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US4272292A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat transfer printing

Assignee: Dai Nippon Printing Co Ltd
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Filing: 1978-11-22
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Granted: 1981-06-09
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Expires: 1998-11-22
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Abstract

Abstract An ink composition for heat transfer printing comprising at least one of carbinol bases of basic dyes or their derivatives, a strong base, a binder and a solvent for dissolving the binder. This ink composition is excellent in storage stability because it contains a carbinol base of a basic dye or its derivative in isolated form as a coloring agent along with a strong base. By using this ink composition, a transfer sheet having high storage stability can be obtained.

Inventors

  • 👤 Shogo Mizuno
  • 👤 Kyoichi Shimomura
  • 👤 Michiaki Kobayashi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 05:37
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/02; C09D11/03; C09D11/033; B; B41; B41M; B41M5/00; B41M5/025; B41M5/035; B41M5/0356; D; D06; D06P; D06P5/00; D06P5/003; D06P5/004; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24843; Y10T428/24893; Y10T428/24901; Y10T428/24934; Y10T428/27; Y10T428/273; Y10T428/277

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 133 words
An ink composition for heat transfer printing having enhanced stability on storage comprising: from about 0.1 to about 10 weight percent of a coloring agent comprising at least one of a carbinol base of a basic dye or a carbinol base derivative, wherein said derivative is the product of the reaction between said basic dye and an alcoholate, and said coloring agent is sublimable at a temperature of from about 80° to about 250° C.; from about 0.1 to about 10 weight percent of a strong base, wherein the mole ratio of said strong base to said coloring agent is from about 1:1 to about 40:1; from about 5 to about 20 weight percent of a binder; and a solvent; wherein all weight percents are based on the total weight of the composition.
Claim 2
Dependent Claim 133 words
An ink composition for heat transfer printing having enhanced stability on storage comprising: from about 0.1 to about 10 weight percent of a coloring agent comprising at least one of a carbinol base of a basic dye or a carbinol base derivative, wherein said derivative is the product of the reaction between said basic dye and an alcoholate, and said coloring agent is sublimable at a temperature of from about 80° to about 250° C.; from about 0.1 to about 10 weight percent of a strong base, wherein the mole ratio of said strong base to said coloring agent is from about 1:1 to about 40:1; from about 5 to about 20 weight percent of a binder; and a solvent; wherein all weight percents are based on the total weight of the composition.
Claim 3
Dependent Claim 30 words
An ink composition as claimed in claim 1 in which the strong base is selected from the group consisting of hydroxides and alcoholates of alkali metals and alkaline earth metals.
Claim 4
Dependent Claim 19 words
An ink composition as claimed in claim 2 in which the strong base is sodium hydroxide or potassium hydroxide.
Claim 5
Dependent Claim 39 words
An ink composition as claimed in claim 1 in which the binder is selected from the group consisting of ethyl cellulose, ethylhydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, polyvinyl alcohol, polyvinyl formal, polyvinyl butyral, polyvinyl acetate, and polyvinyl pyrrolidone.
Claim 6
Dependent Claim 39 words
An ink composition as claimed in claim 1 in which the solvent contains 80% by weight or more based on the total weight of the solvent of a monohydric alcohol, having a total of 3 to 6 carbon atoms.
Claim 7
Dependent Claim 65 words
An ink composition as claimed in claim 1 in which the solvent contains a monohydric alcohol having a total of 3 to 6 carbon atoms, and a secondary solvent selected from the group consisting of butyl acelate, isopropyl acetate, toluene, xylene, and methyl isobutyl ketone in a quantity of a total of 80% by weight or more based on the total weight of the solvent.
Claim 8
Dependent Claim 30 words
An ink composition as claimed in claim 6 in which the ratio of the monohydric alcohol to the secondary solvent component used is 2/8 to 4/6 on a weight basis.
Claim 9
Dependent Claim 40 words
An ink composition as claimed in claim 1, which composition further comprises a conventional quantity of a conventional additive selected from the group consisting of plasticizers, stabilizers, waxes, greases, drying agents, hardening agents, emulsifiers, dispersants, and non-sublimable pigments and dyes.
Claim 10
Dependent Claim 58 words
An ink composition according to claim 1 wherein said carbinol base derivative is selected from the group of compounds of the formula: Dy--O--R wherein: Dy is a cationic moiety of a basic dye; R is selected from the group consisting of an alkyl group having from 1 to 4 carbon atoms, a benzyl group and a phenyl group.

References Cited (Backward Citations)

US3969071A Cited
US4040779A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-06-08 1984-12-08 1985-06-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-06-08 1988-12-08 1989-06-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-06-08 1992-12-08 1993-06-09 $7700.00 Window Closed / Lapsed

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