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US4269744A Expired / Lapsed US ⏱️ 0.0 years remaining

Vinyl halide stabilizer compositions

Assignee: Vibrantz Corp
•
Filing: 1979-06-04
•
Granted: 1981-05-26
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Expires: 1999-06-04
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Abstract

Abstract A vinyl halide resin stabilizer composition which essentially contains: (a) a calcium, zinc or mixed calcium/zinc salt of a higher fatty acid; (b) a polyhydroxy alcohol component wherein at least 50% of this component is either di-or tri-pentaerythritol; and (c) a magnesium compound, particularly magnesium hydroxide or magnesium acetate These compositions synergistically contribute to the heat stability of vinyl halide resin compositions and offer significant heat stabilization economies. Early color as well as long term heat stability performances of the metal salt compounds are improved in the compositions disclosed thereby permitting the reduction in amounts of such compounds needed for stabilization.

Inventors

  • 👤 Ramchandra K. Hulyalkar
  • 👤 Gerald A. Baum

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 16:56
CPC Classifications
C; C08; C08K; C08K13/00; C08K13/02

Claims Analysis

Total Claims: 37
Claim 1
Independent Claim 77 words
A resin heat stabilizer composition which consists essentially of a metal salt of a higher fatty acid, a polyhydric alcohol selected from the group consisting of dipentaerythritol, tripentaerythritol, mixtures of dipentaerythritol and tripentaerythritol, and mixtures of dipentaerythritol and tripentaerythritol, individually and in combination, with any of pentaerythritol, mannitol, sorbitol and mixtures thereof, and a magnesium compound selected from the group consisting of magnesium oxide, magnesium hydroxide, magnesium acetate, magnesium carbonate, magnesium citrate, magnesium phosphate and mixtures thereof.
Claim 2
Dependent Claim 77 words
A resin heat stabilizer composition which consists essentially of a metal salt of a higher fatty acid, a polyhydric alcohol selected from the group consisting of dipentaerythritol, tripentaerythritol, mixtures of dipentaerythritol and tripentaerythritol, and mixtures of dipentaerythritol and tripentaerythritol, individually and in combination, with any of pentaerythritol, mannitol, sorbitol and mixtures thereof, and a magnesium compound selected from the group consisting of magnesium oxide, magnesium hydroxide, magnesium acetate, magnesium carbonate, magnesium citrate, magnesium phosphate and mixtures thereof.
Claim 3
Dependent Claim 30 words
A composition according to claim 1 wherein the metal salt is calcium, zinc, a mixed calcium/zinc salt or a mixture of calcium and zinc salts of a higher fatty acid.
Claim 4
Dependent Claim 30 words
A composition according to claim 2 wherein the proportion of the metal salt component to the polyhydric alcohol component is from about 1 to 9 to about 9 to 1.
Claim 5
Dependent Claim 13 words
A composition according to claim 3 wherein the metal salt is zinc stearate.
Claim 6
Dependent Claim 15 words
A composition according to claim 3 wherein the metal salt is a mixed calcium-zinc stearate.
Claim 7
Dependent Claim 20 words
A composition according to claim 3 wherein the metal salt component is a mixture of calcium stearate and zinc stearate.
Claim 8
Dependent Claim 12 words
A composition according to claim 3 wherein the polyhydric alcohol is dipentaerythritol.
Claim 9
Dependent Claim 12 words
A composition according to claim 3 wherein the polyhydric alcohol is tripentaerythritol.
Claim 10
Dependent Claim 21 words
A composition according to claim 3 wherein the polyhydric alcohol is a 1 to 1 mixture of dipentaerythritol to a pentaerythritol.
Claim 11
Dependent Claim 13 words
A composition according to claim 2 wherein the magnesium compound is magnesium acetate.
Claim 12
Dependent Claim 13 words
A composition according to claim 2 wherein the magnesium compound is magnesium hydroxide.
Claim 13
Dependent Claim 13 words
A composition according to claim 2 wherein the magnesium compound is magnesium oxide.
Claim 14
Dependent Claim 19 words
A composition according to claim 2 wherein the magnesium component is a mixture of magnesium hydroxide and magnesium acetate.
Claim 15
Dependent Claim 91 words
A vinyl halide resin composition which comprises a vinyl halide resin and, as a stabilizer an effective amount of a composition consisting essentially of a metal salt of a higher fatty acid, a polyhydric alcohol selected from the group consisting of dipentaerythritol, tripentaerythritol, mixtures of dipentaerythritol and tripentaerythritol; and mixtures of dipentaerythritol and tripentaerythritol, individually and in combination, with any of pentaerythritol, mannitol, sorbitol and mixtures thereof and a magnesium compound from the group consisting of magnesium oxide, magnesium hydroxide, magnesium acetate, magnesium carbonate, magnesium citrate, magnesium phosphate and mixtures thereof.
Claim 16
Dependent Claim 91 words
A vinyl halide resin composition which comprises a vinyl halide resin and, as a stabilizer an effective amount of a composition consisting essentially of a metal salt of a higher fatty acid, a polyhydric alcohol selected from the group consisting of dipentaerythritol, tripentaerythritol, mixtures of dipentaerythritol and tripentaerythritol; and mixtures of dipentaerythritol and tripentaerythritol, individually and in combination, with any of pentaerythritol, mannitol, sorbitol and mixtures thereof and a magnesium compound from the group consisting of magnesium oxide, magnesium hydroxide, magnesium acetate, magnesium carbonate, magnesium citrate, magnesium phosphate and mixtures thereof.
Claim 17
Dependent Claim 16 words
A composition according to claim 14, wherein the vinyl halide resin is a vinyl chloride resin.
Claim 18
Dependent Claim 29 words
A composition according to claim 15 wherein the metal salt is calcium, zinc, a mixed calcium/zinc, or a mixture of calcium and zinc salts of a higher fatty acid.
Claim 19
Dependent Claim 30 words
A composition according to claim 16 wherein the proportion of the metal salt component to the polyhydric alcohol component is from about 1 to 9 to about 9 to 1.
Claim 20
Dependent Claim 13 words
A composition according to claim 16 wherein the metal salt is zinc stearate.
Claim 21
Dependent Claim 15 words
A composition according to claim 16 wherein the metal salt is a mixed calcium-zinc stearate.
Claim 22
Dependent Claim 20 words
A composition according to claim 16 wherein the metal salt component is a mixture of calcium stearate and zinc stearate.
Claim 23
Dependent Claim 12 words
A composition according to claim 16 wherein the polyhydric alcohol is dipentaerythritol.
Claim 24
Dependent Claim 12 words
A composition according to claim 16 wherein the polyhydric alcohol is tripentaerythritol.
Claim 25
Dependent Claim 13 words
A composition according to claim 16 wherein the magnesium compound is magnesium acetate.
Claim 26
Dependent Claim 13 words
A composition according to claim 16 wherein the magnesium compound is magnesium hydroxide.
Claim 27
Dependent Claim 19 words
A composition according to claim 16 wherein the magnesium component is a mixture of magnesium hydroxide and magnesium acetate.
Claim 28
Dependent Claim 20 words
A composition according to claim 17 wherein the polyhydric alcohol is a 1 to 1 mixture of dipentaerythritol to pentaerythritol.
Claim 29
Dependent Claim 24 words
A composition according to claim 15 wherein the proportion of resin to stabilizer is from about 100 to 0.5 to about 100 to 5.
Claim 30
Dependent Claim 32 words
A vinyl halide resin composition which comprises 100 parts of a vinyl chloride resin and of a stabilizer consisting essentially of 0.5 to 5 parts of zinc stearate, dipentaerythritol and magnesium acetate.
Claim 31
Dependent Claim 32 words
A vinyl halide resin composition which comprises 100 parts of a vinyl chloride resin and of a stabilizer consisting essentially of 0.5 to 5 parts of zinc stearate, dipentaerythritol and magnesium acetate.
Claim 32
Dependent Claim 32 words
A vinyl halide resin composition which comprises 100 parts of a vinyl chloride resin and of a stabilizer consisting essentially of 0.5 to 5 parts of zinc stearate, magnesium hydroxide and tripentaerythritol.
Claim 33
Dependent Claim 32 words
A vinyl halide resin composition which comprises 100 parts of a vinyl chloride resin and of a stabilizer consisting essentially of 0.5 to 5 parts of zinc stearate, magnesium hydroxide and tripentaerythritol.
Claim 34
Dependent Claim 32 words
A vinyl halide resin composition which comprises 100 parts of a vinyl chloride resin and of a stabilizer consisting essentially of 0.5 to 5 parts of zinc stearate, magnesium hydroxide and dipentaerythritol.
Claim 35
Dependent Claim 32 words
A vinyl halide resin composition which comprises 100 parts of a vinyl chloride resin and of a stabilizer consisting essentially of 0.5 to 5 parts of zinc stearate, magnesium hydroxide and dipentaerythritol.
Claim 36
Dependent Claim 32 words
A vinyl halide resin composition which comprises 100 parts of a vinyl chloride resin and of a stabilizer consisting essentially of 0.5 to 5 parts of zinc stearate, tripentaerythritol and magnesium acetate.
Claim 37
Dependent Claim 32 words
A vinyl halide resin composition which comprises 100 parts of a vinyl chloride resin and of a stabilizer consisting essentially of 0.5 to 5 parts of zinc stearate, tripentaerythritol and magnesium acetate.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-05-25 1984-11-24 1985-05-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-05-25 1988-11-24 1989-05-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-05-25 1992-11-24 1993-05-26 $7700.00 Window Closed / Lapsed

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