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US4272497A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for treating a nitrogen oxide- and sulphur oxide-containing waste gas

Assignee: Electric Power Development Co Ltd
•
Filing: 1980-07-28
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Granted: 1981-06-09
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Expires: 2000-07-28
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Abstract

Abstract A method for treating a nitrogen oxide- and sulphur oxide-containing waste gas, in which gaseous ammonia is mixed with said waste gas, the resulting mixed gas is passed in the cross current direction through a first reactor provided with a moving bed of carbonaceous catalyst particles adapted to move downwards, the gas having passed through the upper part of said reaction is discharged outside of the reactor without undergoing treatment, the gas having passed through the lower part of the reactor is mixed with a fresh gaseous ammonia, and this mixed gas is passed in the cross current direction through a second reactor provided with a moving bed of carbonaceous catalyst particles adapted to move downwards and then discharged outside of the reactor.

Inventors

  • 👤 Kazuyoshi Takahashi
  • 👤 Hiromi Tanaka

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 17:59
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8637; B01J; B01J8/00; B01J8/08; B01J8/12

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 128 words
A method for removing nitrogen oxides and sulphur oxides from waste gas which comprises the steps of: mixing gaseous ammonia with a nitrogen oxide- and sulphur oxide-containing waste gas; passing the resulting mixed gas in a cross current direction through a first reactor provided with a moving bed of carbonaceous catalyst adapted to move downwards; introducing the gas passed through the upper part of said reactor into a flue without undergoing any treatment; re-mixing the gas passed through the bottom part of the reactor with a fresh gaseous ammonia; thereafter allowing said mixed gas to pass in a cross current direction through a second reactor provided with a moving bed of carbonaceous catalyst adapted to move downwards; and introducing the gas passed through said reactor into the flue.
Claim 2
Independent Claim 128 words
A method for removing nitrogen oxides and sulphur oxides from waste gas which comprises the steps of: mixing gaseous ammonia with a nitrogen oxide- and sulphur oxide-containing waste gas; passing the resulting mixed gas in a cross current direction through a first reactor provided with a moving bed of carbonaceous catalyst adapted to move downwards; introducing the gas passed through the upper part of said reactor into a flue without undergoing any treatment; re-mixing the gas passed through the bottom part of the reactor with a fresh gaseous ammonia; thereafter allowing said mixed gas to pass in a cross current direction through a second reactor provided with a moving bed of carbonaceous catalyst adapted to move downwards; and introducing the gas passed through said reactor into the flue.
Claim 3
Dependent Claim 26 words
A method as claimed in claim 1, wherein said carbonaceous catalyst is activated carbon, charcoal, coal, coke or one of these materials supporting oxidized metal thereon.
Claim 4
Dependent Claim 40 words
A method as claimed in claim 1, wherein the quantity of ammonia to be injected in the gas supplied to each reactor is determined by the following formula: Quantity of ammonia to be injected=(Concentration of NOx)×(Denitrification efficiency)+(Concentration of SOx)×(Desulphurization efficiency)×(0.1-1.0).
Claim 5
Dependent Claim 40 words
A method as claimed in claim 1, wherein the quantity of ammonia to be injected in the gas supplied to each reactor is determined by the following formula: Quantity of ammonia to be injected=(Concentration of NOx)×(Denitrification efficiency)+(Concentration of SOx)×(Desulphurization efficiency)×(0.3-0.6).
Claim 6
Dependent Claim 63 words
A method as claimed in claim 1 which comprises providing, downstream of the second reactor, a third reactor having a moving bed of carbonaceous catalyst adapted to move downwards, and allowing the gas passed through the bottom part of the second reactor after it has been mixed with a fresh gaseous ammonia to pass through the third reactor in a cross current direction.
Claim 7
Dependent Claim 63 words
A method as claimed in claim 1 which comprises connecting four or more reactors in series, said reactor having a moving bed of carbonaceous catalyst adapted to move downwards, and allowing the gas passed through the bottom part of one upstream reactor after it has been mixed with gaseous ammonia to pass through a downstream reactor adjacent thereto in a cross current direction.
Claim 8
Dependent Claim 62 words
A method as claimed in claim 1 which comprises supplying the carbonaceous catalyst derived at the bottom of the second reactor, without undergoing regeneration, to the top part of the first reactor and supplying the carbonaceous catalyst derived at the bottom of the first reactor, after it has been regenerated, to the top part of each of the first and second reactors.

References Cited (Backward Citations)

NL7409500A Cited
US4003711A Cited
US4044102A Cited
JPS5228462A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-06-08 1984-12-08 1985-06-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-06-08 1988-12-08 1989-06-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-06-08 1992-12-08 1993-06-09 $7700.00 Window Closed / Lapsed

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