 30 words
A composition of matter of claim 5 wherein said silane compound is present in an amount in the range of about 0.05 to about 5 g per 100 g polymer.
Claim 9
Dependent Claim 42 words
A composition of matter of claim 5 wherein said ethylene polymers containing vinyl groups are homopolymers of ethylene or copolymers of ethylene with up to about 20 mole percent of another aliphatic mono-1-olefin containing from about 3 to about 10 carbon atoms.

References Cited (Backward Citations)

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US3738959A Cited
US3808172A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-06-22 1984-12-22 1985-06-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-06-22 1988-12-22 1989-06-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-06-22 1992-12-22 1993-06-23 $7700.00 Window Closed / Lapsed

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