US4269972A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for producing cellulose diacetate having improved resistance to delustering phenomenon in hot water
Assignee: Daicel Corp
•
Filing: 1979-06-11
•
Granted: 1981-05-26
•
Expires: 1999-06-11
Abstract
Abstract Cellulose diacetate having improved resistance to delustering in hot water is produced by acetylation cellulose in the presence of a catalyst and then hydrolyzing (or ripening) the product to form secondary cellulose acetate; wherein the catalyst in the acetylated mixture is completely neutralized before about the middle of the hydrolysis reaction at the latest and thereafter hydrolysis is carried out at a temperature of about 110° to 120° C. while maintaining the concentration of acetic acid in the reaction mixture at about 67 to 78% by weight based on the total weight of the acetic acid and water, the relation between the hydrolysis temperature and the concentration of acetic acid being defined by the area between and including points A, B, C and D in FIG. 2.
Inventors
- 👤 Hideo Yabune
- 👤 Yoshiyuki Ikemoto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 22:41
CPC Classifications
C; C08; C08B; C08B3/00; C08B3/06
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
100 words
A process for producing cellulose diacetate having reduced delustering tendency in hot water which comprises acetylating cellulose in the presence of an acetylation catalyst and hydrolyzing the product to form secondary cellulose acetate, with the process further comprising completely neutralizing the acetylation catalyst before at least the middle stage of the hydrolysis reaction while maintaining the temperature and concentration of the bath within the area defined by and including the points A (110, 78), B (110, 71), C (120, 67), and D (120, 75), in rectangular coordinates (degree C., % by weight) shown in FIG. 2 in the accompanying drawings.
Claim 2
Dependent Claim
100 words
A process for producing cellulose diacetate having reduced delustering tendency in hot water which comprises acetylating cellulose in the presence of an acetylation catalyst and hydrolyzing the product to form secondary cellulose acetate, with the process further comprising completely neutralizing the acetylation catalyst before at least the middle stage of the hydrolysis reaction while maintaining the temperature and concentration of the bath within the area defined by and including the points A (110, 78), B (110, 71), C (120, 67), and D (120, 75), in rectangular coordinates (degree C., % by weight) shown in FIG. 2 in the accompanying drawings.
Claim 3
Dependent Claim
15 words
The process of claim 1, wherein said catalyst is completely neutralized before said hydrolyzing step.
Claim 4
Dependent Claim
27 words
The process of claim 1, wherein said catalyst is completely neutralized after the initiation of said hydrolyzing step but before the middle stage of said hydrolysis reaction.
Claim 5
Dependent Claim
37 words
The process of claim 1, wherein after neutralizing said catalyst, water is added to the hydrolysis bath to adjust the bath concentration to the area defined by said points A, B, C and D in FIG. 2.
Claim 6
Dependent Claim
16 words
The process of claim 1, wherein said catalyst is neutralized at about 60° to 75° C.
Claim 7
Dependent Claim
79 words
A process for producing cellulose diacetate having reduced delustering tendency in hot water which comprises acetylating cellulose in the presence of an acetylation catalyst, neutralizing the acetylation catalyst, adding water to the acetylation bath to adjust the bath concentration within the area defined by the points A (110, 78), B (110, 71), C (120, 67), and D (120, 75) in rectangular coordinates (degree C., % by weight) in FIG. 2, and hydrolyzing the product to form secondary cellulose acetate.
Claim 8
Dependent Claim
79 words
A process for producing cellulose diacetate having reduced delustering tendency in hot water which comprises acetylating cellulose in the presence of an acetylation catalyst, neutralizing the acetylation catalyst, adding water to the acetylation bath to adjust the bath concentration within the area defined by the points A (110, 78), B (110, 71), C (120, 67), and D (120, 75) in rectangular coordinates (degree C., % by weight) in FIG. 2, and hydrolyzing the product to form secondary cellulose acetate.
References Cited (Backward Citations)
US2095326A
Cited
US2432153A
Cited
US2432341A
Cited
US2523384A
Cited
GB638316A
Cited
US2607771A
Cited
US2775584A
Cited
US2772266A
Cited
US3505313A
Cited
US3485816A
Cited
US3595854A
Cited
US3767642A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-05-25 | 1984-11-24 | 1985-05-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-05-25 | 1988-11-24 | 1989-05-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-05-25 | 1992-11-24 | 1993-05-26 | $7700.00 | Window Closed / Lapsed |