US4273667A
Expired / Lapsed
US
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Thermal energy storage material comprising hydrated compound and water-swollen cross-linked polymer
Assignee: IC Gas International Ltd
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Filing: 1980-02-27
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Granted: 1981-06-16
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Expires: 2000-02-27
Abstract
Abstract The thermal energy storage material comprises at least one hydrated compound (such as an inorganic salt) having a reversible transition to the anhydrous or a less hydrated form and a hydrogel, comprising a water-swollen cross-linked polymer formed by cross-linking a synthetic hydrophilic polymer by a covalent cross-linking mechanism, throughout which the compound is dispersed. The hydrogel is made by reacting a water-soluble or water-dispersible synthetic hydrophilic polymer, which is preferably linear and thermoplastic, with a cross-linking agent therefor in an aqueous medium containing the hydrated compound. The hydrophilic polymer, the aqueous medium and the hydrated compound are used in such amounts that the storage material contains a major proportion, by weight, of the hydrated compound and a minor proportion, by weight, of the cross-linked polymer.
Inventors
- 👤 Peter J. C. Kent
- 👤 John K. R. Page
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 22:23
CPC Classifications
C; C09; C09K; C09K5/00; C09K5/02; C09K5/06; C09K5/063
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
61 words
In a thermal energy storage material which comprises at least one hydrated compound which has a reversible transition to the anhydrous or a less hydrated form and a minor amount of hydrogel throughout which said compound is dispersed, the improvement comprising that the hydrogel comprises a water-swollen cross-linked polymer formed by cross-linking a synthetic hydrophilic polymer by a covalent cross-linking mechanism.
Claim 2
Dependent Claim
61 words
In a thermal energy storage material which comprises at least one hydrated compound which has a reversible transition to the anhydrous or a less hydrated form and a minor amount of hydrogel throughout which said compound is dispersed, the improvement comprising that the hydrogel comprises a water-swollen cross-linked polymer formed by cross-linking a synthetic hydrophilic polymer by a covalent cross-linking mechanism.
Claim 3
Dependent Claim
42 words
A thermal energy storage material according to claim 1, wherein said synthetic hydrophilic polymer has functional groups selected from the group consisting of hydroxy, carboxy and amide groups, said functional groups being reacted with a cross-linking agent to form said cross-linked polymer.
Claim 4
Dependent Claim
40 words
A thermal energy storage material according to claim 1, wherein said synthetic hydrophilic polymer has groups which have been reacted with a cross-linking agent selected from the group consisting of an aldehyde, a polyfunctional isocyanate and a polyfunctional carboxylic acid.
Claim 5
Dependent Claim
38 words
A thermal energy storage material according to claim 3, wherein said synthetic hydrophilic polymer is selected from the group consisting of polyvinyl alcohol, a hydroxyalkyl acrylate polymer, a methacrylamide polymer, an acrylamide polymer and a hydroxyalkyl methacrylate polymer.
Claim 6
Dependent Claim
22 words
A thermal energy storage material as set forth in claim 3 in which the groups which have been reacted are hydroxy groups.
Claim 7
Dependent Claim
95 words
In a method of preparing a thermal energy storage material which comprises a hydrogel having dispersed therein a hydrated compound which has a transition temperature to the anhydrous or a less hydrated form in the range 0° to 100° C., the improvement comprising that the hydrogel is formed by reacting a water-soluble synthetic hydrophilic thermoplastic addition polymer having a substantially linear carbon-carbon backbone and active hydrogen atoms in pendant groups thereof with a cross-linking agent therefor in an aqueous medium containing said hydrated compound, such that the resulting hydrogel comprises a water-swollen, covalently cross-linked polymer.
Claim 8
Dependent Claim
95 words
In a method of preparing a thermal energy storage material which comprises a hydrogel having dispersed therein a hydrated compound which has a transition temperature to the anhydrous or a less hydrated form in the range 0° to 100° C., the improvement comprising that the hydrogel is formed by reacting a water-soluble synthetic hydrophilic thermoplastic addition polymer having a substantially linear carbon-carbon backbone and active hydrogen atoms in pendant groups thereof with a cross-linking agent therefor in an aqueous medium containing said hydrated compound, such that the resulting hydrogel comprises a water-swollen, covalently cross-linked polymer.
Claim 9
Dependent Claim
22 words
A method according to claim 6, wherein said active hydrogen atoms are present in amide groups and said cross-linking agent is formaldehyde.
Claim 10
Dependent Claim
51 words
A method according to claim 6, wherein said polymer has pendant acid groups and wherein the reaction is carried out in the presence of a water-soluble salt of a polyvalent metal, such that the cross-linked polymer is cross-linked by cations of said polyvalent metal as well as by said cross-linking agent.
Claim 11
Dependent Claim
87 words
In a method of extracting heat by passing a fluid in heat-exchange relationship with a thermal energy storage material comprising at least one hydrated inorganic salt selected from the group consisting of sodium sulphate decahydrate, disodium hydrogen phosphate dodecahydrate, sodium thiosulphate pentahydrate, sodium carbonate decahydrate and calcium chloride hexahydrate and a minor amount of a hydrogel throughout which said salt is dispersed, the improvement comprising that the hydrogel comprises a water-swollen cross-linked polymer formed by cross-linking a water-soluble linear synthetic thermoplastic polymer by a covalent cross-linking mechanism.
Claim 12
Dependent Claim
87 words
In a method of extracting heat by passing a fluid in heat-exchange relationship with a thermal energy storage material comprising at least one hydrated inorganic salt selected from the group consisting of sodium sulphate decahydrate, disodium hydrogen phosphate dodecahydrate, sodium thiosulphate pentahydrate, sodium carbonate decahydrate and calcium chloride hexahydrate and a minor amount of a hydrogel throughout which said salt is dispersed, the improvement comprising that the hydrogel comprises a water-swollen cross-linked polymer formed by cross-linking a water-soluble linear synthetic thermoplastic polymer by a covalent cross-linking mechanism.
Claim 13
Dependent Claim
18 words
A method according to claim 9, wherein said polymer contains acrylamide repeating units and acrylic acid repeating units.
Claim 14
Dependent Claim
16 words
A method according to claim 10, wherein said polymer has been cross-linked by means of formaldehyde.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-06-15 | 1984-12-15 | 1985-06-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-06-15 | 1988-12-15 | 1989-06-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-06-15 | 1992-12-15 | 1993-06-16 | $7700.00 | Window Closed / Lapsed |